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A kind of high thermal conductivity modified plastic and its preparation method

A high thermal conductivity, plastic technology, applied in the field of polymer materials, can solve the problems of uneven distribution, unsuitable for industrial production, large consumption of carbon black, etc., to achieve the effect of simple preparation, suitable for industrial production, and low cost

Inactive Publication Date: 2016-03-16
ZHONGSHAN YONGWEI NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Now we generally add silane coupling agent and additive blending directly in actual production, but this kind of surface treatment also has the disadvantages of uneven distribution and single selectivity, which will cause the local thermal conductivity of the produced thermally conductive plastic to be uneven, resulting in less than stable product
[0005] Chinese patent application number: 200510057168.7 introduces an inorganic oxide conductive powder / polyaniline conductive polymer composite material and its preparation method. The method is to select a single conductive polymer polyaniline, and the quality of the aniline monomer is the 2-40 times the quality, not suitable for industrial production
This patent needs to consume a large amount of carbon black, which greatly increases the cost of preparation

Method used

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  • A kind of high thermal conductivity modified plastic and its preparation method
  • A kind of high thermal conductivity modified plastic and its preparation method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] The weight percentage components of high thermal conductivity modified plastics are: magnesia powder 32%, flake boron nitride 32%, nylon 16%, nylon 6616%, maleic anhydride graft compatibilizer 1%, dispersant 3%;

[0037] The preparation method of embodiment 1 is:

[0038] a. First mix magnesium oxide powder and flake boron nitride to form a thermally conductive filler mixture, then add the mixture of aniline monomer, water and hydrochloric acid in a volume ratio of 1:15:1, and then add aniline monomer and other substances in batches A certain amount of initiator was reacted for 28 hours, and a thin layer of polyaniline was coated on the surface of the thermally conductive filler mixture to obtain a thermally conductive additive, wherein the mass ratio of aniline monomer to the thermally conductive filler mixture was 1:10;

[0039] b. Blend the heat-conducting additive with the main plastic, coupling agent and dispersant, add it to the feeder of the twin-screw extruder, ...

Embodiment 2

[0041] The weight percentage components of high thermal conductivity modified plastics are: 48% of alumina fiber, 18% of flake boron nitride, 16% of polypropylene, 12% of polyethylene, 2% of silane coupling agent, and 4% of dispersant;

[0042] The preparation method of embodiment 2 is:

[0043] a. First mix alumina fiber and flake boron nitride to form a thermally conductive filler mixture, then add the mixture of pyrrole monomer, water and sulfuric acid at a volume ratio of 1:15:1, and then add pyrrole monomer and other substances in batches A large amount of initiator was reacted for 26 hours, and a thin layer of polypyrrole was coated on the surface of the thermally conductive filler mixture to obtain a thermally conductive additive, wherein the mass ratio of the pyrrole monomer to the thermally conductive filler mixture was 1:3;

[0044] b. Blend the heat-conducting additive with the main plastic, coupling agent and dispersant, add it to the feeder of the twin-screw extru...

Embodiment 3

[0046]The weight percentage components of high thermal conductivity modified plastics are: alumina fiber 30%, magnesium oxide powder 20%, polyethylene terephthalate 15%, polypropylene 16%, polyethylene 12%, aluminate 2 %, dispersant 5%;

[0047] The preparation method of embodiment 3 is:

[0048] a. First mix alumina fiber and magnesium oxide powder to form a thermally conductive filler mixture, then add the mixture of thiophene monomer, water and hydrochloric acid in a volume ratio of 1:15:1, and then add the amount of thiophene monomer and other substances in batches The initiator was reacted for 30 hours, and a thin layer of polythiophene was coated on the surface of the thermally conductive filler mixture to obtain a thermally conductive additive, wherein the mass ratio of thiophene monomer to the thermally conductive filler mixture was 1:5;

[0049] b. Blend the heat-conducting additive with the main plastic, coupling agent and dispersant, add it to the feeder of the twi...

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Abstract

The invention discloses highly heat-conducting modified plastic and a preparation method thereof. The heat-conducting plastic comprises the following components in percentage by weight: a heat-conducting additive, main body plastics, a coupling agent and a dispersant, wherein the heat-conducting additive is obtained by wrapping a conducting polymer on the surface of a mixture of two or three of heat-conducting filler aluminum oxide fibers, magnesium oxide powder and sheet-like boron nitride through an aqueous solution polymerization method. A thin layer conducting polymer is polymerized on the surface of the heat-conducting additive, and the heat-conducting additive as well as the main body plastics such as polyethylene glycol terephthalate, polypropylene, polyethylene and nylon are bonded by means of high conducting characteristic of metalloid bonds of the conducting polymer, so that the heat-conducting additive and the main body plastics are well compatible so as to prepare the high-conducting modified plastic. Through detection by authorities, the heat-conducting coefficient of the modified plastic prepared by the method disclosed by the invention reaches 4.20W / m.K.

Description

【Technical field】 [0001] The invention relates to a high thermal conductivity modified plastic and a preparation method thereof, belonging to the technical field of polymer materials. 【Background technique】 [0002] Modified plastics are intermediate products in the petrochemical industry chain. It is a new type of plastic product processed on the basis of general-purpose plastics and engineering plastics through filling, blending, and reinforcement. It is mainly processed from the five major general-purpose plastics and the five major engineering plastics as the plastic matrix, and has the characteristics of flame retardancy, impact resistance, high toughness, and easy processing. Modified plastics is a typical industry that benefits from technological progress and consumption upgrades. Thanks to the accelerated transfer of production capacity such as global home appliances, computers, electric tools and toys to China, my country has become a major player in these fields by...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08L23/12C08L23/06C08L77/00C08L77/10C08K9/10C08K7/08C08K7/00C08K3/22C08K3/38
Inventor 徐常威
Owner ZHONGSHAN YONGWEI NEW MATERIAL CO LTD