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Three-dimensional porous lithium battery current collector and preparation method thereof

A three-dimensional porous, lithium battery technology, applied in the direction of electrode carrier/current collector, etc., can solve the problem of high contact resistance, and achieve the effect of reducing battery volume, improving powder removal, and increasing adsorption capacity

Active Publication Date: 2014-05-07
XINJIANG JOINWORLD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The present invention provides a three-dimensional porous lithium battery current collector and its preparation method, which overcomes the above-mentioned deficiencies in the prior art, and can effectively solve the problem of desorption in the prior art. The problem of high contact resistance due to powder drop phenomenon

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  • Three-dimensional porous lithium battery current collector and preparation method thereof

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Embodiment 1

[0016] Example 1, the three-dimensional porous lithium battery current collector is obtained according to the following preparation method: the three-dimensional porous lithium battery current collector is characterized in that it is obtained according to the following method: in the first step, put 0.1g to 1g per liter of phosphoric acid aqueous solution Aluminum foil meter, put the aluminum foil into the phosphoric acid aqueous solution with a mass concentration of 0.1% to 20%, and perform phosphoric acid corrosion treatment at a temperature of 20°C to 80°C for 30s to 10min; Add 0.1g to 5g of aluminum foil, put the aluminum foil after phosphoric acid corrosion treatment into the electrocorrosion solution, and use 50Hz power frequency alternating current at a current density of 0.133A / cm 2 up to 10 A / cm 2 , Carry out galvanic corrosion at a temperature of 10°C to 80°C for 1s to 10min; in the third step, put 0.1g to 1g of aluminum foil in each liter of nitric acid aq...

Embodiment 2

[0017] Example 2, the three-dimensional porous lithium battery current collector is obtained according to the following preparation method: in the first step, 0.1 g or 1 g of aluminum foil is put into each liter of phosphoric acid aqueous solution, and the aluminum foil is put into 0.1% or 20% of the mass concentration In the phosphoric acid aqueous solution, the phosphoric acid corrosion treatment is carried out at 20°C or 80°C for 30s or 10min; in the second step, 0.1g or 5g of aluminum foil is put into each liter of electro-corrosion solution, and the aluminum foil after phosphoric acid corrosion treatment Put it into the electro-corrosion solution, use 50Hz power frequency alternating current at a current density of 0.133A / cm 2 or 10 A / cm 2 , The temperature is 10°C or 80°C for 1s or 10min; the third step is to put 0.1g or 1g of aluminum foil into each liter of nitric acid aqueous solution, and put the aluminum foil after galvanic corrosion into the concentration...

Embodiment 3

[0018] Embodiment 3, preferably as above-mentioned embodiment, in the first step, put into 0.45g aluminum foil meter in every liter of phosphoric acid aqueous solution, put aluminum foil into the phosphoric acid aqueous solution that mass concentration is 0.1% to 20%; In the second step, press Put 1.5g of aluminum foil into each liter of electro-corrosion solution, put the aluminum foil after phosphoric acid corrosion treatment into the electro-corrosion solution; in the third step, put 0.45g of aluminum foil into each liter of nitric acid aqueous solution, put the Put the final aluminum foil into the nitric acid aqueous solution with a concentration of 0.01mol / L to 1mol / L; in the fourth step, put 0.45g of aluminum foil into each liter of chemical etching solution, put the aluminum foil after nitric acid etching into chemical etching in the liquid.

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Abstract

The invention relates to the technical fields of current collectors and electrochemical corrosion, particularly a three-dimensional porous lithium battery current collector and a preparation method thereof. The preparation method comprises the following steps: 1. putting an aluminum foil into a phosphoric acid water solution to perform phosphoric acid corrosion treatment; 2. putting the aluminum foil subjected to phosphoric acid corrosion treatment into an electric corrosion solution to perform power-on corrosion; 3. putting the aluminum foil subjected to power-on corrosion into a nitric acid water solution to perform nitric acid corrosion treatment; and 4. putting the aluminum foil subjected to nitric acid corrosion treatment into a chemical corrosion solution to perform chemical corrosion, thereby obtaining the three-dimensional porous lithium battery current collector. The current collector can increase the adsorption capacity of active substances, improve the common phenomena of peeling and swelling in the prior art, enhance the specific capacity, lower the contact resistance, increase the electric conductivity of the positive plate, enhance the charge and discharge capacity of the lithium battery, reduce the volume of the battery and prolong the service life of the battery.

Description

technical field [0001] The invention relates to the technical field of current collectors and electrochemical corrosion, and relates to a three-dimensional porous lithium battery current collector and a preparation method thereof. Background technique [0002] As a new type of energy storage power supply, lithium-ion batteries have the advantages of high energy, high working voltage, wide working temperature range, small size, light weight, long storage life, etc. The new favorite is gradually replacing nickel-cadmium and nickel-metal hydride batteries. Lithium-ion power batteries have great market application prospects in hybrid vehicles, electric vehicles, electric bicycles, electric hand tools, and future solar LED street lamp energy storage equipment; in modern military equipment such as various weapons and devices Detection systems, fuze systems, sea, land and air portable weapons, military communications and aerospace applications also use lithium-ion batteries as hig...

Claims

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Application Information

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IPC IPC(8): H01M4/66H01M4/70
CPCC25F3/04H01M4/80Y02E60/10
Inventor 郭敏洪涛
Owner XINJIANG JOINWORLD CO LTD