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Water-based laminated adhesive and preparation method thereof

An adhesive and film coating technology, applied in the directions of adhesives, adhesive types, ester copolymer adhesives, etc., can solve problems such as foaming and environmental pollution, and achieve convenient use, high bonding strength, and reduction of residual monomers. amount of effect

Active Publication Date: 2015-01-07
浙江春雨新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The invention provides a water-based film-coating adhesive and a preparation method thereof for solvent-based film-coating adhesives, which have quality problems such as foaming in paper-plastic composite products due to the action of solvents, and cause relatively large pollution to the environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Formula: Total amount=1000kg

[0040] BYK024 1kg

[0041] WA-300 15kg

[0042] EF-800 5kg

[0043] Sodium bicarbonate 1.5kg

[0044] Ammonium persulfate 2.0kg

[0045] Butyl acrylate 300kg

[0046] Methyl methacrylate 100kg

[0047] Methacrylic acid 10kg

[0048] Diisooctyl maleate 15kg

[0049] Diacetone acrylamide 5kg

[0050]Methacrylamide ethyl ethylene urea 2.5kg

[0051] Adipic acid dihydrazide 2.5kg

[0052] Eastman OE300 1kg

[0053] Cytec OT-75 1kg

[0054] Rohm and Haas LXE 1kg

[0055] 70% tert-butyl hydroperoxide 200g

[0056] Carved white block 200g

[0057] 15% ammonia solution 17.5kg

[0058] Deionized water 519.6kg

[0059] Production Process:

[0060] 1. Dissolve 0.8kg of ammonium persulfate into 15kg of deionized water to obtain 15.8kg of the first initiator solution; dissolve 1.2kg of ammonium persulfate, 2kg of WA-300 and 1kg of EF-800 into 15kg of deionized water to obtain 19.2kg of the first initiator solution Two initiator soluti...

Embodiment 2

[0075] Formula: Total amount=1000kg

[0076] Cognis SN-154 1.1kg

[0077] WA-300 15kg

[0078] Co436 10kg

[0079] Sodium acetate 1.8kg

[0080] Ammonium persulfate 2.5kg

[0081] Butyl acrylate 320kg

[0082] Methyl methacrylate 120kg

[0083] Methacrylic acid 11kg

[0084] Diisooctyl maleate 17kg

[0085] Diacetone acrylamide 7kg

[0086] Methacrylamide ethyl ethylene urea 3.0kg

[0087] Adipic acid dihydrazide 3.5kg

[0088] Loxanol CA5308 1.2kg

[0089] Cytec OT-75 1.2kg

[0090] Rohm and Haas LXE 1.2kg

[0091] 70% tert-butyl hydroperoxide 300g

[0092] Carved white block 300g

[0093] 15% ammonia solution 17.5kg

[0094] Deionized water 466.4kg

[0095] Production Process:

[0096] 1. Dissolve 1kg of ammonium persulfate into 15kg of deionized water to obtain 16kg of the first initiator solution; dissolve 1.5kg of ammonium persulfate, 2kg of WA-300 and 2kg of Co436 into 15kg of deionized water to obtain 20.5kg of the second initiator solution ; 300g of t...

Embodiment 3

[0111] Formula: Total amount=1000kg

[0112] BYK024 1.2kg

[0113] WA-300 20kg

[0114] EF-800 10kg

[0115] Sodium dihydrogen phosphate 2kg

[0116]Potassium persulfate 3kg

[0117] Butyl acrylate 350kg

[0118] Methyl methacrylate 150kg

[0119] Methacrylic acid 12kg

[0120] Diisooctyl maleate 20kg

[0121] Diacetone Acrylamide 8kg

[0122] Methacrylamide ethyl ethylene urea 4kg

[0123] Adipic acid dihydrazide 4kg

[0124] Loxanol CA5308 1.5kg

[0125] OT-75 2kg

[0126] Rohm and Haas LXE 1.5kg

[0127] tert-butyl hydroperoxide 400g

[0128] Carved white block 400g

[0129] 15% ammonia solution 17.5kg

[0130] Deionized water 392.5kg

[0131] Production Process:

[0132] 1. Dissolve 1.2kg potassium persulfate in 15kg deionized water to obtain 16.2kg of the first initiator solution; dissolve 1.8kg potassium persulfate, 3kg WA-300 and 2kgEF-800 into 15kg deionized water to obtain 21.8kg of the first initiator solution Second initiator solution: Dissolve 400...

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Abstract

The invention discloses a water-based laminated adhesive and a production technique thereof. The water-based laminated adhesive mainly comprises deionized water, butyl acrylate, methyl methacrylate, acrylic acid, diisooctyl maleate, diacetone acrylamide, diamidohydrazine adipate, methacrylamido ethyl ethylene urea, an emulsifier, an initiator, a buffering agent, a defoaming agent, a film formation assistant and a preservative. A pre-emulsification technique is utilized to prepare the milk white liquid with blue fluorescence on appearance; the viscosity is 100-500 mPa.s, and the solid content is 48-55%; the film forming material is colorless and transparent, and the pH value is 7-9; the emulsion belongs to a self-crosslinking type; the macromolecules are automatically crosslinked in the compounding process, so the adhesive has high peel strength; and the emulsion has higher solid content, so the adhesive satisfies the requirement of dry-type composite quick drying.

Description

technical field [0001] The invention relates to an adhesive preparation technology, in particular to a water-based film-covering adhesive and a preparation method thereof. Background technique [0002] In the post-press process of the printing and packaging industry, the coating improves the brightness and water resistance of the printed matter, and provides a beautiful visual effect for people's lives. With the continuous emergence of various advanced processes, advanced equipment, and advanced glues, some new trends have emerged in post-press lamination. In recent years, paper-plastic laminating glue has been widely used, mainly in decorative materials, packaging materials, hardcover books and product advertisements. Paper-plastic laminating glue is to use adhesives to laminate polypropylene (BOPP), polyester (PET) and other plastic films with paper prints, thereby greatly improving the appearance and waterproof and anti-fouling properties of prints. Paper-plastic lamina...

Claims

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Application Information

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IPC IPC(8): C09J133/08C09J11/00C08F220/18C08F220/14C08F220/06C08F222/14C08F220/60C08F220/58
Inventor 刘维均罗平周闰阳陆斌徐建宋志强
Owner 浙江春雨新材料科技有限公司
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