Preparation method of non-edible animal and plant crude oil refined oil
A technology for refining oil, animals and plants, applied in the direction of fat oil/fat refining, fat production, etc., can solve the problems that the refined oil cannot fully meet the requirements of raw material indicators, long process route, high COD value, and achieve high refining efficiency and stability. The effect of simplifying the refining process and saving production costs
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Embodiment 1
[0018] Heat 100g jatropha crude oil (phosphorus content 231ug / g, metal 165ug / g, unsaponifiable matter 0.6%, acid value 4.8mgKOH / g) to 60°C, and add at a concentration of 0.5% under stirring at 500 rpm 2.6 g of citric acid solution, stirred at constant temperature for 60 min, and then centrifuged to obtain degummed oil. The degummed oil was vacuum dehydrated under the conditions of vacuum degree 0.08MPa, temperature 90°C, time 20min, then 3.0g silica gel was added under the conditions of 90°C and 200 rpm stirring, reacted for 30min and then filtered to obtain refined oil. The phosphorus content of the product is 1.8ug / g, the metal is 4.1ug / g, the unsaponifiable matter is 0.4%, and the acid value is 4.8mgKOH / g, which meet the raw material index requirements for the preparation of bio-jet fuel / biodiesel by hydrogenation.
Embodiment 2
[0020] Mix 100g jatropha crude oil and gutter oil at a ratio of 1:1 (phosphorus content 123ug / g, metal 144ug / g, unsaponifiable matter 0.58%, acid value 6.9mgKOH / g) and heat the oil to 60°C at 500 rpm Under the condition of stirring, 3.0 g of citric acid solution with a concentration of 0.5% was added, stirred at constant temperature for 60 minutes, and then centrifuged to obtain degummed oil. The degummed oil was vacuum dehydrated under the conditions of vacuum degree 0.08MPa, temperature 90°C, time 20min, and then 3.5g of silica gel was added under the conditions of 90°C and 200 rpm stirring, reacted for 30min and then filtered to obtain refined oil. The phosphorus content of the product is 1.3ug / g, the metal is 3.5ug / g, the unsaponifiable matter is 0.44%, and the acid value is 6.9mgKOH / g, which meet the raw material index requirements for the production of bio-jet fuel / biodiesel by hydrogenation.
Embodiment 3
[0022] Mix 100g jatropha crude oil and gutter oil at a ratio of 1:1 (phosphorus content 123ug / g, metal 144ug / g, unsaponifiable matter 0.58%, acid value 6.9mgKOH / g) and heat the oil to 60°C at 500 rpm Under stirring conditions, add 2.0 g of citric acid and acetic anhydride solution with a concentration of 0.5% and a ratio of 1:1, stir at a constant temperature for 60 minutes, and then centrifuge to obtain degummed oil. The degummed oil is vacuum dehydrated under the conditions of vacuum degree 0.08MPa, temperature 90°C, time 20min, then 4.0g of activated carbon and silica gel are added under the conditions of 90°C and 200 rpm stirring, reacted for 30min and filtered to obtain refined oil. The phosphorus content of the product is 0.9ug / g, the metal is 2.9ug / g, the unsaponifiable matter is 0.35%, and the acid value is 6.9mgKOH / g, which meet the raw material index requirements for the production of bio-jet fuel / biodiesel by hydrogenation.
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