Melbine crystal, medicinal composition of melbine crystal and pioglitazone and preparation method for medicinal composition
A technology of metformin and pioglitazone, which is applied in the field of medicine, can solve problems such as large differences in tablet weight, weaken patient compliance, and gastrointestinal irritation, reduce the amount and type of excipients, save preparation costs and processes, and simplify preparation processes Effect
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Embodiment 1
[0049] [Example 1] Preparation of metformin crystals
[0050] 1) dissolving metformin powder in a water / ethanol mixed solution to form a metformin solution;
[0051] 2) Under stirring, add chloroform dropwise to the metformin solution prepared in step 1) until it becomes turbid;
[0052] 3) heating the turbid solution obtained in step 2) under an ultrasonic field until the solution becomes clear, and filtering;
[0053] 4) Leave the filtrate obtained in step 3) until the product precipitates, filter, wash the filter cake with anhydrous chloroform, and dry in vacuum to obtain metformin crystals.
[0054] The particle diameter of the metformin crystals obtained is 80 μm, and the X-ray powder diffraction pattern (see figure 1 ) in the characteristic peaks are displayed at 2θ of 11.2, 12.8, 14.9, 15.2, 15.3, 18.8, 22.8, 23.5, 26.6.
Embodiment 2
[0055] [Example 2] Preparation of metformin crystals
[0056] 1) Dissolve metformin powder in a water / ethanol mixed solution with a volume ratio of 1:8 to make a concentration of 10mol L -1 metformin solution;
[0057] 2) Under stirring, at 25°C, add chloroform dropwise to the metformin solution prepared in step 1) at a rate of 1ml / min until it becomes turbid;
[0058] 3) Heat the turbid solution obtained in step 2) to 40° C. under an ultrasonic field until the solution becomes clear, and filter;
[0059] 4) Stand the filtrate obtained in step 3) at 20° C. for 2 days until the product precipitates, filter, wash the filter cake with anhydrous chloroform, and dry in vacuum to obtain metformin crystals.
[0060] The obtained metformin crystals have a particle size of 60 μm, and the X-ray powder diffraction pattern measured by Cu-Kα rays is consistent with that of Example 1.
Embodiment 3
[0061] [Example 3] Preparation of metformin crystals
[0062] 1) Dissolve metformin powder in a water / ethanol mixed solution with a volume ratio of 1:3 to make a concentration of 25mol L -1 metformin solution;
[0063] 2) Under stirring, at 15°C, add chloroform dropwise to the metformin solution prepared in step 1) at a rate of 3ml / min until it becomes turbid;
[0064] 3) Heating the turbid solution obtained in step 2) to 50° C. under an ultrasonic field until the solution becomes clear, and filtering;
[0065] 4) Stand the filtrate obtained in step 3) at 25° C. for 2 days until the product precipitates, filter, wash the filter cake with anhydrous chloroform, and dry in vacuum to obtain metformin crystals.
[0066] The obtained metformin crystals have a particle size of 100 μm, and the X-ray powder diffraction pattern measured by Cu-Kα rays is consistent with that of Example 1.
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