Novel N-type silicon hetero-junction battery with IBC (interdigitated back-contacted) structure and fabrication method thereof

A silicon heterojunction, N-type technology, applied in circuits, photovoltaic power generation, electrical components, etc., can solve problems such as battery decline, battery efficiency limitation, and improvement, and achieve the goal of increasing short-circuit current density, improving stability, and reducing damage Effect

Inactive Publication Date: 2011-09-28
HEFEI HAREON SOLAR TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the phosphorus atoms on the front surface of this N-type crystalline silicon cell can still form boron-oxygen bonds with the oxygen in the substrate under the action of ultraviolet light. Conducive to the improvement of solar cell efficiency
At the same time, the shielding of the gate and the high temperature boron diffusion process of about 900 degrees in this traditional battery reduce the minority carrier lifetime of the N-type silicon substrate, which limits the further improvement of the battery efficiency.

Method used

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  • Novel N-type silicon hetero-junction battery with IBC (interdigitated back-contacted) structure and fabrication method thereof
  • Novel N-type silicon hetero-junction battery with IBC (interdigitated back-contacted) structure and fabrication method thereof
  • Novel N-type silicon hetero-junction battery with IBC (interdigitated back-contacted) structure and fabrication method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Such as figure 1A new IBC structure N-type silicon heterojunction cell is shown, including: N-type silicon substrate 1, silicon nitride film 2, aluminum oxide film 3, intrinsic amorphous silicon 4, and P-type amorphous silicon 5. N-type heavily doped region 6, positive electrode 7 of the battery, negative electrode 8 of the battery; the front surface of the N-type silicon substrate 1 is covered with an aluminum oxide film 3, and the aluminum oxide layer film 3 is covered with a nitride Silicon thin film 2; intrinsic amorphous silicon 4 and P-type amorphous silicon 5 are deposited on the back surface of the N-type silicon substrate 1, and intrinsic amorphous silicon 4 and P-type amorphous silicon 5 are provided with grooves. The bottom of the groove is an N-type heavily doped region 6, and the electrode negative electrode 8 is arranged in the groove; the positive electrode 7 of the battery is arranged on the back surface of the P-type amorphous silicon 5.

[0046] The p...

Embodiment 2

[0061] The structure of the new type IBC structure N-type silicon heterojunction cell is the same as in Example 1;

[0062] The preparation method of the novel IBC structure N-type silicon heterojunction cell in Example 2 is as follows:

[0063] (a) Select an N-type silicon substrate, and the resistivity of the N-type silicon substrate is 5??cm;

[0064] (b) Use potassium hydroxide solution to texture the surface of the N-type single crystal silicon substrate, prepare a pyramid-shaped light-trapping structure on the surface of the N-type silicon substrate, and perform chemical cleaning with a mixed solution of hydrochloric acid and hydrofluoric acid The concentration of potassium hydroxide solution is 1.5%; in the mixed solution of hydrochloric acid and hydrofluoric acid, the ratio of hydrochloric acid to hydrofluoric acid is 1:2; the concentration of mixed solution of hydrochloric acid and hydrofluoric acid is 0.9%;

[0065] (c) Deposit intrinsic amorphous silicon and P-type...

Embodiment 3

[0077] The structure of the new type IBC structure N-type silicon heterojunction cell is the same as in Example 1;

[0078] The preparation method of the novel IBC structure N-type silicon heterojunction cell in Example 3 is as follows:

[0079] (a) Select an N-type silicon substrate, and the resistivity of the N-type silicon substrate is 0.3??cm;

[0080] (b) Use potassium hydroxide solution to texture the surface of the N-type single crystal silicon substrate, prepare a pyramid-shaped light-trapping structure on the surface of the N-type silicon substrate, and perform chemical cleaning with a mixed solution of hydrochloric acid and hydrofluoric acid The concentration of potassium hydroxide solution is 0.5%; in hydrochloric acid and hydrofluoric acid mixed solution, hydrochloric acid: hydrofluoric acid ratio is 1:3; the concentration of hydrochloric acid and hydrofluoric acid mixed solution is 0.8%;

[0081] (c) Deposit intrinsic amorphous silicon and P-type amorphous silico...

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Abstract

The invention discloses a novel N-type silicon hetero-junction battery with an IBC structure, wherein an Al2O3 thin film covers the front surface of an N-type silicon substrate; a Si3N4 thin film covers the Al2O3 thin film; intrinsic amorphous silicon and P-type amorphous silicon are deposited on the back surface of the N-type silicon substrate and are provided with a trench respectively; an N-type heavily doped region is arranged at the bottom of each trench; a negative electrode is arranged in each trench; and a positive electrode of the battery is arranged on the back surface of the P-type amorphous silicon. The invention also discloses a fabrication method of the battery. In the invention, since the amorphous silicon is deposited by laser doping and PECVD (plasma enhanced chemical vapor deposition), a high-temperature diffusion process does not occur in the entire process, thereby maximally keeping the service life of minority carriers of the silicon substrate and reducing the damage of the high-temperature process to the N-type silicon substrate. Meanwhile, the battery with the IBC structure enables a battery plate to fully utilize the solar spectra so as to maximally improve the short-circuit current density of the battery; and the stability of the solar battery is improved due to no P-type heavily doped region exists.

Description

technical field [0001] The invention relates to the field of manufacturing crystalline silicon solar cells, in particular to a novel IBC (Interdigitated back-contacted) structure N-type silicon heterojunction cell and a preparation method. Background technique [0002] In the context of energy shortage and increasingly prominent environmental pollution problems, the development of renewable energy has become a major global issue, and the use of solar energy is a key direction for the development of renewable energy. The world photovoltaic market has maintained an average annual growth rate of 30% in the past ten years. The high-speed growth rate of more than 100% has reached an astonishing 152.8% in 2009. Production increased from 7.91GW in 2008 to nearly 20GW in 2009. Compared with foreign advanced cell preparation technology, my country's crystalline silicon solar cell preparation technology is still relatively backward. The basic process consists of texturing, diffusion,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/072H01L31/18
CPCY02E10/50Y02P70/50
Inventor 高艳涛邢国强张斌陶龙忠沙泉李晓强
Owner HEFEI HAREON SOLAR TECH
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