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A preparation method of photocatalytic material for degrading air pollutants by using LED light source

A technology of air pollutants and LED light sources, applied in chemical instruments and methods, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc., can solve problems such as high cost and low efficiency, and achieve equipment The effect of less material, low cost and high removal efficiency

Inactive Publication Date: 2016-08-24
GUANGXI NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current TiO 2 Photocatalytic technology uses ultraviolet light as the light source, which is expensive and limits its industrial application. Although solar energy can be used as the light source, TiO 2 Only 5% of the ultraviolet part of the solar energy can be used, the efficiency is very low, and the light source has become TiO 2 The biggest obstacle to the industrial application of photocatalytic technology

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Add tourmaline powder with a particle size of 3000 mesh into 20mL of absolute ethanol, the doping amount is 0.2 wt%, and under constant stirring, add 10mL of butyl titanate and 1mL of acetylacetone, and stir well to form A solution; add 0.8 Mix wt% lanthanum nitrate with 20mL absolute ethanol, then add 2mL distilled water and 2.5mL glacial acetic acid to form solution B; mix 0.5 wt% hydrated chromium nitrate with 20mL absolute ethanol, then add 2mL distilled water, 2.5mL of glacial acetic acid to form solution C; under continuous stirring, add solution B dropwise to solution A to make it evenly mixed, then add solution C dropwise, continue stirring for 0.5h, and age for 20h to form a stable sol; Nickel foam cut into a size of 145mm×80mm is placed in the sol and dipped for 0.2h; pulled at a constant speed of 2cm / min by a pull coater, and dried in an oven at 120°C; dipping, pulling, and drying Repeat the operation twice; sinter at 400°C for 2 hours to obtain a photocataly...

Embodiment 2

[0029] Add tourmaline powder with a particle size of 4000 mesh into 20mL of absolute ethanol, the doping amount is 0.4 wt%, and under constant stirring, add 10mL of butyl titanate and 1mL of acetylacetone, and stir well to form A solution; Mix wt% lanthanum nitrate and cerium nitrate mixture (weight ratio 1:1) with 20mL of absolute ethanol, and then add 2mL of distilled water and 2.5mL of glacial acetic acid to form B solution; Mix copper (1:1) mixture with 20mL of absolute ethanol, and then add 2mL of distilled water and 2.5mL of glacial acetic acid to form C solution; under constant stirring, add B solution to A solution drop by drop to make it evenly mixed , then add solution C drop by drop, continue to stir for 1 hour, and age for 20 hours to form a stable sol; place the copper foam cut into a size of 145mm×80mm in the sol for 0.3 hours; Pull at a constant speed, put it in an oven and dry at 120°C; dip, pull, and dry repeatedly for 3 times; sinter at 500°C for 1.5 hours to...

Embodiment 3

[0032] Add tourmaline micropowder with a particle size of 5000 mesh into 20mL of absolute ethanol, and the doping amount is 0.6 wt%. Under constant stirring, add 10mL of butyl titanate and 1mL of acetylacetone, and stir to form A solution; 1.2 Mix wt% lanthanum nitrate and neodymium nitrate mixture (weight ratio 1:1) with 20mL absolute ethanol, then add 2mL distilled water and 2.5mL glacial acetic acid to form B solution; Mix ammonium molybdate (1:1) mixture with 20mL absolute ethanol, and then add 2mL distilled water and 2.5mL glacial acetic acid to form C solution; under constant stirring, add B solution dropwise to A solution to make it Mix evenly, then add solution C drop by drop, continue to stir for 2 hours, and age for 24 hours to form a stable sol; place nickel foam cut into a size of 145mm×80mm in the sol for 0.5h; use a pull coater at 1cm / min Pull at a constant speed at a constant speed, put it in an oven and dry at 180°C; dip, pull, and dry repeatedly for 4 times; s...

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Abstract

The invention discloses a preparation method of a photocatalysis material capable of degrading air pollutants by utilization of an LED light source. The method includes doping one or a mixture of more than two of tourmaline micro powder, mixed rare earth oxides or nitrates and transition metal compounds into foam metal so as to be modified and supported by the foam metal to obtain a photocatalytic material, sintering the photocatalytic material at a certain temperature for a certain period of time to obtain photocatalytic film, wherein the, and assembling the photocatalytic film and a light emitting diode (LED) plane light source with a certain wavelength to obtain an air pollutant photocatalytic degradation module. The method is advantaged by being simple and feasible, less in equipment material, low in cost, and the like. Tests show that: the product of the method can efficiently remove the air pollutants, the removing cycle is short, and the removing rate of formaldehyde is 97.6%. The method can be widely used in the field of poison gas and harmful gas cleaning, and has a wide application prospect.

Description

technical field [0001] The invention relates to the field of poisonous and harmful gas treatment, in particular to a preparation method of a photocatalytic material for degrading air pollutants by using an LED light source. Background technique [0002] Indoor air pollution has become a prominent problem endangering human health and safety. In the three major cities of my country, Beijing, Shanghai, and Tianjin, the rate of formaldehyde in indoor air exceeding the standard is 79%, 82%, and 81%, respectively, and some even exceed the standard by dozens of times. Indoor air pollution can have adverse effects on nervous, immune, endocrine, reproductive and other systems, or cause cancer and mutagenesis. According to statistics, 68% of human diseases are caused by air pollution, and 4 million people die from air pollution per year in the world, of which 111,000 people per year in my country. Therefore, the World Health Organization (WHO) has listed indoor air pollution as a One...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/887B01D53/86
Inventor 蒙冕武刘庆业刘明登邓希敏
Owner GUANGXI NORMAL UNIV