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Composite membrane support and composite membrane using same

A composite membrane and support technology, applied in membrane technology, semi-permeable membrane separation, textile, etc., can solve the problems of unevenness, uneven area weight, unevenness, etc., and achieve high adhesion and high thermal adhesion , The effect of low crystallinity

Inactive Publication Date: 2014-10-08
ASAHI KASEI KK +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, although this non-woven fabric is not easy to produce fluff that can cause membrane defects called Cut & Slit, it can be fully suitable as a support for precision filtration membranes and ultrafiltration membranes, but there are still problems as follows: when used as a composite membrane In the case of a support, local defects tend to occur and there is unevenness in desalination performance
However, due to the melting and bonding of low melting point components, local thinning parts will occur, and the uniformity of coating cannot be satisfied, and the dimensional stability at high temperature is insufficient.
[0015] Similarly, in the pamphlet of International Publication No. 2009 / 017086, it is also proposed to use a laminated nonwoven fabric of a sheath-core structure using a low-melting point component for the sheath and a high-melting point component for the core as a membrane support. solid, but insufficient in terms of resinization of low melting point components and dimensional stability at high temperatures
In addition, as a single-component support nonwoven fabric of PET that does not contain low-melting point components and exhibits the tensile strength necessary for a film support and the adhesiveness of surface fibers, it is disclosed that the single Spunbond web (Spunbond web) is a support non-woven fabric obtained by thermocompression bonding; but because it is a single layer, it is prone to inhomogeneity caused by uneven weight per unit area of ​​spunbond and local high weight per unit area. Partial over-crimping leads to thinning, which is not satisfactory

Method used

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  • Composite membrane support and composite membrane using same
  • Composite membrane support and composite membrane using same
  • Composite membrane support and composite membrane using same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0165] (Manufacture of Composite Membrane Support)

[0166] As the surface layer (coated surface of the composite membrane solution), polyethylene terephthalate was used as the thermoplastic resin and the filament group was extruded toward the moving wire surface at a spinning temperature of 300° C. by the spunbonding method to spun Spinning at a speed of 4000m / min, a fiber with a diameter of 11μm and a weight per unit area of ​​31.3g / m was produced on the catch net 2 thermoplastic long fiber web. Next, using polyethylene terephthalate as the intermediate layer, the spinning temperature was 300°C and the heating air was 1000Nm by the melt-blowing method. 3 Spinning under the condition of / hr / m, the average fiber diameter is 1.6μm, and the weight per unit area is 7.4g / m 2 A layer of meltblown fibers was blown onto the spunbond-based thermoplastic long fiber web described above. Further, by the same method as the original thermoplastic long fiber web, the fiber diameter of 12...

Embodiment 2

[0178] Set the diameter of the melt-blown fiber to 1.7 μm and the weight per unit area to 8.2 g / m 2 , set the spunbond unit area weight of the surface and inner layers to 31g / m 2 , except that, a composite membrane support was produced by the same method as in Example 1. A polyamide composite reverse osmosis membrane and a spiral composite reverse osmosis membrane element were fabricated using the obtained composite membrane support and using the same method as in Example 1.

[0179] The properties of the obtained composite membrane support body, polyamide composite reverse osmosis membrane, and spiral composite reverse osmosis membrane element are shown in Table 1 and Table 2 together.

Embodiment 3

[0181] A composite membrane support was produced by the same method as in Example 1 except that the diameter of the melt blown fiber was 1.5 μm. A polyamide composite reverse osmosis membrane and a spiral composite reverse osmosis membrane element were fabricated using the obtained composite membrane support and using the same method as in Example 1.

[0182] The properties of the obtained composite membrane support body, polyamide composite reverse osmosis membrane, and spiral composite reverse osmosis membrane element are shown in Table 1 and Table 2 together.

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Abstract

The purpose of the invention of the present application is to provide a composite membrane support formed by dry thermoplastic long fiber non-woven fabric, and a high-performance composite membrane and composite membrane element using it. The composite membrane support has the ability to be formed on Extremely high uniformity of the porous layer without defects such as offset and pinholes during film formation, no defects in the skin layer when forming the skin layer, and excellent mechanical strength and dimensional stability at high temperatures. The composite film support of the invention of the present application is characterized in that it is a laminated dry thermoplastic long fiber of more than three layers comprising at least a melt-blown fiber layer in the middle layer and a spunbond fiber layer on both sides of the middle layer. For non-woven fabrics, the average value of the air resistance is 2.0 to 30.0 kPa·s / m, and the ratio of the average value to the standard deviation of the air resistance is 0.6 or less.

Description

technical field [0001] The present invention relates to a separation membrane support, a method for producing the same, a separation membrane and a separation membrane element using the separation membrane support. More specifically, the present invention relates to a composite membrane support formed by laminating dry-type thermoplastic long-fiber non-woven fabrics with excellent mechanical strength and uniformity, a manufacturing method thereof, a composite membrane using the composite membrane support, and a composite membrane element , the composite membrane support is particularly preferably used for reverse osmosis membranes, nanofiltration membranes, ultrafiltration membranes, gas separation membranes, etc., comprising a skin layer and maintaining a porous layer of the skin layer and reinforcing the skin layer and the porous layer Supported composite membranes. Background technique [0002] Membrane separation technology is widely used in the desalination of river wa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D69/10B01D69/12B01D63/10B01D71/48B01D71/56B01D71/68B32B5/26D04H3/02D04H3/16D04H3/009B01D63/00D04H1/559D04H3/14
CPCB32B2250/40B32B2255/26B32B2305/28B01D69/12B32B5/022D04H3/14B32B2305/20B32B2262/0284B32B2262/0276B32B2250/03B32B2250/20B32B2307/726B32B2305/026B32B2255/02D04H1/559Y10T442/609B32B5/26Y10T442/66D04H3/02B01D63/10B32B2255/28B01D69/10Y02A20/131B01D69/1216B01D69/1071B01D63/101B01D71/68B01D71/56B01D2239/0622B01D2239/0627B01D2239/0618
Inventor 吉田实上野郁雄松尾则尚石塚浩敏藤冈宏树西美咏子
Owner ASAHI KASEI KK
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