The invention discloses a sterilization and smoke suppression halogen-free wood fire retardant. The sterilization and smoke suppression halogen-free wood fire retardant is composed of, by mass, 40-80 parts of guanyl urea phosphate, 30-50 parts of urea, 10-20 parts of zinc borate, 5-10 parts of ammonium molybdate, 3-10 parts of pentaerythritol, 1-20 parts of ammonium dihydrogen phosphate, 12-25 parts of silica sol, 3-15 parts of decabromodiphenyl ether, 5-10 parts of fatty alcohol-polyoxyethylene ether, 1-20 parts of hexadecyltrimethoxysilane, and 1-20 parts of nanometer titania modified by one of Pt, Ag and Fe<3+>. The sterilization and smoke suppression halogen-free wood fire retardant is good in flame retardant property, high in anti-moisture absorption property and leaching resistance, good in stability, completely non-poisonous and low in cost and has the smoke suppression and sterilization effects.