Method for initiating graft polymer through ultraviolet induction on surface of glass

A technology for grafting polymers and glass surfaces, which is applied in the field of UV-induced redox-induced free radical polymerization and glass surface grafting, can solve problems such as heavy pollution, complex processes, and difficult industrialized production, and achieves less environmental pollution and operation technology. Simple, easy-to-obtain results

Inactive Publication Date: 2012-10-03
CHANGZHOU UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The purpose of the present invention is to provide a method for grafting polymer chains on the surface of glass, which adopts simple technology, cheap and easy-to-obtain raw materials, and adopts ultravio

Method used

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  • Method for initiating graft polymer through ultraviolet induction on surface of glass
  • Method for initiating graft polymer through ultraviolet induction on surface of glass
  • Method for initiating graft polymer through ultraviolet induction on surface of glass

Examples

Experimental program
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Effect test

Embodiment 1

[0049] Disperse 0.05g of benzophenone and 1g of DMAAm in 10g of acetone to make a reaction solution, then evenly coat the reaction solution on the surface of the glass sheet treated by the method of step (1), and put it into a UV curing machine After irradiating for 3 minutes, a glass sheet sample with PDMAAm grafted on the surface was prepared. In step (1), the mass percent concentration of KH-550 in the PAAm aqueous solution is 1%, and the mass percent concentration in the PAAm aqueous solution is 0.05%. analyzed by infrared spectroscopy, the Figure 11 It can be seen that at 2930cm -1 、1610cm -1 and 1400cm -1 Appears Nearby - CH 3 , C=O and C-N characteristic peaks, indicating that PDMAAm has been successfully grafted onto nano-SiO 2 superior. Depend on Figure 12 It can be seen that the contact angle between the surface of the glass sheet sample grafted with PDMAAm and water is 78.14°. The measured mass of the glass sheet before the reaction was 0.7865g, the mass o...

Embodiment 2

[0051] Disperse 0.05g of benzophenone and 1g of AAm in 10g of acetone to make a reaction solution, then evenly coat the reaction solution on the surface of the glass sheet treated by the method of step (1), and put it into a UV curing machine After irradiating for 3 minutes, a glass sheet sample with PAAm grafted on the surface was prepared. In step (1), the mass percent concentration of KH-550 in the PAAm aqueous solution is 2%, and the mass percent concentration in the PAAm aqueous solution is 0.1%. analyzed by infrared spectroscopy, the Figure 13 It can be seen that at 1650cm -1 and 1450cm -1 The characteristic peaks of C=O and C-N appear nearby, indicating that PAAm has been successfully grafted onto nano-SiO 2 superior. Depend on Figure 14 It can be seen that the contact angle between the surface of the glass sheet sample grafted with PAAm and water is 55.78°. The mass of the glass sheet before the reaction was 0.8025g, the mass of the glass sheet after the reacti...

Embodiment 3

[0053] Disperse 0.05g of benzophenone and 1g of DMAPS in 10g of acetone / water mixed solution to make a reaction solution, and then apply the reaction solution evenly on the surface of the glass sheet treated by the method of step (1), and put it into the ultraviolet Irradiate in a light curing machine for 3 minutes to prepare a glass sheet sample grafted with PDMAPS on the surface. In step (1), the mass percent concentration of KH-550 in the PAAm aqueous solution is 3%, and the mass percent concentration in the PAAm aqueous solution is 0.15%. analyzed by infrared spectroscopy, the Figure 15 It can be seen that at 1720cm -1 and 1480cm -1 The characteristic peaks of C=O and ammonium ions on the ester group appear nearby, indicating that PDMAPS has been successfully grafted onto nano-SiO 2 superior. Depend on Figure 16 It can be seen that the contact angle between the surface of the glass sheet sample grafted with PDMAPS and water is 45.87°. It is measured that the mass o...

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Abstract

The invention relates to a method for initiating a graft polymer through ultraviolet induction on the surface of glass, belonging to the technical field of surface modification of the glass. The method comprises the following steps of: uniformly coating a prepared reaction solution on the surface of the glass treated by a silane coupling agent, and placing the glass in an ultraviolet light curing machine to irradiate the glass for 3min, thereby obtaining a sheet glass sample, the surface of which is fixed with a polymer chain. The method has the advantages that an operating technology is simple, the grafting effect is obvious, and raw materials used are commercially available, can be used without needing to be subjected to a complex purification process and are low in cost and easily obtained; graft polymerization is initiated through ultraviolet induction, the operation is simple, the reaction time is short, and the environmental pollution is low; and the method can be used for the reinforcement of adhesive property between resin in a reinforced material and the glass and the modification of the surface character of the glass and has wide industrial application prospect.

Description

technical field [0001] The invention belongs to the technical field of glass surface modification, relates to a glass surface grafting method, in particular to a method for initiating free radical polymerization and grafting polymer chains on the glass surface through ultraviolet-induced redox. Background technique [0002] Graft polymerization modification on the surface of inorganic materials can produce many new properties, such as amphiphilicity, chemical activity, dispersibility, adsorption and compatibility. Silicon-based materials, such as glass, nano-SiO 2 etc. Due to its excellent performance and relatively low price, it has become the preferred matrix for the preparation of polymer / inorganic hybrid composites. [0003] At present, the grafting techniques reported in domestic and foreign literature mainly include: (1) grafting by atom transfer radical polymerization (ATRP). Bottcher et al. (Buttcher H, Hallensleben M L. ATRP grafting from silica surface to create ...

Claims

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Application Information

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IPC IPC(8): C03C17/28
Inventor 陈肖博葛伟禹周永生翟光群
Owner CHANGZHOU UNIV
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