Organic waste gas adsorbent and preparation method thereof
A technology of organic waste gas and adsorbent, which is applied in the direction of separation methods, chemical instruments and methods, and other chemical processes, can solve the problems of inability to selectively adsorb organic matter, failure to achieve separation and purification, and harsh desorption conditions. Low cost, improved adsorption capacity and treatment capacity, high adsorption capacity effect
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Embodiment 1
[0032] Mechanically mix 90g of Y-type (silicon-aluminum ratio: 12) all-silicon molecular sieve and 2g of graphene, add 8g of halloysite powder while stirring, after mechanical mixing for 30 minutes, add 5g of methylcellulose pore expander and mix well , then dropwise add 100mL of dilute nitric acid peptizer with a concentration of 5wt%, stir until it is semi-dry, and shape it into a honeycomb ceramic carrier. Get the adsorbent of the present invention.
[0033] The adsorption capacity of the above-mentioned adsorbent for n-hexane is as high as 43%, and the adsorption capacity for naphthalene and naphthol reaches 3.4 mmol / g.
Embodiment 2
[0035] Mechanically mix 80g of all-silicon Beta molecular sieve and 5g of graphene, add 15g of diatomaceous earth powder while stirring, after mechanical mixing for 60 minutes, add 2g of turnip powder and mix evenly, then dropwise add 80g of lemon with a concentration of 2wt%. Acid peptizer, stirred to a semi-dry state, molded into a honeycomb ceramic carrier, dried at 100°C, and then calcined at 500°C for 10 hours under argon atmosphere to obtain the adsorbent of the present invention.
[0036] The adsorption capacity of the above-mentioned adsorbent for n-hexane is as high as 43%, and the adsorption capacity for naphthalene and naphthol reaches 3.8 mmol / g.
Embodiment 3
[0038] Mix 80g of all-silicon Silicalite-1 molecular sieve and 5g of carbon nanotubes with mechanical stirring, add 15g of bentonite powder while stirring, after mechanical mixing for 60 minutes, add 2g of methylcellulose pore expander and mix evenly, and then add 80g of concentration It is 2wt% oxalic acid peptizer, stirred to a semi-dry state, and molded into a honeycomb ceramic carrier. After drying at 100°C, it is roasted at 500°C for 24h under nitrogen atmosphere to obtain the adsorbent of the present invention.
[0039] The adsorption capacity of the above-mentioned adsorbent for n-hexane is as high as 39%, and the adsorption capacity for naphthalene and naphthol reaches 3.4 mmol / g.
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