Azobenzene polymer surface undulation grating photoetching machine based on guided mode interference

A technology of azobenzene and polymers, applied in the field of lithography machines, can solve the problems of long exposure time, high cost, complicated process, etc., and achieve the effects of reduced exposure time, short exposure time and simple optical path

Inactive Publication Date: 2014-12-10
UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1. The depth of the grating is shallow. Since the penetration depth of the surface plasmon wave is very small, it is difficult to write a deep sub-wavelength grating, which affects the application of the grating
[0004] 2. The excitation light has a single polarization mode. In maskless surface plasmon subwavelength lithography, only TM polarized light can excite surface plasmon waves, while TE polarized light cannot excite surface plasmon waves.
[0005] 3. The photolithography process is complicated: the maskless surface plasma lithography technology of traditional photoresist is used. After exposure, chemical treatment processes such as developing and fixing are required in the darkroom. The process is complicated and time-consuming. If one of the links goes wrong , you need to start over
[0006] 4. The cost is high. Based on surface plasmon lithography technology, the light source is mostly ultraviolet light. The price of ultraviolet light source is obviously higher than that of visible light band light source.
[0007] 5. The exposure time is long. When the azobenzene polymer film is used as the lithography medium, although the process can be simplified, but because the light field is mainly distributed at the interface between the metal and the azobenzene polymer, the required exposure time is longer

Method used

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  • Azobenzene polymer surface undulation grating photoetching machine based on guided mode interference
  • Azobenzene polymer surface undulation grating photoetching machine based on guided mode interference
  • Azobenzene polymer surface undulation grating photoetching machine based on guided mode interference

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Embodiment 1

[0039] refer to figure 1 An azobenzene polymer surface relief grating lithography machine based on guided mode interference is shown, including: a laser light source 1, a photoelectric shutter 2, a short focal length lens 3, a long focal length lens 4, a half-wave plate 5, and a polarizer 6. Beam splitter 7, plane mirror A8, plane mirror B9, prism 10, matching oil 11, glass substrate 12, metal film 13, azobenzene polymer film 14, optical waveguide parameter measuring instrument 15; wherein, in A metal thin film 13 (25nm silver film) is vapor-deposited on the glass substrate 12, and then spin-coated with an azobenzene polymer cyclopentanone solution to obtain a 208nm thick azobenzene polymer film 14, and the glass substrate is coated with matching oil 11 12 is bonded with the prism 10, and placed in the center of the optical waveguide parameter measuring instrument 15. The polarizing direction of the polarizer 6 is adjusted to the horizontal direction to generate TM polarized ...

Embodiment 2

[0041] By changing the thickness of the azobenzene polymer film and the excited guided wave mode, the writing of subwavelength gratings with different periods can be realized. When the thickness of the azobenzene polymer film is 100nm, the polarization direction of the polarizer 6 is in the vertical direction, and the excitation angle of the excited TE1 mode is measured to be 52.8° under low-intensity laser conditions. The grating period of the subwavelength azobenzene polymer surface relief grating written under the conditions is 189nm, and its atomic force microscope photo is shown in Figure 4 .

[0042] Other structures are with embodiment 1.

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Abstract

The invention discloses an azobenzene polymer surface undulation grating photoetching machine based on guided mode interference. The azobenzene polymer surface undulation grating photoetching machine comprises a laser light source, a photoelectric shutter, a lens, a half wave plate, a polarizer, a beam splitter, a plane reflector, a prism, matched oil, a glass substrate, a metal film, an azobenzene polymer film and an optical waveguide parameter measuring instrument. Light emitted from the laser light source is subjected to beam expansion, passes through the half wave plate and the polarizer to form needed polarized light and is split into two beams with same intensity after passing through the beam splitter; after being reflected by the plane mirror, the two beams of light irradiate the metal film with a same guided mode excitation angle and further excite guided modes in a multi-layer structure; and interference between the guided modes of the two beams of light causes mass transfer of an azobenzene polymer, so that a sub-wavelength surface undulation grating is etched. The photoetching machine based on a guided mode interference field and the azobenzene polymer film realizes etching of the large-area sub-wavelength surface undulation grating, and is short in photoetching time, simple in technology and free from developing and fixing; and the etched grating is erasable and reconfigurable.

Description

technical field [0001] The invention relates to the technical field of lithography machines in the field of micro-nano processing such as microelectronics and optoelectronic device preparation, and in particular to a photolithography machine for azobenzene polymer surface relief gratings based on guided mode interference. Background technique [0002] Photolithography is a sophisticated micro-nano processing technology. The existing maskless surface plasmon subwavelength lithography technology mainly has the disadvantages of shallow writing grating depth, excitation light polarization is limited to TM polarization and so on. This lithography method has limitations in practical applications. Its main problems are: [0003] 1. The depth of the grating is shallow. Since the penetration depth of the surface plasmon wave is very small, it is difficult to write a deep sub-wavelength grating, which affects the application of the grating. [0004] 2. The excitation light has a si...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G03F7/20G02B27/09G02B27/10
Inventor 王向贤张斗国朱良富陈漪恺胡继刚王沛明海
Owner UNIV OF SCI & TECH OF CHINA
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