Preparation method of oil/water separation material

A technology of oil-water separation and template method, applied in separation methods, liquid separation, chemical instruments and methods, etc., can solve the problems of complex operation, membrane fouling, and high cost, and achieve the effects of simple operation, controllable experimental parameters, and low cost.

Inactive Publication Date: 2014-06-11
HARBIN INST OF TECH
View PDF1 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The preparation of porous materials by the hydrogen bubble template method is a simple, convenient, low-cost, and parameter-controllable method. This method can be deposited on copper mesh to obtain a three-dimensional porous network film. The porous film is prepared using dynamic hydrogen bubbles as a tem

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of oil/water separation material
  • Preparation method of oil/water separation material
  • Preparation method of oil/water separation material

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach 1

[0022] Specific Embodiments 1. In this embodiment, a superhydrophobic reticular porous film is prepared according to the following steps:

[0023] The first step, the preparation of mesh porous Ni film by hydrogen bubble template method ( figure 2 )

[0024] Electrodeposited mesh porous Ni thin films by hydrogen bubble template method are based on platinum sheet (1cm 2 ) as the anode, and the counter electrode uses copper mesh (aperture 300μm, area 3*3cm 3 ) is the cathode, and its electroplating device such as figure 1 shown. The pretreatment of the copper mesh in the experiment includes polishing, degreasing, acid etching, water washing, absolute ethanol soaking, acetone cleaning, and low-temperature blast drying. The composition of the plating solution is 0.01-0.2mol L -1 NiCl 2 and 0.2-2mol L -1 NH 4 Cl, pH is controlled within the range of 4.0±0.5, and the current density range of electrodeposition is 0.1-6.0A cm -2 , the deposition time is 10-40s. By adjusting...

specific Embodiment approach 2

[0028] Specific embodiment two: In this embodiment, a superhydrophobic mesh porous film is prepared according to the following steps:

[0029] Step 1. Preparation of mesh-like porous Ni film by hydrogen bubble template method

[0030] Electrodeposited mesh porous Ni thin films by hydrogen bubble template method are based on platinum sheet (1cm 2 ) as the anode, and the counter electrode uses copper mesh (aperture 300μm, area 3*3cm 2 ) is the cathode. The pretreatment of the copper mesh in the experiment includes polishing, degreasing, acid etching, water washing, absolute ethanol soaking, acetone cleaning, and low-temperature blast drying. The composition of the plating solution is 0.2mol L -1 NiCl 2 and 0.5mol·L -1 NH 4 Cl, pH is controlled within the range of 4.0±0.5, and the current density of electrodeposition is 0.5A cm -2 , the deposition time is 30s. By adjusting the deposition parameters such as current density, deposition time, bath composition, etc., the stru...

specific Embodiment approach 3

[0034] Specific embodiment three: In this embodiment, a superhydrophobic reticulated porous film is prepared according to the following steps:

[0035] Step 1. Preparation of mesh-like porous Ni film by hydrogen bubble template method

[0036] Hydrogen bubble template electrodeposition network porous Ni thin film is to use platinum sheet (1cm2) as anode, copper mesh (aperture 300μm, diameter 3cm) is used as cathode for counter electrode. The pretreatment of the copper mesh in the experiment includes polishing, degreasing, acid etching, water washing, absolute ethanol soaking, acetone cleaning, and low-temperature blast drying. The composition of the plating solution is 0.2mol L -1 NiCl 2 and 2mol L -1 NH 4 Cl, pH is controlled within the range of 4.0±0.5, and the current density of electrodeposition is 0.5A cm -2 , the deposition time is 30s. The deposited net film should be immediately rinsed with distilled water, soaked in absolute ethanol and then dried to obtain a ne...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Apertureaaaaaaaaaa
Login to view more

Abstract

The invention discloses a preparation method of an oil/water separation material. The method comprises the following steps of (1) preparing a porous meshy Ni film by using a hydrogen bubble template method; (2) annealing the surface of the Ni film at a certain temperature to ensure that a surface layer is oxidized to form NiO, and modifying the surface of the porous meshy Ni film by using dodecylthiol and tetradecanoic acid to obtain a super-hydrophobic porous meshy film. The hydrogen bubble template method for preparing a porous material has the advantages of simplicity, convenience, low cost and parameter controllability; a three-dimensional porous meshy film can be obtained through depositing on a copper wire mesh by using the method; the porous film is prepared by taking a dynamic hydrogen bubble as a template; compared with a hard template method, the method has the advantages that the template is not needed to be removed, the problems such as high cost, complexity in operation and serious film pollution in the traditional method are solved, and the industrial production is expected to be realized.

Description

technical field [0001] The invention relates to a preparation method of a super-hydrophobic porous network film. Background technique [0002] Oily wastewater is a common wastewater in industry. Direct discharge will cause serious harm to the environment, indirectly pollute the atmosphere and soil, and seriously endanger human health. Oil-water separation technology has an important impact in petrochemical and other fields, including the recovery of sea waste oil, oil production wastewater, and the separation of organic solvents. Due to the large difference in surface tension between water and oil, choosing a surface with different wettability to water and oil can selectively adsorb one phase and repel the other phase. Enhancing the wettability of the surface can improve the separation efficiency. [0003] The superhydrophobic phenomenon ubiquitous in nature, the main factors affecting its wettability are the surface chemical composition and surface microstructure, accordin...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C25D1/08C25D3/12B05D5/08B01D17/022
Inventor 刘宇艳张恩爽王友善吕通刘羽熙
Owner HARBIN INST OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap