Fiber-reinforced composite refractory castable for molten iron desulphurization lance and preparation method of fiber-reinforced composite refractory castable

A refractory castable and fiber composite technology, applied in the field of refractory castables, can solve the problems of not providing a specific method for uniform dispersion of carbon fibers, failure to provide thermal shock stability, and expensive raw materials, etc., to slow down high-temperature oxidation ablation process, improving thermal shock stability and volume stability, mitigating further expansion, and the effect of

Active Publication Date: 2017-05-17
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the raw materials used are expensive, and there is no description of the shape, fiber diameter and length of carbon nanofibers, how to obtain them, and how to uniformly disperse them in the castable. The detection equipment is also difficult to complete the detection, and at the same time, it fails to provide relevant test results support for the thermal shock stability of concern
[0006] "A casting material for blast furnace iron trough containing carbon fiber

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] A fiber composite toughened refractory castable for a molten iron desulfurization spray gun and a preparation method thereof. The composition and mass parts of the fiber composite toughened refractory castable for molten iron desulfurization spray guns are: 10-11 parts by mass of first-grade high-alumina bauxite clinker, 36-38 parts by mass of natural fused mullite , 20-21 parts of andalusite, 1-1.2 parts of high-purity capacitor mullite particles, 1-1.8 parts of high-purity fused mullite powder, 3-3.5 parts of kyanite, 5~6 parts by mass of fused dense corundum fine powder, 5~6 parts by mass of α-Al 2 o 3 Micropowder, 4-5 parts by mass of silicon micropowder, 1-1.5 parts by mass of silicon carbide powder and 6-7 parts by mass of pure calcium aluminate cement as raw materials; 2.1-2.6 parts by mass of composite fiber, 0.5-1 by mass Silicon powder, 0.05-0.08 parts of polypropylene fiber, 0.02-0.03 parts of carboxymethyl cellulose, 0.01-0.02 parts of defoamer and 0.2-0.2...

Embodiment 2

[0054] A fiber composite toughened refractory castable for a molten iron desulfurization spray gun and a preparation method thereof. The composition and mass parts of the fiber composite toughened refractory castable for molten iron desulfurization spray guns are: 11-12 parts by mass of first-grade high-alumina bauxite clinker, 31-36 parts by mass of natural fused mullite , 21~22 parts of andalusite, 1~1.5 parts of high-purity capacitor mullite particles, 2~2.5 parts of high-purity fused mullite powder, 3.5~4 parts of kyanite, 6~6.5 parts by mass of fused dense corundum fine powder, 6~6.5 parts by mass of α-Al 2 o 3 Micropowder, 5-5.5 parts by mass of silicon micropowder, 1.5-2.5 parts by mass of silicon carbide powder and 5.5-6 parts by mass of pure calcium aluminate cement as raw materials; 1.9-2.4 parts by mass of composite fiber, 1-1.5 parts by mass Silicon powder, 0.08-0.11 parts of polypropylene fiber, 0.03-0.04 parts of carboxymethyl cellulose, 0.01-0.02 parts of defo...

Embodiment 3

[0058] A fiber composite toughened refractory castable for a molten iron desulfurization spray gun and a preparation method thereof. The composition and mass parts of the fiber composite toughened refractory castable for molten iron desulfurization spray guns are: 12-15 parts by mass of first-grade high-alumina bauxite clinker, 30-31 parts by mass of natural fused mullite , 22~25 parts of andalusite, 1.5~2 parts of high-purity capacitor mullite particles, 2.5~4 parts of high-purity fused mullite powder, 4~5 parts of kyanite, 6.5-8 parts by mass of fused dense corundum fine powder, 6.5-8 parts by mass of α-Al 2 o 3 Micropowder, 5.5-7 parts by mass of silicon micropowder, 2.5-3 parts by mass of silicon carbide powder and 5-5.5 parts by mass of pure calcium aluminate cement as raw materials; 1.8-2.3 parts by mass of composite fiber, 1.5-2 parts by mass Silica fume, 0.11-0.15 parts by mass of polypropylene fiber, 0.04-0.05 parts by mass of carboxymethyl cellulose, 0.01-0.02 part...

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PUM

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Abstract

The invention relates to a fiber-reinforced composite refractory castable for a molten iron desulphurization lance and a preparation method of the fiber-reinforced composite refractory castable. According to the technical scheme, the method comprises the steps of dispersing the following raw materials in parts by weight: 1-4 parts of mullite powder, 3-5 parts of kyanite, 5-8 parts of fused dense corundum powder, 5-8 parts of alpha-Al2O3 micro powder, 4-7 parts of silica powder, 1-4 parts of silicon carbide powder and 5-7 parts of pure aluminum silicate cement and an additive into a flat container and mixing evenly by using a rake; adding the following raw materials in parts by weight: 10-15 parts of first-level bauxite chamotte, 30-38 parts of natural fused mullite, 20-25 parts of andalusite and 1-2 parts of high-purity fused mullite particles; and pouring the mixed materials into a stirrer for stirring to obtain the fiber-reinforced composite refractory castable for the molten iron desulphurization lance. The fiber-reinforced composite refractory castable is low in cost and wide in raw material source, the obtained product is good in mechanical property and thermal shock resistance, the service life of the molten iron desulphurization lance can be prolonged, and the desulphurization cost can be reduced.

Description

technical field [0001] The invention relates to the technical field of refractory castables. In particular, it relates to a fiber composite toughened refractory castable for a molten iron desulfurization spray gun and a preparation method thereof. Background technique [0002] According to the type of desulfurizer and the structure of the molten iron container, the desulfurization process is divided into calcium-based or magnesium-based mixed, calcium-based or magnesium-based composite, metal particle magnesium pure spray, etc.; the corresponding spray gun structure is: oblique single nozzle, straight Inverted T-shaped double nozzles, inverted Y-shaped double nozzles, straight-through single nozzles and gasification chamber nozzles, etc. Although the structures are different, all kinds of molten iron desulfurization spray guns are composite structures composed of a metal gun core and a refractory material gun lining wrapped around the metal gun core. Among them, the main f...

Claims

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Application Information

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IPC IPC(8): C04B35/66
CPCC04B35/66
Inventor 李远兵欧阳思李淑静徐娜娜向若飞
Owner WUHAN UNIV OF SCI & TECH
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