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Biomass methanol diesel oil and preparation method thereof

A biomass and methanol technology, which is applied in the petroleum industry, liquid carbon-containing fuels, fuels, etc., can solve the problems of corrosive biodiesel technology, such as cumbersome technology, poor lubricity equipment, and low cetane number, and achieve environmental protection and safety. Excellent reproducibility, water resistance, and high cetane number effects

Inactive Publication Date: 2014-04-02
HUNAN YITONG NEW ENERGY DEV CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The present invention aims at problems such as low cetane number, low flash point, low calorific value, poor lubricity and corrosion to equipment when pure methanol is used as a power fuel, and the technical process of preparing biodiesel from animal and vegetable oil is cumbersome and the cost is relatively high. Advanced issues, comprehensive raw material sources, environmental protection characteristics, combustion characteristics and other factors, using relatively abundant methanol, animal and vegetable oils, and diesel as raw materials, prepared a new type of biomass methanol that is relatively cheap, environmentally friendly and partially renewable diesel fuel

Method used

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  • Biomass methanol diesel oil and preparation method thereof

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Effect test

Embodiment 1

[0021] Composition and ratio of biomass methanol diesel: 100 parts by weight of diesel oil, 40 parts by weight of fatty acid methyl ester, 15 parts by weight of methanol, and 8 parts by weight of composite co-solvent.

[0022] The raw material composition and ratio of the composite co-solvent are as follows: 100 parts by weight of alkylphenol polyoxyethylene ether, 75 parts by weight of sodium dodecylsulfonate, 25 parts by weight of amyl alcohol, and 10 parts by weight of sodium edetate.

[0023] The preparation method of this embodiment is:

[0024] (1) Preparation of composite co-solvent:

[0025] 100 parts by weight of alkylphenol polyoxyethylene ether, 75 parts by weight of sodium dodecyl sulfonate, 25 parts by weight of amyl alcohol, and 10 parts by weight of sodium ethylenediaminetetraacetate are added to the reactor equipped with a stirrer for reaction. In the container, stir evenly to obtain a composite co-solvent system, in which sodium ethylenediaminetetraacetate ac...

Embodiment 2

[0029] Composition and ratio of biomass methanol diesel: 100 parts by weight of diesel oil, 50 parts by weight of fatty acid methyl ester, 20 parts by weight of methanol, and 15 parts by weight of composite co-solvent.

[0030] Wherein the raw material composition and proportioning of the composite co-solvent: Tween80: 100 parts by weight, sodium dodecylbenzenesulfonate: 60 parts by weight, isobutanol: 20 parts by weight, sodium tartrate: 15 parts by weight.

[0031] The preparation method of this embodiment is:

[0032] (1) Preparation of composite co-solvent:

[0033] The Tween80 of 100 parts by weight, the sodium dodecylbenzenesulfonate of 60 parts by weight, the isobutanol of 20 parts by weight, the sodium tartrate of 15 parts by weight are successively added in the reactor that agitator is equipped with, stir evenly, obtain A compound co-solvent system, in which sodium tartrate acts as a stabilizer to complex heavy metal ions.

[0034] (2) Preparation of biomass...

Embodiment 3

[0037] Composition and ratio of biomass methanol diesel: 100 parts by weight of diesel oil, 50 parts by weight of fatty acid methyl ester, 30 parts by weight of methanol, and 20 parts by weight of composite co-solvent.

[0038] The raw material composition and ratio of the composite auxiliary solvent are as follows: Span80: 100 parts by weight, sodium dodecylbenzenesulfonate: 70 parts by weight, isoamyl alcohol: 25 parts by weight, and sodium citrate: 20 parts by weight.

[0039] The preparation method of this embodiment is:

[0040] (1) Preparation of composite co-solvent:

[0041] The Span80 of 100 parts by weight, the sodium dodecylbenzenesulfonate of 70 parts by weight, the isoamyl alcohol of 25 parts by weight, the sodium citrate of 20 parts by weight are successively added in the reactor that agitator is equipped with, stir evenly, A complex co-solvent system is obtained, in which sodium tartrate is used as a stabilizer to complex heavy metal ions.

[0042] (2)...

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Abstract

The invention discloses biomass methanol diesel oil. The biomass methanol diesel oil comprises the following components by weight: 100 parts of diesel oil, 40-60 parts of fatty acid methyl ester, 15-40 parts of methanol, and 2-20 parts of composite cosolvent. The biomass methanol diesel oil comprises the following steps: adding 100 parts by weight of diesel oil in a reactor with a stirring apparatus, a heating device, a thermometer and a constant pressure funnel, at 25-500 DEG C, adding 2-20 parts by weight of composite cosolvent, stirring the solution uniformly, gradually adding 40-60 parts by weight of fatty acid methyl ester and 15-40 parts of methanol based in the constant pressure funnel, stirring the mixture uniformly to form the homogeneous biomass methanol diesel oil which is thermodynamically stable. The biomass methanol diesel oil is wide in resource, relatively cheap, high in point of flammability, high in cetane number, and good in water resistance, environmental protection, high safety and renewability, and can be used to directly substitute the common diesel oil in fields.

Description

technical field [0001] The invention relates to a biomass methanol diesel with biomass fatty acid methyl ester, methanol and diesel as raw materials and a preparation method thereof. Background technique [0002] Resource utilization and environmental protection are important issues in the social economy and sustainable development plan in the 21st century. Energy issues will face severe challenges. The development of alternative energy will change the traditional energy structure, replace scarce energy with superior energy, and replace it with renewable energy. The idea of ​​petrochemical energy and gradually increasing the proportion of alternative energy in the energy structure is the strategic policy for the long-term development of our country in the future. [0003] With the improvement of people's production and living standards, the amount of fuel used as power (such as automobiles, fuel generators, internal combustion engines, etc.) has increased rapidly, and gasoli...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L1/04
Inventor 肖细梅彭钢陈洪贺治国王正祥傅学正
Owner HUNAN YITONG NEW ENERGY DEV CO LTD
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