Production method for preparing ammonium dihydrogen phosphate and byproduct special fertilizer for radix scutellariae

A technology of ammonium dihydrogen phosphate and ammonium dihydrogen phosphate, which is applied in the direction of phosphate, phosphorus oxyacid, application, etc., can solve the problems of reducing the output and quality of Huangling, difficulty in meeting industrial needs, and impact on purity, and achieves significant Environmental protection value and economic benefits, increase product added value, output and quality improvement effect

Inactive Publication Date: 2015-01-07
GUIYANG KAILIN FERTILIZER CO LTD +2
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AI Technical Summary

Problems solved by technology

Usually, in the planting and cultivation technology of Huangling, a large amount of miscellaneous fertilizers are used to mix, and phosphorus fertilizer is used as the base fertilizer, so as to provide technical means for the cultivation of Huangling. When Huang Ling is planted with base fertilizer, due to the absorption defect of the crop itself (the absorption rate of nitrogen fertilizer is about 20-46%, the absorption rate of phosphorus fertilizer is about 10-25%, and the absorption rate of potassium fertilizer is about 46-60%), so that a large amount of nitrogen Phosphorus and potassium elements remain in the soil, resulting in an increase in fertilization costs. At the same time, such residues for a long time will cause changes in the soil structure, thereby polluting the environment, increasing the input of fertilizer nutrients, and reducing the yield and quality of Huangling.
[0003] At the same time, the preparation process of ammonium dihydrogen phosphate products is usually produced by wet-process phosphoric acid and hot-process phosphoric acid, but no matter whether it is produced by hot-process phosphoric acid or wet-process phosphoric acid The purity of the ammonium product is affected, so that the purity of the ammonium dihydrogen phosphate product is relatively poor, and it is difficult to meet the industrial needs. Purification of urea phosphate; for this reason, some researchers adopted the method of intermediate replacement, reacting phosphoric acid with urea to prepare the intermediate of urea phosphate, but the reaction was completed below 80°C, and then crystallized by cooling to precipitate phosphoric acid diphosphate ammonium hydrogen phosphate products, and then improve the purity of ammonium dihydrogen phosphate products; however, this process step often requires deep crystallization of ammonium dihydrogen phosphate, thereby minimizing the waste of nitrogen and phosphorus elements in the solution, thereby reducing the concentration of dihydrogen phosphate The cost of ammonium product preparation can also avoid a large amount of waste liquid discharge to cause certain pollution to the environment; and in the process of deep crystallization, it is often accompanied by the production of other products, mixed with ammonium dihydrogen phosphate crystallization, and then affects again Guaranteed the purity of ammonium dihydrogen phosphate product

Method used

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  • Production method for preparing ammonium dihydrogen phosphate and byproduct special fertilizer for radix scutellariae
  • Production method for preparing ammonium dihydrogen phosphate and byproduct special fertilizer for radix scutellariae
  • Production method for preparing ammonium dihydrogen phosphate and byproduct special fertilizer for radix scutellariae

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] A kind of production method of preparing ammonium dihydrogen phosphate by-product Huang Ling special fertilizer, comprises the following steps:

[0047] (1) Preparation and mixing of raw materials: Put phosphoric acid and urea in a stirred reactor at a molar ratio of 1.5:1, at a temperature of 90°C, and control the stirring speed of the stirred tank at 180r / min to stir and mix for 1 hour to obtain an intermediate material pulp;

[0048] (2) Preparation of ammonium dihydrogen phosphate: Ammonia gas is passed into the intermediate slurry obtained in step 1), and the temperature in the reactor is controlled to be 70°C, and the stirring speed is 60r / min, and the stirring reaction is 30min, and the reaction ends PH value is 4.2, obtains the slurry containing ammonium dihydrogen phosphate product;

[0049] (3) Cyclic crystallization and filtration: place the slurry containing ammonium dihydrogen phosphate obtained in step 2) in a cooling crystallizer to cool down to a temper...

Embodiment 2

[0056] A kind of production method of preparing ammonium dihydrogen phosphate by-product Huang Ling special fertilizer, comprises the following steps:

[0057] (1) Preparation and mixing of raw materials: Put phosphoric acid and urea in a stirred reactor at a molar ratio of 1.7:1, at a temperature of 140°C, and control the stirring speed of the stirred tank at 200r / min to stir and mix for 3 hours to obtain an intermediate material pulp;

[0058] (2) Preparation of ammonium dihydrogen phosphate: Ammonia gas is passed into the intermediate slurry obtained in step 1), and the temperature in the reactor is controlled to be 80°C. According to the stirring speed of 80r / min, the stirring reaction is 40min, and the reaction ends PH value is 4.6, obtains the slurry containing ammonium dihydrogen phosphate product;

[0059] (3) Cyclic crystallization and filtration: place the slurry containing ammonium dihydrogen phosphate obtained in step 2) in a cooling crystallizer to cool down to a...

Embodiment 3

[0066] A kind of production method of preparing ammonium dihydrogen phosphate by-product Huang Ling special fertilizer, comprises the following steps:

[0067] (1) Preparation and mixing of raw materials: Put phosphoric acid and urea in a stirred reactor at a molar ratio of 1.6:1, at a temperature of 125°C, and control the stirring speed of the stirred tank at 190r / min to stir and mix for 2 hours to obtain an intermediate material pulp;

[0068] (2) Preparation of ammonium dihydrogen phosphate: Ammonia gas is passed into the intermediate slurry obtained in step 1), and the temperature in the reactor is controlled to be 75°C. According to the stirring speed of 70r / min, the stirring reaction is 35min, and the reaction ends PH value is 4.4, obtains the slurry containing ammonium dihydrogen phosphate product;

[0069] (3) Cyclic crystallization and filtration: place the slurry containing ammonium dihydrogen phosphate obtained in step 2) in a cooling crystallizer to cool down to a...

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Abstract

The invention relates to the technical field of chemical engineering, and particularly relates to a production method for preparing ammonium dihydrogen phosphate and a byproduct special fertilizer for radix scutellariae. Through analysis on requirements on nutritional elements in the radix scutellariae growth process, analysis and realization of fertilization conditions of traditional radix scutellariae planting, research and discussion of the absorption conditions of crops on nitrogen, phosphorus and potassium, and analysis by combining with the defects in the preparation process of an ammonium dihydrogen phosphate product, the production process of the special fertilizer for the radix scutellariae is combined with the preparation process of the ammonium dihydrogen phosphate product, so that the preparation process of the ammonium dihydrogen phosphate product and the preparation process of the special fertilizer for the radix scutellariae are complementary; production of the special fertilizer for the radix scutellariae is carried out by using liquid waste generated in the preparation process of the ammonium dihydrogen phosphate product; the added value of the product in the preparation process of the ammonium dihydrogen phosphate product is increased; the discharge of the liquid waste is lowered; and meanwhile, deep crystallization of the ammonium dihydrogen phosphate product in the ammonium dihydrogen phosphate process is unnecessary, thus waste of nitrogen and phosphorus resources can also be avoided.

Description

technical field [0001] The invention relates to the technical field of chemical industry, in particular to a production method for preparing ammonium dihydrogen phosphate by-product Huangling special fertilizer. Background technique [0002] Huangling, aliases: Tiaoling, Ziling, Kuling, Kuiling, Camellia root, perennial herb. Born on dry sunny hillsides, it can cure plague fever, lung heat cough, damp-heat jaundice, diarrhea, restless fetus, etc. It also has antibacterial, antipyretic, and antihypertensive effects. Usually, in the planting and cultivation technology of Huangling, a large amount of miscellaneous fertilizers are used to mix, and phosphorus fertilizer is used as the base fertilizer, so as to provide technical means for the cultivation of Huangling. When Huang Ling is planted with base fertilizer, due to the absorption defect of the crop itself (the absorption rate of nitrogen fertilizer is about 20-46%, the absorption rate of phosphorus fertilizer is about 10-...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B25/28C05G1/00
Inventor 朱飞武高贵龙廖吉星陈肖虎韩朝应薛涛周勇赵伟毅曾舒赵平原
Owner GUIYANG KAILIN FERTILIZER CO LTD
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