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Pretreatment method of wood flour suitable for plastic filling

A treatment method and pretreatment technology, which is applied in the field of wood powder pretreatment, can solve the problems of unfavorable environmental protection, waste liquid pollution, etc., and achieve the effect of improving crystallinity and good mechanical properties

Inactive Publication Date: 2011-10-26
EAST CHINA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The pretreatment of wood powder does not use expensive coupling agents or compatibilizers in production, but from the perspective of material properties, the effect of wood powder pretreatment is not as good as that of directly adding coupling agents or compatibilizers , and alkali treatment and surface grafting treatment will produce polluted waste liquid, which is not conducive to environmental protection

Method used

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  • Pretreatment method of wood flour suitable for plastic filling
  • Pretreatment method of wood flour suitable for plastic filling

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Adopt 80 mesh poplar wood flour, provided by Zhejiang Lin'an Mingzhu Bamboo and Wood Powder Co., Ltd.; PP, provided by Sinopec Shanghai Chemical Co., Ltd., brand T300, MFI=3g / 10min (2.16KG / 230 ℃), the stretching of this PP The strength is 31MPa, the bending strength is 31MPa, and the impact strength is 9KJ / m 2 . Boil the wood powder directly with an electric kettle, add wood powder and water according to the mass ratio of wood powder and water 1:8, stir until the wood powder sinks to the bottom of the pot and start heating. Boil for 10 minutes after the water boils, stop heating and suction filter while it is hot, and process the wood flour filter cake in a vacuum oven for 12 hours, and the vacuum degree of the oven is 0.09-0.1MPa. After the treatment, open the oven door to dry the wood flour to constant weight, and then sieve through 80 meshes.

[0021] Add 30phr of treated wood powder, 70phr of PP and processing aids into the HAAKE rheometer to melt and blend for 15...

Embodiment 2

[0023] Adopt 80 mesh poplar wood flour, provided by Zhejiang Linan Mingzhu Bamboo and Wood Powder Co., Ltd.; PP, provided by Sinopec Shanghai Chemical Co., Ltd., brand T300; PP-g-mah, provided by Nanjing Deba Chemical Co., Ltd., the grafting rate is about 1%. Boil the wood powder with an electric kettle, add wood powder and water according to the mass ratio of wood powder and water 1:10, stir until the wood powder sinks to the bottom of the pot and start heating. Boil for 10 minutes after the water boils, stop heating and suction filter while it is hot, and perform sauna treatment on the wood flour filter cake for 12 hours in a vacuum oven, and the vacuum degree of the oven is 0.09-0.1MPa. After the treatment, open the oven door to dry the wood flour to constant weight, and then sieve through 80 meshes.

[0024] Add 30phr of treated wood powder, 70phr of PP and 5phr of PP-g-mah into the HAAKE rheometer for melt blending for 15min at a speed of 60rpm and a blending temperature...

Embodiment 3

[0026]Adopt 80 mesh poplar wood flour, provided by Zhejiang Linan Mingzhu Bamboo and Wood Powder Co., Ltd.; PP, provided by Sinopec Shanghai Chemical Co., Ltd., brand T300; PP-g-mah, provided by Nanjing Deba Chemical Co., Ltd., the grafting rate is about 1%. Boil the wood powder with an electric kettle, add wood powder and water according to the mass ratio of wood powder and water at 1:10, boil for 15 minutes after the water boils, stop heating and suction filter while it is hot, and put the wood powder filter cake in a vacuum oven for sauna After 12 hours of treatment, the vacuum degree of the oven is at 0.09-0.1MPa. After the treatment, open the oven door to dry the wood flour to constant weight, and then sieve through 80 meshes.

[0027] Add 60phr of treated wood flour, 40phr of PP and 5phr of PP-g-mah into the HAAKE rheometer for melt blending for 15min at a speed of 60rpm and a blending temperature of 180°C; use a 25-ton flat vulcanizer to prepare composite material shee...

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Abstract

The present invention discloses a high-temperature treatment method of wood flour, which is characterized by adding wood flour and water at a weight ratio of (1:5)-(1:20) into a container, boiling, placing the boiled wood flour in a vacuum oven, carrying out vacuum high-temperature treatment at the temperature of 100-110 DEG C for 6-50 hours and drying at the temperature of 100-110 DEG C to constant weight to obtain treated wood flour. The PP (polypropylene)-based wood-plastic composite material prepared from the wood flour treated by the high-temperature treatment method has mechanical properties equivalent to the PP-based wood-plastic composite material containing a compatibilizer PP-g-mah (polypropylene-graft-maleic anhydride), and the simultaneous use of the wood flour and PP-g-mah greatly improves the mechanical properties of the PP-based wood-plastic composite material. The high-temperature treatment method has the advantages of simple used utensil, simple operation process, excellent performance of the prepared materials, no pollutant generation during the production process and reusable boiled wastewater and is an environmentally-friendly high-efficiency wood flour treatment mode.

Description

Technical field: [0001] The invention relates to a wood powder pretreatment method, in particular to a wood powder pretreatment method used in the production of wood powder-filled polypropylene (PP) plastic polymer composite materials. Background technique: [0002] Nowadays, the plastic industry is developing rapidly and is widely used in various fields. In order to meet different requirements, various plastic alloys, polymer composite materials filled with rigid particles such as inorganic particles and fibers have come out one after another, and wood powder, Plant fibers such as straw and rice husks are filled with thermoplastic resins, and wood-plastic composites (WPC), which are processed by extrusion, injection molding and other plastic molding methods, have also become a research topic due to their excellent performance and convenient processing methods. one of the hotspots. Wood-plastic composite material combines the characteristics of wood and plastic materials. I...

Claims

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Application Information

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IPC IPC(8): C08J3/00C08L23/12C08L97/02
Inventor 郭卫红杨俊王纪斌汪济奎张桂新陈程王伟
Owner EAST CHINA UNIV OF SCI & TECH
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