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194results about How to "Relieve swelling" patented technology

Lithium ion battery silicon-based composite anode material, preparation method thereof and battery

The invention relates to a lithium ion battery silicon-based composite anode material, a preparation method of the lithium ion battery silicon-based composite anode material, and a battery. The lithium ion battery silicon-based composite anode material adopts an embedded composite core-shell structure, a core has a structure formed by embedding nano silicon particles into a gap of an inner layer of hollowed graphite, and a shell is made from a non-graphite carbon material. According to the silicon-based composite anode material, mechanical grinding, mechanical fusing, isotropic compression processing and carbon coating technologies are combined, so that the nano silicon particles can be successfully embedded into the inner layer of the graphite and the surfaces of graphite particles are uniformly coated; the high-performance silicon-based composite anode material is obtained and is excellent in cycle performance (the 300-times cycle capacity retention ratio is more than 90%) and high in first efficiency (more than 90%); in addition, the silicon-based composite anode material is high in specific energy and compaction density, and can meet the requirements of a high-power density lithium ion battery; the preparation process is simple, the raw material cost is low, and the environment is protected.
Owner:BTR NEW MATERIAL GRP CO LTD

Double-shell-layer structure composite material, preparation method of double-shell-layer structure composite material, and lithium ion battery containing composite material

The invention discloses a double-shell-layer structure composite material, a preparation method of the double-shell-layer structure composite material, and a lithium ion battery containing the composite material. The double-shell-layer structure composite material comprises a nanometer silicon inner core, wherein a first coating layer and a second coating layer are sequentially arranged on the surface of the inner core; the first coating layer is nanometer metal particles embedded on the surface of the inner core; pores are formed between the nanometer metal particles; the second coating layeris a carbon coating layer positioned at the outer most layer of the composite material. Firstly, a layer of metal hydroxide covers in situ on the surface of the nanometer silicon particles; then, thesurface is subjected to organic carbon coating; the coating layer organic carbon is subjected to high-temperature carbonization, metal hydroxide of the first coating layer is firstly decomposed intometal oxides and is then reduced into nanometer metal simple substance particles by the carbon coating layer of the second coating layer; a great number of pores are left; the double-shell-layer structure composite material is obtained. The process is simple; when the composite material is used for a negative electrode of the lithium ion battery, the high specific volume and excellent circulationperformance are realized.
Owner:BTR NEW MATERIAL GRP CO LTD

High-capacity ratio rate carbon-based composite material, preparation method thereof and application thereof in lithium ion battery

The invention discloses a carbon-based composite material, a preparation method thereof and application thereof. The carbon-based composite material comprises micron-order soft carbon, micron-order hard carbon, a nano-active material, a first carbon coating layer and a second carbon coating layer, wherein the first carbon coating layer is coated on the surface of the nano-active material to form composite particles; the composite particles are dispersed on the surfaces of the soft carbon and the hard carbon and in the second carbon coating layer; the second carbon coating layer coats the softand hard carbon and the composite particles. The method disclosed by the invention comprises the following steps: 1) performing carbon coating on the nano-active material to form composite particles;2) dispersing the composite particles on the surface of the soft carbon and the hard carbon to form a first precursor; 3) performing coating modification by using an organic matter; 4) performing VC heating mixing or mixed kneading and molding; 5) sintering at a high temperature, thereby obtaining the composite material. The composite material disclosed by the invention is very suitable to serve as a negative electrode active material of the lithium ion battery, has high capacity and first charge and discharge efficiency and is excellent in rate capability.
Owner:BTR NEW MATERIAL GRP CO LTD

A negative electrode active material for a lithium ion battery, a preparing method thereof, a negative electrode plate of the lithium ion battery and the lithium ion battery

A negative electrode active material for a lithium ion battery is provided. The active material includes a composite formed by connecting a carbon material and black phosphorus through C-P bonds. The carbon material and the black phosphorus in the active material form the C-P bonds, thus ensuring tight contact between the carbon material and the black phosphorus in charge-discharge processes, and avoiding bad contact with the carbon material and a current collector when the black phosphorus is expanded. In addition, the carbon material is high in flexibility so that expansion of the black phosphorus can be relieved in the aspect of volume. The invention also provides a preparing method of the active material. The method includes mixing the carbon material and the black phosphorus, and then subjecting the mixture to ball milling at a ball milling speed of 300-700 r / min for 10-20 h, wherein the carbon material and the black phosphorus are connected through the C-P bonds to form the composite, and then the active material is formed. The method is simple and easy to operate. The invention also provides a negative electrode plate of the lithium ion battery and the lithium ion battery. The lithium ion battery has extremely high energy density and long cyclic lifetime.
Owner:SHENZHEN UNIV

Fiber-reinforced composite refractory castable for molten iron desulphurization lance and preparation method of fiber-reinforced composite refractory castable

The invention relates to a fiber-reinforced composite refractory castable for a molten iron desulphurization lance and a preparation method of the fiber-reinforced composite refractory castable. According to the technical scheme, the method comprises the steps of dispersing the following raw materials in parts by weight: 1-4 parts of mullite powder, 3-5 parts of kyanite, 5-8 parts of fused dense corundum powder, 5-8 parts of alpha-Al2O3 micro powder, 4-7 parts of silica powder, 1-4 parts of silicon carbide powder and 5-7 parts of pure aluminum silicate cement and an additive into a flat container and mixing evenly by using a rake; adding the following raw materials in parts by weight: 10-15 parts of first-level bauxite chamotte, 30-38 parts of natural fused mullite, 20-25 parts of andalusite and 1-2 parts of high-purity fused mullite particles; and pouring the mixed materials into a stirrer for stirring to obtain the fiber-reinforced composite refractory castable for the molten iron desulphurization lance. The fiber-reinforced composite refractory castable is low in cost and wide in raw material source, the obtained product is good in mechanical property and thermal shock resistance, the service life of the molten iron desulphurization lance can be prolonged, and the desulphurization cost can be reduced.
Owner:WUHAN UNIV OF SCI & TECH

Lithium ferric phosphate battery adopting compound conductive agent and manufacturing method thereof

The invention discloses a manufacturing method for a lithium ferric phosphate battery adopting a compound conductive agent. The manufacturing method comprises the following steps of: dissolving anode binder polyvinylidene fluoride in N-methyl pyrrolidone and stirring, thereby obtaining anode glue; adding a carbon nano-tube/conductive polymer compound material into the anode glue and scattering; adding anode active matter LiFePO4 and stirring, thereby obtaining anode slurry; uniformly coating the anode slurry on two surfaces of an aluminum foil, drying, and then rolling and slicing, thereby obtaining anode plates; uniformly mixing cathode active matter graphite, the carbon nano-tube/conductive polymer compound material, a cathode binder and de-ionized water, thereby obtaining cathode slurry; uniformly coating the cathode slurry on two surfaces of a copper foil, drying, and then rolling and slicing, thereby obtaining cathode slices; coiling, flatly pressing and banding, and then drying for 8 hours in vacuum at 65 DEG C; filling electrolyte into a dried battery; and forming an end product of the lithium ferric phosphate battery after filling the electrolyte. According to the manufacturing method provided by the invention, the capacity, multiplying power, circulation and safety property of the battery are greatly improved.
Owner:ZHEJIANG ZHENLONG BATTERY

Eye care apparatus

The invention relates to the field of health care, in particular to an eye care apparatus. The eye care apparatus comprises an installation frame, an installation plate, eye socket massage mechanism and two temple massage mechanisms; the installation plate is installed in the middle of the installation frame, four slide chutes are formed between the installation plate and the installation frame, two connecting plates are arranged on two sides of the installation frame, the eye socket massage mechanisms are fixedly connected with the installation plate, the temple massage mechanism are respectively installed on the connecting plates, each eye socket massage mechanism comprises a driving assembly and two massage assemblies, the massage assemblies are symmetrically arranged and are fixedly connected with the installation plate, and the massage assemblies are connected with the driving assembly. The eye care apparatus has the advantages that eye strain and swelling pain can be relieved through operation of the eye socket massage mechanisms and the temple massage mechanisms, eye temperature can be reduced through fitness of two water filling cushions and the eyes, comfortableness is improved, and the eye care apparatus is ingenious in structure, convenient to carry and low in cost.
Owner:THE FIRST AFFILIATED HOSPITAL OF HENAN UNIV OF SCI & TECH

Lithium-sulfur battery positive electrode material and preparation method thereof

The invention provides a lithium-sulfur battery positive electrode material and a preparation method thereof. The lithium-sulfur battery positive electrode material comprises a porous carbon material for accommodating sulfur and a metal sulfide loaded on the outer layer of the porous carbon material, wherein sulfur in the porous carbon material containing the sulfur comprises elemental sulfur with multiple pore channels and liquid metal in the pore channels of the elemental sulfur. The elemental sulfur with the multiple pore channels is adopted, so that the expansion of the electrode material can be reduced, and the ion conduction can be enhanced. The contact resistance between the carbon material and the elemental sulfur is reduced by the liquid metal in the elemental sulfur with multiple channels, and the contact area between the elemental sulfur and the conductor is increased, so that a catalytic effect is achieved on the elemental sulfur to form the polysulfide. Metal sulfides outside of carbon materials are capable of absorbing S<2-> formed in the discharging process. Through the synergistic adsorption catalysis effect of the liquid metal in the elemental sulfur with the pore channels and the metal sulfides wrapping outside the sulfur-loaded porous carbon, the electrode material is enabled to have high energy density and high cycling stability.
Owner:FUZHOU UNIV

Caron-coated stannous oxide compound and preparation method and application thereof

The invention discloses a carbon-coated stannous oxide compound. The carbon-coated stannous oxide compound is prepared by the steps of dissolving trihydroxymethyl aminomethane into water, stirring and preparing into a buffer solution; weighing the buffer solution, adding stannous oxide, stirring to form a black turbid solution; adding dopamine and continuously stirring; performing washing, centrifuging and drying; and performing calcining in nitrogen atmosphere to obtain the carbon-coated stannous oxide composite material. Dopamine is used as the carbon source for coating the surface of SnO, so that volume expansion of SnO in a circulation process is relieved, thereby improving the cycling performance in the application when SnO is used as a negative electrode material of a sodium ion battery; in the synthesis process, the solvent is non-toxic and harmless, the cost is relatively low and the operation is simple; the carbon-coated stannous oxide composite material has the most major advantage of excellent cycling performance; the initial-circle charging specific capacity can be close to 500mAh/g and the capacity is barely attenuated after 300 cycles, so that possibility is provided for the actual application of the composite material in the sodium ion battery material in the future.
Owner:NORTHEAST NORMAL UNIVERSITY

Lithium battery negative electrode material containing pre-lithiated silylene material, preparation method and lithium battery

The embodiment of the invention relates to a lithium battery negative electrode material containing a pre-lithiated silylene material, a preparation method and a lithium battery. The negative electrode material has a core-shell structure, wherein an inner core is a mixture of the pre-lithiated silylene material and carbon particles, and an outer shell is one or more carbon-containing layers; the mass ratio of the inner core to the negative electrode material is [80%, 99%]; the mass ratio of the pre-lithiated silylene material in the inner core to the inner core is [10%, 90%]; the mass ratio ofthe outer shell to the negative electrode material [1%, 20%]; the pre-lithiated silylene material is of a sheet structure, and a phase comprises nano silicon and / or silicon oxide and lithium silicate; and the lithium silicate is one or more of Li4SiO4, Li2SiO5 and Li2SiO3. The negative electrode material effectively alleviates the expansion problem of the negative electrode material through the flaky characteristics of silylene or silylene oxide; by lithiating the silylene material in advance, the first charge-discharge efficiency of the negative electrode material is improved; and through carbon coating on the surface layer, the negative electrode material has the advantages of long cycle and high cycle stability.
Owner:LIYANG TIANMU PILOT BATTERY MATERIAL TECH CO LTD

A molybdenum disulfide matrix composite material for negative electrode of lithium ion capacitor and preparation method thereof

ActiveCN109243834A(002) surface characteristic peak broadeningLow priceMaterial nanotechnologyHybrid capacitor electrodesThioureaReaction temperature
The invention belongs to the technical field of lithium ion capacitors, and discloses a molybdenum disulfide-based composite material for a negative electrode of a lithium ion capacitor and a preparation method thereof. The method includes: (1) Ammonium molybdate tetrahydrate or ammonium molybdate, aniline, phosphorus and graphene oxide were mixed uniformly in water; the pH value of the reaction system is adjusted to 4-5, the reaction temperature is kept to obtain the precursor; (2) the precursor reacts under acidic condition and initiator to obtain intermediate product; Acidic condition refers to pH 1.7 - 2.3 of the reaction solution; 3) dispering that intermediate product and thiourea in water, and place the intermediate product and thiourea in a hydrothermal reaction device for hydrothermal reaction to obtain molybdenum disulfide matrix composite material. The method of the invention is simple and efficient. As that composite material obtain has excellent electrochemical propertiesand cycle stability, the composite material has excellent lithium storage performance in a lithium ion capacitor negative electrode material, and has wide application prospect in a lithium ion capacitor.
Owner:SOUTH CHINA UNIV OF TECH

AA-MBBR sewage treatment system and sewage treatment method

The invention discloses an AA-MBBR sewage treatment system. The AA-MBBR sewage treatment system comprises a water inlet pond, a water inlet pump, an anoxic MBBR pond, a main reaction pond, a sludge refluxing pump and a secondary sedimentation tank. The water inlet pond is connected to the anoxic MBBR pond via a water inlet tube through the water inlet pump; the main reaction pond is divided into an aerobic MBBR pond positioned in the outer ring and an anaerobic pond positioned in the inner ring; a water outlet tube of the anoxic MBBR pond is connected into the anaerobic pond in the inner ring of the main reaction pond through a pipeline; an aerator tube is arranged at the bottom in the aerobic MBBR pond and is provided with an aerator; a refluxing hole is formed in the bottom of the anaerobic pond; a water inlet hole which communicates to the inside of the aerobic MBBR pond is formed in a position, which is close to the bottom, of the anaerobic pond; a water outlet is formed in the upper part of the outer side of the main reaction pond and is connected into the secondary sedimentation tank via a pipeline; the bottom of the secondary sedimentation tank is connected with a refluxing tube; and the secondary sedimentation tank is connected to the refluxing hole of the anaerobic pond via the refluxing tube through the sludge refluxing pump. The AA-MBBR sewage treatment system is high in nitrogen and phosphorus removal ability and good in effect.
Owner:SHENYANG ACAD OF ENVIRONMENTAL SCI

Silicon-carbon negative electrode material and preparation method thereof

The invention discloses a silicon-carbon composite negative electrode material and a preparation method thereof. The silicon-carbon negative electrode material comprises a nano-silicon material whichis prepared from nano-silicon and a conductive polymer material and is coated with a conductive carbon film on the surface, and the nano silicon material coated with the conductive carbon film is uniformly distributedin the spherical graphite, on the surface of the spherical graphite and on the surface of the graphene to form a nano silicon/graphite/graphene structure, and two layers of organic carbon sources are uniformly coatedon the nano silicon/graphite/graphene structure to obtain the silicon-carbon negative electrode material. The conductive polymer material and two layers of organic carbon sources are coated on the surface of the nano silicon, so that the conductivity of the silicon is enhanced, and the expansion of the silicon is inhibited; aslurry is subjected to drying and twiceroasting in a short time through three times of spray drying, so that the silicon-carbon negative electrode material which is relatively good in silicon dispersion effect and is uniformly coated withorganic pyrolytic carbon is obtained; the preparation method of the silicon-carbon composite negative electrode material is simple, environment-friendly, rich in used raw materials, low in equipment cost and suitable for industrial production and application.
Owner:SHAANXI COAL & CHEM TECH INST
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