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Barium titanate/polymer composite material with high dielectric constant and its preparation method

A technology of high dielectric constant and composite materials, which is applied in the field of high dielectric, can solve the problems of inorganic particle agglomeration, poor compatibility, and limited performance of composite materials, and achieve enhanced interface interaction, improved dielectric properties, and low dielectric properties. The effect of electrical loss

Active Publication Date: 2013-11-06
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, due to the huge difference in the surface properties of ceramics and polymers, the compatibility between the two is not good, resulting in a large amount of agglomeration of inorganic particles, which limits the further improvement of the performance of composite materials.

Method used

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  • Barium titanate/polymer composite material with high dielectric constant and its preparation method
  • Barium titanate/polymer composite material with high dielectric constant and its preparation method
  • Barium titanate/polymer composite material with high dielectric constant and its preparation method

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Embodiment 1

[0033] This embodiment relates to a barium titanate / polymer composite material with a high dielectric constant, and the composite material includes the following components in volume percentage:

[0034] Barium titanate ceramic particles 60%,

[0035] Hyperbranched Polyamide 20%,

[0036] Polymethylmethacrylate 20%,

[0037] Wherein, the relative dielectric constant of hyperbranched polyamide is 4-10, and the relative dielectric constant of polymethyl methacrylate is 3-4.

[0038] This embodiment also relates to a method for preparing a barium titanate / polymer composite material with a high dielectric constant, comprising the following steps:

[0039] Step 1, disperse 50g of barium titanate ceramic particles into 300ml of 30% hydrogen peroxide solution, heat to 120°C, stir for 1 hour, centrifuge to separate the barium titanate particles, and dry them in vacuum to obtain refined barium titanate ceramic particles;

[0040] Step 2, then disperse the refined barium titanate cer...

Embodiment 2

[0046] This embodiment relates to a barium titanate / polymer composite material with a high dielectric constant, and the composite material includes the following components in volume percentage:

[0047] Barium titanate ceramic particles 53%,

[0048] Linear Polyamide 11%,

[0049] Polymethylmethacrylate 36%,

[0050] Among them, the relative dielectric constant of linear polyamide is 4-10, and the relative dielectric constant of polymethyl methacrylate is 3-4.

[0051] This embodiment also relates to a method for preparing a barium titanate / polymer composite material with a high dielectric constant, comprising the following steps:

[0052] Step 1, disperse 100g of barium titanate ceramic particles into 500ml of 30% hydrogen peroxide solution, heat to 105°C, stir for 4 hours, centrifuge to separate the barium titanate particles, and dry them in vacuum to obtain refined barium titanate ceramic particles;

[0053] Step 2: Disperse refined barium titanate ceramic particles int...

Embodiment 3

[0059] This embodiment relates to a barium titanate / polymer composite material with a high dielectric constant, and the composite material includes the following components in volume percentage:

[0060] Barium titanate ceramic particles 1%,

[0061] Hyperbranched Amide 30%,

[0062] Polymethylmethacrylate 69%,

[0063] Wherein, the relative dielectric constant of hyperbranched polyamide is 4-10, and the relative dielectric constant of polymethyl methacrylate is 3-4.

[0064] This embodiment also relates to a method for preparing a barium titanate / polymer composite material with a high dielectric constant, comprising the following steps:

[0065] Step 1, disperse 50g of barium titanate ceramic particles into 400ml of 30% hydrogen peroxide solution, heat to 60°C, stir for 6 hours, centrifuge to separate the barium titanate particles, and dry them in vacuum to obtain refined barium titanate ceramic particles;

[0066] Step 2: Disperse refined barium titanate ceramic particles...

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Abstract

The invention discloses a barium titanate / polymer composite material with a high dielectric constant and its preparation method. The composite material comprises the following components by volume: 1-60% of a single nucleus, 3-30% of an inner shell, and 20-80% of an outer shell. The single nucleus is composed of barium titanate ceramic particles, the inner shell is polyamide with a high dielectric constant, and the outer shell is polymethyl methacrylate with a low dielectric constant. The invention also relates to a preparation method of the composite material. The method includes: firstly using amino silane to perform surface treatment on the single nucleus, introducing an organic functional group, and then dispersing different products into different monomer solutions in order, thus obtaining the composite material with the nucleus-shell-shell structure connected by covalent bonds. The composite material has the characteristics of high dielectric constant, low dielectric loss, and uniformly distributed inorganic particles. The composite material provided in the invention is suitable for preparation of embedded capacitors, high energy storage capacitors, field emission triodes and other advanced electrical and electronic equipment.

Description

technical field [0001] The invention belongs to the field of high dielectric technology, and in particular relates to a high dielectric constant barium titanate / polymer composite material and a preparation method thereof. Background technique [0002] High dielectric materials have very important applications in electronic appliances and power systems, such as embedded capacitors required by overall packaging technology, thin film transistors, cable terminals, and high-power capacitors required by some advanced weapons. Practical applications require high dielectric materials to have high dielectric constant and low dielectric loss. Traditional high-dielectric materials are mainly high-dielectric ceramics and polymers, but ceramics are easy to break down and difficult to process, and the dielectric constant of polymers is not high, so the performance needs to be further improved, so people have prepared inorganic ceramics / polymer composites . The preparation of composite m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F293/00C08G83/00
Inventor 谢礼源江平开黄兴溢黄彦辉杨科吴新锋吴超
Owner SHANGHAI JIAO TONG UNIV
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