Hyperbranched polytriazole formate as well as preparation method and application thereof

A technology of polytriazole formate and polymerization reaction, applied in the fields of polymer chemistry and material science, can solve the problems of affecting the biological and optoelectronic properties of polymers, difficult to remove copper catalysts, poor polymer solubility, etc. Effects of functional group compatibility, elimination of cytotoxicity, good processability
CN102585220AActive Publication Date: 2012-07-18ZHEJIANG UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ZHEJIANG UNIV
Publication Date
2012-07-18

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Abstract

The invention discloses hyperbranched polytriazole formate as well as a preparation method and application thereof. The preparation method of hyperbranched polytriazole formate comprises the following steps: firstly, synthesizing binary azide containing a tetraphenyl ethylene unit; then synthesizing a ternary ester compound containing alkynyl based on ternary alcohol and propiolic acid as raw materials; and finally, carrying out non-metal-catalytic 'click' polymerization reaction under the heating condition in a polar solvent by utilizing the azide and the alkynyl-containing ester compound soas to obtain a target polymer in high yield. The hyperbranched polytriazole formate prepared by using the method is high in 1,4-stereoregularity, good in workability and high in thermal stability, degradability, illumination patterning and aggregation-induced emission property. The invention also discloses application of hyperbranched polytriazole formate in detection of a polynitroarene explosive.
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Description

technical field

[0001] The invention relates to the fields of polymer chemistry and material science, in particular to a novel hyperbranched polytriazole formate and its preparation method and application. Background technique

[0002] In the 1960s, German chemist Rolf Huisgen first studied the 1,3-dipolar cycloaddition reaction of cyclic triazoles prepared from organic azide and alkyne compounds (Chem. Ber. 1967, 100, 2494). However, due to the slow reaction rate and the lack of stereoselectivity of the product, this reaction has not been widely used. In 2002, the Meldal and Sharpless research groups independently reported the monovalent copper salt catalyzed azide-alkynyl cycloaddition reaction, and found that the reaction rate was greatly accelerated, and the product was stereoselective, only generating 1,4-disubstituted 1,2,3-triazole compounds (J.Org.Chem.2002, 67, 3057, Angew.Chem., Int.Ed.2011, 40, 2004). Immediately, Sharpless et al named the reaction "click chemis...

Claims

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