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Surface silanization protection treatment agent for corrosion inhibiting and resisting metal and preparation method thereof

A technology for corroding metals and metal surfaces, applied in anti-corrosion coatings, coatings, etc., can solve problems such as environmental hazards, complex processes, and unstable film formation, and achieve the effects of enhanced corrosion resistance and low polarization current density

Active Publication Date: 2013-05-08
JIANGSU LIANGYOU STEEL WIRE CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The phosphating treatment process uses ammonium dihydrogen phosphate, zinc, manganese, and nickel as the main raw materials, causing serious environmental pollution such as heavy metals, phosphorus, and nitrite, and will more or less produce sediment and harmful gases during the treatment process. It affects the normal production, and the discharged wastewater COD and heavy metals will endanger the environment if they are not treated in an environmentally friendly manner; in addition, most of the phosphating treatment needs to be carried out under heating conditions, which consumes a lot of energy, the process is complicated, and the operation is inconvenient
Silane surface treatment technology has appeared, but the film formation of silane surface treatment agent on the metal surface is unstable, the anti-corrosion performance is unstable, and the effect is not good

Method used

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Embodiment Construction

[0018] A corrosion-inhibiting and anti-corrosion metal surface silanization protective treatment agent is made of the following components, and the weight (grams) of each raw material component in every 500 grams of mixed solution is:

[0019] Ammonium Benzoate 2, Triethanolamine 1, Methylcellulose 3, Rosin 10, Trishydroxyethylisocyanurate 1.2, Maleic Anhydride 10, Diethylene Glycol Butyl Ether 4, Isopropanol 5, Phosphoric Acid Ammonium dihydrogen 1, urea 2, N-2-(aminoethyl)-3-aminopropyltrimethoxysilane 5, and the balance is deionized water.

[0020] The preparation method of described metal surface silanization protective treatment agent comprises the following steps:

[0021] (1) Heat and melt the rosin to 110-115°C, add diethylene glycol butyl ether, N-2-(aminoethyl)-3-aminopropyltrimethoxysilane, and stir for 35-50 minutes;

[0022] (2) Heat up to 145-160°C, add trihydroxyethylisocyanurate and maleic anhydride, and stir for 40-50 minutes;

[0023] (3) Continue to heat u...

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Abstract

The invention discloses a surface silanization protection treatment agent for corrosion inhibiting and resisting metal. The surface silanization protection treatment agent is prepared from the following ingredients in weight (gram) in every 500g of mixture liquid: 1-2g of benzoic acid amide, 1-2g of triethanolamine, 3-5g of methyl cellulose, 8-10g of rosin, 0.5-1.2g of trihydroxyethyl isocyanurate, 10-12g of maleic anhydride, 4-6g of diethylene glycol butyl ether, 5-8g of isopropanol, 0.5-1g of ammonium dihydrogen phosphate, 1-2g of urea, 5-8g of N-2-(aminoethyl)-3-aminopropyl trimethoxysilane and the balance of deionized water. According to the surface silanization protection treatment agent, rosin serving as a reaction raw material is polymerized with raw materials, such as maleic anhydride and silane, and then, a strong protecting film can be formed on the surface of metal; and the corrosion resistance of metallic matrixes is enhanced.

Description

technical field [0001] The invention relates to a silanization treatment agent on the metal surface and a process for silanization treatment on the metal surface. Background technique [0002] Phosphating treatment has been widely used in metal coating pretreatment, lubrication, antirust and other industries. Especially in the coating pretreatment industry, phosphating treatment is one of the most commonly used pretreatment methods. Phosphating treatment is a process in which a protective film of ammonium dihydrogen phosphate is formed on the surface of a metal after reacting in an acidic ammonium dihydrogen phosphate solution. Phosphate film also has good lubricity, insulation and corrosion resistance, so it is widely used in the manufacturing fields of automobiles, machinery manufacturing, aerospace and household appliances. The phosphating treatment process uses ammonium dihydrogen phosphate, zinc, manganese, and nickel as the main raw materials, causing serious environ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D4/06C09D7/12C09D5/08
Inventor 夏坤财
Owner JIANGSU LIANGYOU STEEL WIRE CO LTD
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