Temperature resistant, non-crosslinked and biodegradable gel leak-stopping agent and preparation method thereof
A technology of plugging agent and gel, which is applied in the field of degradable gel plugging agent and its preparation, temperature resistance, and non-crosslinking. Return to the wellbore and other issues to achieve the effects of fast dissolution, convenient construction, and improved pressure bearing capacity
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Embodiment 1
[0036] Preparation and performance test of gel plugging agent 1:
[0037] 1. Weigh 24g of maleic anhydride and dissolve it in 112.4g of toluene solvent, add 52g of n-hexadecanol, and add 1.6g of catalyst sodium p-toluenesulfonate to react at 62 ° C for 8 hours, and then use 10g of hydroxide After the sodium is neutralized for 1.5 hours, the solid obtained after cooling to room temperature and filtering is the associative monomer maleic acid monohexadecyl ester sodium salt.
[0038] 2. Weigh 7.2 g of sodium hydroxide and dissolve it in 64.8 g of deionized water to prepare a sodium hydroxide solution. Then 15.6 g of acrylic acid was weighed, and 9.6 g of sodium salt of monohexadecyl maleate, an associative monomer synthesized in the first step, was weighed after neutralizing the two for 30 min. 8.4 g of sodium benzenesulfonate, 79.2 g of acrylamide, 115.2 g of deionized water were added, and the mixture was fully stirred and dissolved at 20°C.
[0039] 3. Add 0.3 g of potassiu...
Embodiment 2
[0042] Preparation and performance test of gel plugging agent 2:
[0043]1. Weigh 56g of maleic anhydride and dissolve it in 197.6g of toluene solvent, add 120g of n-hexadecanol, and add 2.4g of catalyst sodium p-toluenesulfonate to react at 78°C for 6 hours, and then use 24g of hydroxide After the sodium is neutralized for 2 hours, the solid obtained after cooling to room temperature and filtering is the associative monomer maleic acid monohexadecyl ester sodium salt.
[0044] 2. Weigh 9.6 g of sodium hydroxide and dissolve it in 70.4 g of deionized water to prepare a sodium hydroxide solution. Then 19.2 g of acrylic acid was weighed, and 8.4 g of sodium salt of monohexadecyl maleate, an associative monomer synthesized in the first step, was weighed after neutralizing the two for 30 min. 6 g of sodium benzenesulfonate, 76.8 g of acrylamide, 209.6 g of deionized water were added, and the mixture was fully stirred and dissolved at 28°C.
[0045] 3. Add 0.8 g of ammonium persu...
Embodiment 3
[0048] Preparation and performance test of gel plugging agent 3:
[0049] 1. Weigh 39g of maleic anhydride and dissolve it in 157.5g of toluene solvent, add 84g of n-hexadecanol, and add 3g of catalyst sodium p-toluenesulfonate to react at 71 ° C for 7 hours, and then use 16.5g of hydrogen peroxide After the sodium is neutralized for 1 hour, the solid obtained after cooling to room temperature and filtering is the associative monomer maleic acid monohexadecyl ester sodium salt.
[0050] 2. Weigh 4.9 g of sodium hydroxide and dissolve it in 39.6 g of deionized water to prepare a sodium hydroxide solution. Then 10.2 g of acrylic acid was weighed, and 4.2 g of the associative monomer monohexadecyl maleate sodium salt synthesized in the first step was weighed after the neutralization reaction was carried out for 30 min. 4.2 g of sodium benzenesulfonate, 46.5 g of acrylamide, 90.4 g of deionized water were added, and the mixture was fully stirred and dissolved at 12°C.
[0051] 3...
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