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Preparation method of special polyethylene anti-seepage composite hot-melt adhesive for geotextile

A technology of anti-seepage geotextile and hot-melt adhesive, which is applied in the direction of graft polymer adhesive, adhesive, adhesive type, etc., and can solve problems such as polyethylene anti-seepage geotextile hot-melt adhesive that is not mentioned

Active Publication Date: 2014-05-21
SHANGHAI TIANYANG HOT MELT ADHESIVE CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But none of the above-mentioned patents mentions hot melt adhesives for polyethylene impermeable geotextiles

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Accurately weigh 20.0g of low-density polyethylene with a melt index of 26.6g / 10min, 120.0g of water, 10.0g of xylene, and 0.16g of alkylphenol polyoxyethylene ether OP-100.16g, and add them to a three-necked flask with a reflux tube and a stirrer. , under nitrogen protection, stirred and heated to 80 °C for 2 h, then heated to 90 °C, added maleic anhydride 7.0 g, dibenzoyl peroxide 0.5 g and N,N-dimethylformamide 1.5 g, stirred and refluxed The reaction was stopped after 4 h of reaction. The obtained product was filtered, washed with water and dried. After NMR analysis and test, the graft ratio of maleic anhydride was 6.12%. The product was blended with JCC-115 type copolyester hot melt adhesive powder with a melt index of 30g / 10min / 160℃ in a mass ratio of 4.5:1 , obtain composite hot melt adhesive, use the obtained hot melt adhesive to bond non-woven fabric and PE film, and carry out peel strength test with reference to ministerial standard FZ / T01085-20000, and its p...

Embodiment 2

[0020] Accurately weigh 20.0 g of low-density polyethylene with a melt index of 22.2 g / 10min, 160.0 g of water, 8.5 g of xylene and 200.14 g of polysorbate, and add them to a three-necked flask with a reflux tube and a stirrer, under nitrogen protection. The temperature was raised to 75°C for 1.5h under stirring, and then heated to 95°C, and then 6.5g maleic anhydride, 0.6g dibenzoyl peroxide and 1.6g N,N-methylacetamide were added, and the reaction was stopped after stirring and refluxing for 3.5h. reaction. The obtained product was filtered, washed with water and dried. After NMR analysis and test, the graft ratio of maleic anhydride was 5.37%. The product was blended with JCC-116 type copolyester hot melt adhesive powder with a melt index of 24g / 10min / 160°C in a mass ratio of 5.0:1. , obtain composite hot melt adhesive, use the obtained hot melt adhesive to bond non-woven fabric and PE film, and carry out peel strength test with reference to ministerial standard FZ / T01085-...

Embodiment 3

[0022] Accurately weigh 20.0 g of low-density polyethylene with a melt index of 26.6 g / 10min, 100.0 g of water, 7.0 g of xylene and 200.12 g of sorbitan stearate and add them to a three-necked flask with a reflux tube and a stirrer, Under nitrogen protection, the temperature was stirred and heated to 70 °C for 2.0 h, then heated to 85 °C, and then 3.5 g of maleic anhydride, 0.2 g of dibenzoyl peroxide and 1.8 g of N,N-dimethylacetamide were added, and the reaction was stirred and refluxed. The reaction was stopped after 3.0h. The obtained product was filtered, washed with water and dried. After NMR analysis and test, the graft ratio of maleic anhydride was 4.47%. The product was blended with JCC-115 type copolyester hot melt adhesive powder with a melt index of 30g / 10min / 160℃ in a mass ratio of 4.0:1 , a composite hot-melt adhesive was obtained, the obtained hot-melt adhesive was used to bond the non-woven fabric and the PE film, and the peel strength was tested with referenc...

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Abstract

The invention discloses a preparation method of a special polyethylene anti-seepage composite hot-melt adhesive for geotextile, which comprises the following steps: adding low-density polyethylene, dimethylbenzene, water and a nonionic surfactant into a three-neck flask provided with a stirrer and a reflex condenser, heating to 70-80 DEG C to carry out swelling for 1-2 hours in a nitrogen protective atmosphere, heating to 85-95 DEG C, adding maleic anhydride, dibenzoyl peroxide and a crosslinking inhibitor, refluxing to react for 2-4 hours, stopping heating, cooling to room temperature, and carrying out vacuum filtration to obtain the maleic-anhydride-modified low-density polyethylene of which the grafting ratio is 3-7%; and proportionally mixing the obtained product with a copolyester hot-melt adhesive to obtain the special polyethylene anti-seepage composite hot-melt adhesive for geotextile. The hot-melt adhesive has the characteristic of high peel strength and is convenient to use.

Description

technical field [0001] The invention relates to a preparation method of a modified polyolefin / polyester composite hot-melt adhesive, which is particularly suitable for the bonding of polyethylene anti-seepage geotextiles. Background technique [0002] Anti-seepage geotextile, also known as composite geomembrane, is a geotechnical anti-seepage material composed of plastic film as the anti-seepage base material and non-woven fabric. Its anti-seepage performance mainly depends on the anti-seepage performance of the plastic film. At present, the plastic films used in anti-seepage applications at home and abroad mainly include polyvinyl chloride (PVC) and polyethylene (PE), which are a kind of polymer chemical flexible material with small specific gravity, strong extensibility, high adaptability to deformation, corrosion resistance, resistance to Low temperature, good frost resistance. The non-woven fabric is also a kind of polymer short fiber chemical material. It has high tens...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J151/06C09J167/00C08F255/02
Inventor 曾作祥周文李哲龙朱万育杨志红周义行
Owner SHANGHAI TIANYANG HOT MELT ADHESIVE CO LTD