Synthesis method for liquid phenolic ester type antioxidants
A technology of antioxidant and synthesis method, applied in chemical instruments and methods, preparation of organic compounds, additives, etc., can solve the problems of unsustainable antioxidant effect, low thermal weight loss temperature, unsuitable use, etc., and achieves obvious antioxidant effect. Good biodegradability and good environmental protection effect
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Examples
Embodiment 1
[0017] Weigh 15g of tripentaerythritol industrial product (the mass fraction of tripentaerythritol is 80%, and dipentaerythritol 20%) and 12.25g of β-3,5-di-tert-butyl-4-hydroxyphenylpropionic acid are placed in a mixer with an electric stirrer and a thermometer. , water separator and condenser in a 250mL three-necked flask, then add 1.5% tin protochloride by catalyst mass fraction, 70mL xylene as a solvent, control the temperature at 120°C, react for 5h, cool to room temperature, and obtain A mixture of compounds and toluene;
[0018] Then add 38.88g of heptanoic acid as a unit fatty acid, control the temperature at 168°C, react for 6.5h, and cool to room temperature;
[0019] Wash with distilled water until neutral, and then distill off water, xylene and excess heptanoic acid under reduced pressure to obtain a clear, light-colored, easy-flowing liquid phenolic ester antioxidant with an acid value of 0.15 mgKOH / g.
Embodiment 2
[0021] Weigh 15g of tripentaerythritol industrial product (the mass fraction of tripentaerythritol is 50%, dipentaerythritol 30%, pentaerythritol 20%) and 16.60g of β-3,5-di-tert-butyl-4-hydroxyphenylpropionic acid are placed in the belt Add catalyst (mass fraction) 1.0% p-toluenesulfonic acid to a 250mL three-necked flask with electric stirring, thermometer, water separator and condenser, then add 80mL toluene as a solvent, control the temperature at 110°C, react for 4 hours, and cool to room temperature , to obtain a mixture of compounds containing antioxidant groups and toluene;
[0022] Then add 46.65 g of octanoic acid as a unit fatty acid, control the temperature at 173° C., react for 7.5 hours, and cool to room temperature;
[0023] Wash with distilled water until neutral, then distill off water, toluene and excess octanoic acid under reduced pressure to obtain a clear, light-colored, easy-flowing liquid phenolic ester antioxidant with an acid value of 0.18 mgKOH / g.
Embodiment 3
[0025] Weigh 15g of tripentaerythritol industrial product (67% of tripentaerythritol, 24% of dipentaerythritol, and 9% of pentaerythritol in mass fraction) and 14.21g of β-3,5-di-tert-butyl-4-hydroxyphenylpropionic acid into the belt Add a catalyst (mass fraction) 0.3% p-toluenesulfonic acid to a 250mL three-necked flask with an electric stirrer, a thermometer, a water separator and a condenser, then add a solvent of 70mL benzene, control the temperature at 120°C, react for 5 hours, and cool to room temperature , to obtain a mixture of compounds containing antioxidant groups and benzene;
[0026] Then add 74.18 g of isohexadecanic acid as a unit fatty acid, control the temperature at 180°C, react for 8 hours, and cool to room temperature;
[0027] Wash with distilled water until neutral, then distill off water, benzene and excess isohexadecanoic acid under reduced pressure to obtain a clear, light-colored, easy-flowing liquid phenolic ester antioxidant with an acid value of 0....
PUM
Property | Measurement | Unit |
---|---|---|
acid value | aaaaa | aaaaa |
acid value | aaaaa | aaaaa |
acid value | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com