Fluorine-containing modified vegetable oil polymer water-repellent finishing agent, and preparation and application thereof

A technology for modified vegetable oil and water-repellent finishing, applied in the field of fluorine-containing modified vegetable oil polymer water-repellent finishing agent and its preparation and application fields, can solve the problem that the fabric is prone to static electricity, the effect of cellulose fiber wearability, and the affinity of cellulose fiber. Water quality reduction and other issues, to achieve the effects of low cost, low environmental pollution, and simple synthesis process

Inactive Publication Date: 2014-01-08
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Cellulose fiber is popular in the field of clothing because of its excellent wearability. However, the hydrophilicity of cellulose fiber after organic fluorine treatment is reduced, which makes the fabric prone to static electricity, which has adverse effects on the original wearability of the cellulose fiber. influences

Method used

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  • Fluorine-containing modified vegetable oil polymer water-repellent finishing agent, and preparation and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] (1) Add 30 mL of absolute ethanol solution and 0.15 mol of sodium hydroxide solution to 29 g of linseed oil, heat in an oil bath at 120° C., stir, and let stand. Heat to remove absolute ethanol. Add 20-30mL of hot saturated sodium chloride solution to precipitate the mixture of sodium linolenate, sodium soybeanate, sodium stearate, sodium oleate, sodium linoleate and sodium linolenate, and remove glycerin with the aqueous sodium chloride solution.

[0038] (2) The mixture of sodium stearate, sodium oleate, sodium linoleate and sodium linolenate prepared in step (1) is acidified by adding 5-10mL1mol / L dilute sulfuric acid to obtain stearic acid, oleic acid, linolenic acid A mixture of oleic and linolenic acids.

[0039] (3) 23g of the mixture of stearic acid, oleic acid, linoleic acid and linolenic acid prepared in step (2) was added to CF containing 0.1mol 3 CH 2 In a three-necked OH bottle, heat up to 60°C, stir, and react for 6 hours to obtain a mixture of trifluor...

Embodiment 2

[0044] (1) Add 30 mL of absolute ethanol solution and 0.15 mol of sodium hydroxide solution to 35 g of soybean oil, heat in an oil bath at 120° C., stir, and let stand. Heat to remove absolute ethanol. Add 20-30mL hot saturated sodium chloride solution to precipitate the mixture of sodium soybean oleate, sodium stearate and sodium oleate, and remove the glycerin with the aqueous sodium chloride solution.

[0045] (2) The mixture of sodium stearate, sodium oleate, and sodium soyate prepared in step (1) is acidified by adding 5 mL of 1mol / L dilute sulfuric acid to obtain a mixture of stearic acid, oleic acid, and soybean acid.

[0046] (3) 21 g of the mixture of stearic acid and oleic acid soybean acid prepared in step (2) is added to CF containing 0.1 mol 3 CH 2 CH 2 In an OH three-necked flask, heat up to 60°C, stir and react for 6 hours to obtain a mixture of fluorine-containing esters.

[0047] (4) Stir and react the fluorine-containing ester prepared in step (3) with 10...

Embodiment 3

[0052] (1) Add 30 mL of absolute ethanol solution and 0.15 mol of sodium hydroxide solution to 30 g of olive oil, heat in an oil bath at 120° C., stir, and let stand. Heat to remove absolute ethanol. Add 20-30mL hot saturated sodium chloride solution to precipitate the mixture of sodium stearate, sodium linoleate and sodium linolenate, and remove the glycerin with the aqueous sodium chloride solution.

[0053] (2) The mixture of sodium stearate, sodium linoleate, and linolenic acid prepared in step (1) is acidified by adding 5 mL of 1mol / L dilute sulfuric acid to obtain a mixture of stearic acid, linoleic acid, and linolenic acid.

[0054] (3) 25g of the mixture of stearic acid, linoleic acid and linolenic acid prepared in step (2) is added to the CF containing 0.1mol 3 (CH 2 ) 2 CH 2 In an OH three-necked flask, heat up to 60°C, stir and react for 6 hours to obtain a mixture of fluorine-containing esters.

[0055] (4) Stir and react the fluorine-containing ester prepared...

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Abstract

The invention relates to a fluorine-containing modified vegetable oil polymer water-repellent finishing agent, and preparation and an application thereof. The water-repellent finishing agent is obtained after a mixture is polymerized with styrene, wherein the mixture is composed of esters; the esters are generated from a reaction between fatty acid and CF3-(CF2)m-CH2OH or CF2H-(CF2)m-CH2OH; and the fatty acid is obtained by hydrolyzing vegetable oil. A preparation method of the water-repellent finishing agent comprises the following steps: (1) hydrolyzing the vegetable oil, thereby obtaining fatty acid sodium; (2) acidizing the fatty acid sodium, thereby obtaining higher fatty acid; (3) performing esterification on the higher fatty acid and fluorine-containing alcohol, thereby obtaining a fluorine-containing ester; and (4) adding the fluorine-containing ester to the styrene, thereby obtaining the water-repellent finishing agent. The water-repellent finishing agent provided by the invention is applied to the water-repellent finishing for cellulose fibers and blend fabrics thereof. The water-repellent finishing agent provided by the invention is free from obvious influence on air permeability, whiteness and breaking strength of the cellulose fibers. The water-repellent finishing agent provided by the invention has the advantages that a synthesizing process is simple, the cost is low, and raw materials are environment-friendly and cause less environmental pollution.

Description

technical field [0001] The invention belongs to the field of fluorine-containing water-repellent finishing agent and its preparation and application, and in particular relates to a fluorine-containing modified vegetable oil polymer water-repellent finishing agent and its preparation and application. Background technique [0002] Water-repellent finishing is an important aspect of functional finishing. With the continuous advancement of science and technology, new fabric water-repellent finishing technologies are constantly being adopted by people, and metal soaps, metal complexes, pyridines, methylol compounds, and organosilicon finishing agents have been used as finishing agents for fabrics. Water-repellent finish. [0003] However, the previous water-repellent finishing agents are gradually eliminated due to the adverse effects on fabric feel, air permeability, whiteness, poor durability and environmental factors, so people began to use low surface energy organic fluorine...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M15/233C08F212/08C08F220/68D06M101/06D06M101/32
Inventor 赵涛郑俊芝
Owner DONGHUA UNIV
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