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Method for continuously coating high-viscosity sizing agent used for preparing positive pole piece of lithium-manganese primary cell

A technology of a battery positive electrode and a coating method, which is applied to the electrodes of primary batteries, devices for coating liquid on the surface, coatings, etc., can solve the problems of reduced battery performance, complicated processes, affecting production efficiency, and the quality of positive electrode pieces. Achieve high-speed coating, reduce water content, and improve production efficiency

Inactive Publication Date: 2013-10-23
中国兵器工业第二一三研究所
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  • Summary
  • Abstract
  • Description
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  • Application Information

AI Technical Summary

Problems solved by technology

Both of the above two methods have the following disadvantages: 1) Unable to work continuously and produce: the preparation process of the above two methods is discontinuous, the process is relatively complicated, and a large number of manual operations affect the production efficiency and the quality of the positive pole piece; 2) The rolling method is suitable for production Thick positive electrode sheet, and the paste method is suitable for producing thinner positive electrode sheet, but the thickness of the electrode sheet is not easy to control; 3) The rolling method needs to add graphite to increase the ductility of the sheet, which leads to a decrease in battery performance

Method used

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  • Method for continuously coating high-viscosity sizing agent used for preparing positive pole piece of lithium-manganese primary cell

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Embodiment Construction

[0014] The present invention will be further described below in conjunction with the accompanying drawings and embodiments, and the present invention includes but not limited to the following embodiments.

[0015] In the present invention, electrolytic manganese dioxide and conductive carbon black after heat treatment at 200°C-600°C for 2-20h are mixed (mixing time 0.1-10h), and then polar alcohol-containing solvents (such as ethanol, isopropanol, n-butyl alcohol, etc.) Alcohol) in deionized water or distilled water, continue to mix for 0.1-10 hours to obtain a wet mixture; then add the aqueous solution of the common binder for lithium batteries in proportion and continue to mix (mix for 0.5-60 minutes) to obtain a high-viscosity slurry. The above-mentioned electrolytic manganese dioxide, conductive carbon black and common binders for lithium batteries (for example: polytetrafluoroethylene (PTFE), sodium carboxymethylcellulose (CMC), polyvinyl alcohol (PVA), polyolefins (PP, P...

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Abstract

The invention provides a method for continuously coating a high-viscosity sizing agent used for preparing a positive pole piece of a lithium-manganese primary cell, wherein thermally treated electrolyzed manganese dioxide is mixed with a conductive black, then deionized water or distilled water containing a polar alcohol solvent is added for continuous mixing to obtain a wet mixture, then an aqueous solution of a binder commonly used by a lithium battery is added for continuous mixing to obtain the high-viscosity sizing agent, the high-viscosity mixed sizing agent is prepared into particles, is rolled by a coating roller into a continuous piece, and is bonded on the two sides of a current collector after being rolled, so that a positive pole material piece with uniform thickness is continuously prepared, and the required positive pole piece can be obtained after the processes of drying, rolling, cutting and clearing the powder. According to the method for continuously coating the high-viscosity sizing agent used for preparing the positive pole piece of the lithium-manganese primary cell, the production efficiency and the production consistency are improved, the uniformity of the thickness of the material piece is guaranteed, and the performance of the pole piece is improved.

Description

technical field [0001] The invention relates to the field of manufacturing lithium-manganese primary batteries, in particular to a method for continuously coating high-viscosity slurry for preparing positive pole pieces of lithium-manganese primary batteries. Background technique [0002] Lithium metal primary battery is one of the series with the highest specific energy among known chemical power sources, and lithium manganese primary battery is the safest one. It has a wide range of applications in the radio frequency identification technology Internet of Things, smoke alarms, and smart electronic instruments. It has high security, high reliability, high specific energy, high environmental adaptability, and good storage performance (no voltage hysteresis) ) and superior cost performance. [0003] Existing coating methods for lithium-manganese primary batteries include roll pressing and paste coating. The rolling method is to fully mix manganese dioxide, conductive agent,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B05D1/28B05C19/04B05C11/02H01M4/04H01M4/08
CPCY02E60/12
Inventor 皮正杰李节宾白宏永李磊孟庆英李军升任冰王静张宏皓
Owner 中国兵器工业第二一三研究所
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