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Method for processing coal bed methane (CBM) associated water through iron carbon microelectrolysis-reverse osmosis combination technology

A technology of iron-carbon micro-electrolysis and combined process, which is applied in infiltration/dialysis water/sewage treatment, chemical instruments and methods, water/sewage multi-stage treatment, etc., to achieve stable operation, good effluent quality, and many pretreatment units.

Inactive Publication Date: 2013-06-05
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is no literature report on the use of iron-carbon micro-electrolysis process alone or as a reverse osmosis pretreatment process for the treatment of high-salinity coalbed methane associated water.

Method used

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  • Method for processing coal bed methane (CBM) associated water through iron carbon microelectrolysis-reverse osmosis combination technology

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The analysis results of various indicators of the used coalbed methane associated water (raw water) are shown in Table 1.

[0025] First adjust the raw water with 15% sulfuric acid to make the pH 6.0, add 2000g of reduced iron powder and 1000g of activated carbon with a particle size of 1-2mm to the 25L water sample, stir well, react at room temperature for 60min, and filter. Feed the treated water into the storage tank (2);

[0026] Through the self-priming pump (3), it enters the activated carbon filter element (4) to absorb chlorine and chlorine by-products, etc., and then enters the fiber filter element (5) with a filter aperture of 1 μm to remove the carbon powder leaked from the activated carbon, and further remove more than The 1 μm suspended matter flows into the reverse osmosis membrane device (6), and the effluent enters the storage tank (7) for reuse.

[0027] The activated carbon filter element is an Aprilia brand 50A-T33 granular activated carbon filter el...

Embodiment 2

[0036] The raw water used is the same as in Example 1, and the coalbed methane associated water is adjusted to a pH of 5.5 with sulfuric acid with a mass fraction of 10%. Add 2000g of reduced iron powder and 1000g of activated carbon with a particle size of 1-2mm in a 25L water sample and stir evenly , in which iron scraps are produced in mechanical processing plants, soaked in 10% lye at 80°C to remove surface oil stains, then soaked in 10% hydrochloric acid solution to remove surface oxides, and then rinsed with deionized water . After the iron-carbon micro-electrolysis system reacts at room temperature for 90 minutes, the effluent is filtered and then enters the reverse osmosis system. Other steps and used reverse osmosis device are with embodiment 1. The results of effluent water quality after treatment by iron-carbon micro-electrolysis-reverse osmosis combined process are shown in Table 2.

[0037] Table 2 Water quality analysis results before and after iron-carbon micr...

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Abstract

The invention provides a method for processing CBM associated water through an iron carbon microelectrolysis-reverse osmosis combination technology. According to the method, iron carbon microelectrolysis is adopted to preprocess high salinity CBM associated water to reduce the TDS (total dissolved solids) and the turbidity of the high salinity CBM associated water, the CBM associated water which reaches inlet water requirements by a reverse osmosis membrane processing system enters the reverse osmosis membrane system and is processed again, so water processed by the reverse osmosis membrane system, which reaches Emission Standard for Pollutants from Coal Industry (GB20426-2006) in China and also reaches Miscellaneous Domestic Water Quality Standard (CJ / T48-1999) in China, can be directly discharged or used as miscellaneous water for local residents. So, the processing process flow is simplified, and the investment cost is reduced. The method has the advantages of simple process flow and low investment cost.

Description

technical field [0001] The invention relates to the field of environmental protection, in particular to a treatment method for coalbed methane associated water. Background technique [0002] Coalbed methane is a high-efficiency and clean energy with abundant reserves in my country. The development process of coalbed methane is generally divided into three stages: exploration, trial production and mining. In each stage, associated water will be produced. Generally, the associated water of coalbed methane must be extracted from the well. Water up to 6 months, maybe even longer. The water associated with coalbed methane generally contains a large amount of monovalent metal ions, and the salinity is very high. The total dissolved solids (TDS) is generally above 1000mg / L. If it is discharged randomly, it will cause soil salinization, compaction, and desertification. Coalbed methane associated water belongs to mine wastewater. It is a pollution source with industry characteristics...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/06C02F1/44
Inventor 刘研萍王斌李秀金刘新春
Owner BEIJING UNIV OF CHEM TECH