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Environment-friendly anti-bacterial PVC (Polyvinyl Chloride) thin film

A technology of PVC film and PVC resin powder, applied in the field of polymer materials, can solve the problems of harmful plasticizers, little research on the application of PVC film, human health hazards, etc., to avoid health problems, excellent bacteriostatic and antiseptic effect, The effect of significantly inhibiting the effect

Active Publication Date: 2013-11-20
ANHUI ANYUAN PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN103102618A, a kind of TiO2Ag / PVC composite bacteriostatic film, although this patent adds modified TiO2Ag in film, makes film have good bacteriostatic performance, but still contains the plasticizer harmful to human body; Chinese patent CN102101928A, a A kind of antibacterial fresh-keeping film, although this patent has added silver ion antibacterial agent in the fresh-keeping film, so that it has antibacterial function, but wherein still contains phthalates plasticizer, and existing research shows, silver ion antibacterial agent Although it has a strong antibacterial function, it will still cause harm to human health if it is accidentally ingested into the human body
At present, lavender essential oil is widely used in the fields of medicine and daily chemicals, but there is little research on its application in PVC film

Method used

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  • Environment-friendly anti-bacterial PVC (Polyvinyl Chloride) thin film

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Environmentally friendly antibacterial PVC film, including the following raw materials in parts by mass: 90 parts of PVC resin powder, 0.1 part of lavender essential oil, 20 parts of acetyl tri-n-butyl citrate, 4 parts of calcium ricinoleate, 0.2 parts of glyceryl stearate share.

[0029] The preparation method of the lavender essential oil is as follows: weigh 20g of lavender flowers, pass through a 60-mesh sieve after crushing, place in a 250mL beaker, add 150mL of n-hexane, soak for 30min, place in an ultrasonic instrument, ultrasonicate for 60min at 40°C, and cool to room temperature , Distilled under reduced pressure, the concentrated solution is lavender essential oil.

[0030] The preparation method of the present invention: add 90 parts of PVC resin powder, 0.1 part of lavender essential oil, 20 parts of acetyl tri-n-butyl citrate, 4 parts of calcium ricinoleate and 0.2 part of glyceryl stearate into a high-speed mixer according to the parts by mass Raise the t...

Embodiment 2

[0034] The environment-friendly antibacterial PVC film comprises the following raw materials in parts by mass: 110 parts of PVC resin powder, 0.2 part of lavender essential oil, 25 parts of acetyl tri-n-butyl citrate, 8 parts of magnesium stearate, and 0.6 part of paraffin.

[0035] The preparation method of the lavender essential oil is as follows: weigh 20g of lavender flowers, pass through a 60-mesh sieve after crushing, place in a 250mL beaker, add 200mL of n-hexane, soak for 50min, place in an ultrasonic instrument, ultrasonicate for 80min at 50°C, and cool to room temperature , Distilled under reduced pressure, the concentrated solution is lavender essential oil.

[0036] The preparation method of the present invention: add 110 parts of PVC resin powder, 0.2 part of lavender essential oil, 25 parts of acetyl tri-n-butyl citrate, 8 parts of magnesium stearate and 0.6 part of paraffin into a high-speed mixer and heat up to 90 °C according to the parts by mass Stir and mix ...

Embodiment 3

[0040] Environmentally friendly antibacterial PVC film, including the following raw materials in parts by mass: 95 parts of PVC resin powder, 0.12 parts of lavender essential oil, 23 parts of acetyl tri-n-butyl citrate, 4 parts of calcium ricinoleate, and 2 parts of magnesium stearate 0.2 parts of glyceryl stearate.

[0041] The preparation method of the lavender essential oil is as follows: weigh 20g of lavender flowers, pass through a 60-mesh sieve after crushing, place in a 250mL beaker, add 180mL of n-hexane, soak for 45min, place in an ultrasonic instrument, ultrasonicate for 75min at 45°C, and cool to room temperature , Distilled under reduced pressure, the concentrated solution is lavender essential oil.

[0042] The preparation method of the present invention: mix 95 parts of PVC resin powder, 0.12 part of lavender essential oil, 23 parts of acetyl tri-n-butyl citrate, 4 parts of calcium ricinoleate, 2 parts of magnesium stearate and 0.12 part of lavender essential oil a...

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Abstract

The invention provides an environment-friendly anti-bacterial PVC (Polyvinyl Chloride) thin film. The environment-friendly anti-bacterial PVC thin film is prepared from the following raw materials in parts by weight: 90-110 parts of PVC resin powder, 0.1-0.2 part of lavender essential oil, 20-25 parts of acetyl-tri-n-butyl citrate, 4-8 parts of heat stabilizer and 0.2-0.6 part of lubricant, wherein the heat stabilizer is one or more than one of calcium ricinoleate, calcium stearate, zinc stearate or magnesium stearate, and the lubricant is one or more than one of glyceryl stearate, octadecanamide, paraffin wax and polyethylene wax. The environment-friendly anti-bacterial PVC thin film can be used for inhibiting the breeding of bacteria around the thin film. Compared with a common commercially available thin film, the environment-friendly anti-bacterial PVC thin film has an obvious inhibitory effect on trichoderma viride, escherichia coli and staphylococcus aureus. As the lavender essential oil is a natural plant extraction anti-bacterial agent, the environment-friendly anti-bacterial PVC thin film can be used for a long term and is safe and non-toxic. The acetyl-tri-n-butyl citrate and tri-n-butyl citrate are used as the plasticizers, so that the health problem caused by use of phthalic acid ester-containing plasticizer products can be effectively avoided.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to an environment-friendly antibacterial PVC film. Background technique [0002] PVC film is widely used on the surface of floors, ceilings and leather. The top layer of this surface film is paint, the main component of the middle layer is polyvinyl chloride, and the bottom layer is back-coated adhesive. Compared with ordinary veneer films, It can be tightly fused with other boards, and the glue will not be opened for ten or even fifteen years, so it is very popular and has become a widely used synthetic material. [0003] At present, the plasticizers commonly used in the industrial production of PVC films are mainly phthalates. Although this type of plasticizer has good performance, its use has been greatly restricted because of its potential carcinogenic danger. my country has also formulated relevant laws and regulations. The regulations will phase out its application...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08K5/00C08K5/11
Inventor 汤毅
Owner ANHUI ANYUAN PLASTIC
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