Lanthanum-hexaboride-reinforced aluminum-silicon-base composite material and preparation method thereof

A technology of lanthanum hexaboride and composite materials, which is applied in the field of aluminum-silicon-based composite materials and its preparation, can solve the problems of complex process, difficult control of reaction process, restricted application, etc., and achieves excellent mechanical properties, high production efficiency, and clean surface. Effect

Active Publication Date: 2012-07-04
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, there have been many reports on the research on particle-reinforced Al-Si matrix composites at home and abroad, such as [Banqiu Wu, Ramana G.Reddy. In-situ formation of SiC-reinforced Al-Si alloy composites using Methane gas mixtures.Metallurgical and Materials Transaction B.2002, 33(4):543-550] reported a silicon carbide particle-reinforced aluminum-silicon matrix composite material and its preparation method, but the process is extremely complicated and the reaction process is difficult to control, which is not conducive to large-scale production; The Chinese patent No. 99114272.1 reports a titanium carbide-enhan

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] (1) Prepare the required raw materials according to the following mass percentages: 60.96% industrial pure aluminum, 5.00% industrial crystalline silicon, 32.00% aluminum-boron alloy, 2.04% industrial pure lanthanum; wherein, in the aluminum-boron alloy The mass percentage of boron is 3.00%.

[0017] (2) Put industrial pure aluminum, industrial crystalline silicon and aluminum-boron alloy in a melting furnace to melt and raise the temperature to 800° C., and keep it warm for 5 minutes.

[0018] (3) Adding commercially pure lanthanum to the melt, reacting in situ for 10 minutes, refining and pouring, the aluminum-silicon-based composite material reinforced with lanthanum hexaboride particles can be obtained.

[0019] The composition of the composite material prepared by this method is: Al-5%Si-3%LaB 6 .

Embodiment 2

[0021] (1) Prepare the required raw materials according to the following mass percentages: 14.58% industrial pure aluminum, 13.00% industrial crystalline silicon, 65.60% aluminum-boron alloy, 6.82% industrial pure lanthanum; wherein, in the aluminum-boron alloy The mass percentage of boron is 5.00%;

[0022] (2) Melting industrial pure aluminum, industrial crystalline silicon and aluminum-boron alloy in a smelting furnace and raising the temperature to 1000°C for 10 minutes;

[0023] (3) Adding commercially pure lanthanum to the melt, reacting in situ for 15 minutes, refining and pouring, the aluminum-silicon-based composite material reinforced with lanthanum hexaboride particles can be obtained.

[0024] The composition of the composite material prepared by this method is: Al-13%Si-10%LaB 6 .

Embodiment 3

[0026] (1) Prepare the required raw materials according to the following mass percentages: 36.84% industrial pure aluminum, 20.00% industrial crystalline silicon, 39.75% aluminum-boron alloy, 3.41% industrial pure lanthanum; wherein, in the aluminum-boron alloy The mass percentage of boron is 4.00%;

[0027] (2) Melting industrial pure aluminum, industrial crystalline silicon and aluminum-boron alloy in a smelting furnace and raising the temperature to 1200°C for 5 minutes;

[0028] (3) Adding commercially pure lanthanum to the melt, reacting in situ for 10 minutes, refining and pouring, the aluminum-silicon-based composite material reinforced with lanthanum hexaboride particles can be obtained.

[0029] The composition of the composite material prepared by this method is: Al-20%Si-5%LaB 6 .

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Abstract

The invention belongs to the field of metal materials, and relates to a lanthanum-hexaboride-reinforced aluminum-silicon-base composite material and a preparation method thereof. The composite material is composed of a matrix alloy and a reinforcing phase. The invention is characterized in that the matrix alloy contains a lanthanum hexaboride reinforcing phase which is dispersively distributed; and the composite material comprises the following components in percentage by mass: 5.00-20.00% of silicon, 0.68-6.82% of lanthanum, 0.32-3.18% of boron and the balance of aluminum. The preparation method comprises the following steps: melting technically pure aluminum, industrial crystalline silicon and aluminum-boron alloy in a smelting furnace according to certain mass ratio, heating to 800-1200 DEG C, keeping the temperature for 5-10 minutes, adding a proper amount of technically pure lanthanum into the melt, carrying out in-situ reaction for 10-15 minutes, refining, and casting, thereby obtaining the lanthanum-hexaboride-particle-reinforced aluminum-silicon-base composite material. The invention can be implemented by a common smelting technique under atmospheric conditions, has the advantages of no pollution, low cost, simple technique and high production efficiency, and is suitable for large-scale production and application.

Description

technical field [0001] The invention belongs to the field of metal materials, in particular to an aluminum-silicon-based composite material reinforced by lanthanum hexaboride and a preparation method thereof. Background technique [0002] Because of its excellent casting properties, such as small shrinkage, high fluidity, good air tightness and small thermal cracking tendency, aluminum-silicon alloy also has good mechanical properties, physical properties and cutting properties after modification. Therefore, it has a wide range of applications in aerospace, automobile industry and other fields. However, the need for energy saving and emission reduction drives the aluminum alloy material to develop in the direction of high specific strength, high specific stiffness, high temperature resistance, and fatigue resistance. Particle-reinforced metal matrix composites can combine the advantages of the matrix alloy and the reinforcing phase to improve the performance of the material...

Claims

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Application Information

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IPC IPC(8): C22C21/00C22C21/02C22C32/00C22C1/03C22C1/06
Inventor 刘相法李鹏廷王栋
Owner SHANDONG UNIV
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