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Mold powder for premelted billet mold and its preparation method

A crystallizer powder and pre-melting technology, which is applied in the field of metallurgical auxiliary materials, can solve the problems such as being unfavorable for the preparation of mold powder with excellent performance, affecting the physical and chemical properties of the powder, and deteriorating the physical and chemical properties of the molten slag. The effect of low yield and uniform composition

Active Publication Date: 2016-08-24
郑州市裕丰耐火材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Disadvantages of red mud: radiation; TiO in red mud 2 If the content is large, it is easy to generate high melting point substances, thereby deteriorating the physical and chemical properties of slag, deteriorating the lubrication effect, and it is one of the reasons for the formation of "cold skin" on the liquid surface of the crystallizer; calcium oxide, silicon oxide, aluminum oxide, etc. in red mud The mass percentage of the substance is irregular, and direct application is not conducive to the preparation of excellent performance mold powder; the bulk density of red mud is 0.67g / cm 3 Too light will directly affect the physical and chemical properties of mold flux

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] The pre-melted billet mold powder of the present invention is represented by weight percentage. The raw material composition of the pre-melted billet mold powder is: 69% of premelt, 14% of wollastonite, 3% of fluorite %, sodium carbonate 4%, carbonaceous material 6% (graphite 4% and carbon black 2%), bentonite 2% and dextrin 2%;

[0036] In terms of weight percent, the raw material composition of the premelt is: 60% red mud, 24% quartz, 11% calcite, 2% clay and 3% barium sulfate.

[0037] The weight percentage of various chemical components in the red mud is Al 2 o 3 8.0~19%, SiO 2 16~25%, Fe 2 o 3 4.0~7.0%, CaO 28~38%, Na 2 O 3.5-5.9%; the particle size of the quartz, calcite, clay and barium sulfate are all 150-250 mesh.

[0038] The processing method of the present embodiment premelt is:

[0039] a. First dry the red mud, control the water content in the dried red mud to be less than 0.4%, and then grind the dried red mud to 150-250 mesh powder;

[0040] c...

Embodiment 2

[0049] Embodiment 2: basically the same as Embodiment 1, the difference is:

[0050] The pre-melted billet mold powder of the present invention is represented by weight percentage. The raw material composition of the pre-melted billet mold powder is: 76% of premelt, 4% of wollastonite, 3% of fluorite %, sodium carbonate 4%, carbonaceous material 7% (graphite 5% and carbon black 2%), quartz 4% and dextrin 2%;

[0051] In terms of weight percent, the raw material composition of the premelt is: 70% red mud, 18% quartz, 4% calcite, 2% clay and 6% barium sulfate.

[0052] The percentages by weight of each chemical component in the mold flux prepared in this example are: Al 2 o 3 5.2~6.9%, SiO 2 30~32.2%, Fe 2 o 3 2.0~2.5%, CaO 23.8~26.1%, Na 2 O 6.0~8.2%, F - 3.0~4.0%, C 固定 10.6-12.1%, BaO 0.95-1.1%. Chemical index: Alkalinity is 0.79-0.84, melting point is 1130°C, viscosity is 0.42Pa·s (1300°C), particle size is 0.15-1mm and over 90%.

[0053] During the use of the m...

Embodiment 3

[0055] Embodiment 3: basically the same as Embodiment 1, the difference is:

[0056] The pre-melted billet mold powder of the present invention is represented by weight percentage. The raw material composition of the pre-melted billet mold powder is: 63% premelt, 8% wollastonite, 5% fluorite %, sodium carbonate 7%, carbonaceous material 4% (graphite 3% and carbon black 1%), bentonite 3%, quartz 6%, lithium carbonate 2% and dextrin 2%;

[0057] In terms of weight percent, the raw material composition of the premelt is: 68% red mud, 8% quartz, 12% calcite, 4% clay and 8% barium sulfate.

[0058] The percentages by weight of each chemical component in the mold flux prepared in this example are: Al 2 o 3 3.4~4.2%, SiO 2 30~35%, Fe 2 o 3 2.0~2.3%, CaO 29~32%, Na 2 O 6.5~8.2%, F - 4.8~7.2%, C 固定 3-6%, BaO 1.2-1.6%. Chemical index: Alkalinity is 0.85~0.88, melting point is 1200°C, viscosity is 0.2-0.6Pa·s (1300°C), particle size is 0.15~1mm above 90%.

[0059] During th...

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Abstract

The invention discloses a pre-molten type square billet crystallizer casting powder and a preparation method thereof. The pre-molten type square billet crystallizer casting powder is composed of the raw materials, by weight percentage, 60-80% of premelting agent, 4-14% of wollastonite, 2-5% of fluorite, 3-8% of sodium carbonate, 4-8% of carbonaceous materials, 0-3% of bentonite, 2% of dextrin, 0-8% of quartz and 0-3% of lithium carbonate, wherein the premelting agent is composed of 60-70% of red mud, 6-24% of quartz, 4-12% of calcite, 2-4% of clay and 2-8% of barium sulfate. The preparation method comprises adding the raw materials into water for uniform mixing; performing ball milling; performing atomizing, drying and prilling after ball milling to obtain the pre-molten type square billet crystallizer casting powder. According to the pre-molten type square billet crystallizer casting powder and the preparation method thereof, the red mud is applied to the crystallizer casting powder and reaches an adding quantity up to 50%, so that a breakthrough on the application quantity of recycled waste red mud can be achieved; meanwhile, the square billet casting powder prepared through the premelting agent is uniform in component, stable in melting performance and relatively low in cost.

Description

technical field [0001] The invention belongs to the technical field of metallurgical auxiliary materials, in particular to a mold powder for a premelted billet mold and a preparation method thereof. Background technique [0002] my country is one of the countries with the highest dependence on energy in the world, among which coal accounts for about 75% of the total energy resources, and has an important strategic position in the national economy. Saving coal resources is of great strategic significance to ensure the stable development of the national economy. During the "Twelfth Five-Year Plan" period, my country's development is still in an important period of strategic opportunities where great achievements can be made. With the acceleration of industrialization and urbanization and the continuous upgrading of the consumption structure, my country's energy demand has shown a rigid growth. Due to the constraints of domestic resource guarantee capacity and environmental ca...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22D11/111
Inventor 张景倚张会敏郑化张志明
Owner 郑州市裕丰耐火材料有限公司
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