The invention discloses a
nitrogen-
doped carbon-coated catalyst as well as a preparation method and application thereof. The invention provides a
nitrogen-
doped carbon-coated catalyst for preparing halogenated arylamine through
catalytic hydrogenation of halogenated nitroaromatic hydrocarbons; the
nitrogen-
doped carbon-coated catalyst comprises a supported
metal catalyst and a
coating layer, the supported
metal catalyst comprises a carrier and a
metal active component, the
coating layer is a nitrogen-doped
carbon layer, and the thickness of the nitrogen-doped
carbon layer is 0.1 nm-10 nm. Themetal
active component is G-M, G is one or more of noble metals Pt, Pd, Rh or Ru, and M comprises at least one of metals Fe, Co, Ni, Sn and Mo. The catalyst provided by the invention is applied to preparation of halogenated arylamine through
catalytic hydrogenation of halogenated nitroaromatic
hydrocarbon; the conversion rate of the halogenated
nitrobenzene is as high as 100%, the nitrogen-doped carbon-coated catalyst is quite high in activity and excellent in stability, high-purity halogenated arylamine can be obtained, the selectivity can reach 99.7% or above, dehalogenation is smaller than0.3%, and dehalogenation is effectively inhibited; a dechlorination inhibitor does not need to be added into a
reaction system, so that the cost is reduced, the complexity of the
reaction system is reduced, and side reactions possibly introduced are reduced.