A kind of preparation method of EVA thin film surface nano-coating

A nano-coating and thin-film technology, used in conductive coatings, polyether coatings, coatings, etc., can solve the problems of accelerated aging, weakening of visible light, and yellowing of EVA film, improving photoelectric conversion rate, good adhesion, Easy to use effect

Inactive Publication Date: 2016-03-02
广东奥优涂料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to make the EVA film have a low yellowing rate and improve the high transmittance of the EVA film to visible light, thereby increasing the photoelectric conversion rate of the battery pack, three methods are usually used: the first one is to add ultraviolet light absorbers and light stabilizers , although the ultraviolet rays are shielded, the aging of the EVA film is accelerated because the energy absorbed by the ultraviolet rays is converted into heat energy; the second is to add antioxidants to eliminate the activity of the film produced by excessive cross-linking agents during use. Free radicals, because such free radicals will make the ultraviolet light absorber or (and) light stabilizer generate new compounds with chromophores, resulting in yellowing; the third is to add infrared reflective nanoparticles to the film, However, while shielding infrared rays, there is a problem that visible light is partially weakened

Method used

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  • A kind of preparation method of EVA thin film surface nano-coating

Examples

Experimental program
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Effect test

Embodiment 1

[0029] The EVA film surface nano coating of the present embodiment is made up of following components:

[0030] Carbon nanotubes 15g

[0031] Nano silica 5g

[0032] Fatty alcohol polyoxyethylene ether 3g

[0033] Silane coupling agent 3g

[0034] Propylene glycol methyl ether acetate 3g

[0035] Anhydrous ethanol 71g;

[0036] Wherein the fatty alcohol polyoxyethylene ether is used as a dispersant, the silane coupling agent is used as a binder, and the propylene glycol methyl ether acetate is used as a film-forming aid.

[0037] The preparation method of the EVA film surface nano-coating of the present embodiment comprises the following specific steps:

[0038] A. Ingredients: Weigh an appropriate amount of carbon nanotubes, nano silicon dioxide, fatty alcohol polyoxyethylene ether, silane coupling agent, propylene glycol methyl ether acetate, ethanol, water, wherein the fatty alcohol polyoxyethylene Vinyl ether is used as a dispersant, the silane coupling agent is used...

Embodiment 2

[0044] The rest of the EVA film surface nano-coating of the present embodiment is identical with embodiment 1, and difference is:

[0045] The EVA film surface nano coating of the present embodiment is made up of following components:

[0046] Carbon nanotubes 20g

[0047] Nano silica 12g

[0048] Fatty alcohol polyoxyethylene ether 10g

[0049] Silane coupling agent 3g

[0050] Propylene glycol methyl ether acetate 4g

[0051] Propanol 50g;

[0052] The rest of the preparation method of the EVA film surface nano-coating of the present embodiment is the same as that of Example 1, except that in step D, the dispersion is ultrasonically oscillated at 20-40°C for 30 minutes and diluted 2 times and applied to The surface of the EVA film is dried and cured.

Embodiment 3

[0054] The rest of the EVA film surface nano-coating of the present embodiment is identical with embodiment 1, and difference is:

[0055] The EVA film surface nano coating of the present embodiment is made up of following components:

[0056] Carbon nanotubes 19g

[0057] Nano silica 15g

[0058] Fatty alcohol polyoxyethylene ether 10g

[0059] Silane coupling agent 5g

[0060] Propylene glycol methyl ether acetate 5g

[0061] 46g of isopropanol;

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Abstract

The invention relates to a preparation method of a nano coating for an EVA (ethylene-vinyl acetate copolymer) film surface. The nano coating comprises the following components by mass percent: 15-20% of carbon nano tube, 5-15% of nano silica, 3-15% of fatty alcohol-polyoxyethylene ether, 3-5% of silane coupling agent, 3-5% of propylene glycol methyl ether acetate and 10-30% of organic solvent, wherein the mass ratio of fatty alcohol-polyoxyethylene ether to the silane coupling agent is (1:1)-(3:1); fatty alcohol-polyoxyethylene ether serves as a dispersing agent; the silane coupling agent serves as a binding agent; propylene glycol methyl ether acetate serves as a film forming aid. A film covered by a coat formed by the nano coating has electrical conductivity and low yellowing rate and simultaneously improves the photoelectric conversion rates of battery packs. The preparation method is simple in process and convenient to operate and can be used for efficiently dispersing and fixing the carbon nano tube and the silica nano tube on the EVA film surface uniformly.

Description

technical field [0001] The invention relates to a preparation method of a nano-coating on the surface of an EVA film, belonging to the technical field of organic chemistry. Background technique [0002] In the context of global warming, deterioration of the human ecological environment, and shortage of conventional energy sources, sustainable development strategies have been accepted by countries all over the world. Solar energy has the advantages of cleanliness, safety, and resource adequacy. It is one of the most important new energy sources in the 21st century and has been valued and supported by governments of all countries. In recent years, the photovoltaic market has expanded rapidly, and photovoltaic products are in short supply. [0003] At present, during the production process of solar cells, the cells need to be packaged. The properties of the encapsulation material will largely determine the performance and lifetime of the solar cell module. A good encapsulati...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D171/00C09D183/04C09D7/12C09D5/24C08J7/04
Inventor 顾正忠陈忠斌
Owner 广东奥优涂料有限公司
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