Hydrocracking catalyst and preparation method thereof
A hydrocracking and catalyst technology is applied in the field of zeolite-containing hydrocracking catalyst and its preparation, which can solve the problems of low heavy naphtha selectivity, different catalyst performance, low catalyst activity and the like, and achieves moderate pore size, Reduced cell constant and high medium oil selectivity
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Embodiment 1
[0029] A preparation process of a modified composite molecular sieve is:
[0030] (1) Take 20 grams of NaY molecular sieves and place them in a 500 ml beaker, add 200 ml of ammonium nitrate solution with a mass fraction of 10%, heat up to 90°C under stirring, keep the temperature at a constant temperature for 2 hours, filter, wash, and dry at 110°C 2 hours, and then put it into a muffle furnace to program the temperature to 550° C., roast for 4 hours, repeat the above operation twice, and modify the molecular sieve product, coded as A.
[0031] (2) Get 10 grams of molecular sieve A and place it in a 250 milliliter three-necked bottle, add 100 milliliters of concentration to be 5w% (NH 4 ) 2 SiF 6 The aqueous solution was heated to 90°C under stirring, and kept at a constant temperature for 4 hours. The product was filtered, washed, dried at 110°C for 2 hours and calcined at 550°C for 2 hours to obtain a modified molecular sieve product, coded as B.
[0032](3) Take 20 grams...
Embodiment 2
[0036] (NH in step (2) 4 ) 2 SiF 6 The concentration of the aqueous solution was changed to 8wt%, and the rest of the preparation process was the same as in Example 1.
Embodiment 3
[0038] In step (4), 1mol / L phosphoric acid solution and 1mol / L lanthanum chloride solution are used to impregnate and modify the molecular sieve, wherein the pH of the impregnation solution is adjusted to 6-8, and the rest of the preparation process is the same as in Example 1.
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