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Environment-friendly type polyaniline shedding-preventing anticorrosion paint

A technology of anti-corrosion coatings and polyaniline, which is applied in the direction of anti-corrosion coatings, epoxy resin coatings, coatings, etc., can solve the problems of poor compatibility of resins in machining performance, affecting polyaniline anti-corrosion performance, and failure to achieve anti-corrosion effects. Good adhesion, high hardness, good leveling effect

Inactive Publication Date: 2015-02-11
QINGDAO YIQUN PANT GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although polyaniline has excellent anti-corrosion properties, its mechanical processing properties and compatibility with resins are poor, which limits its use.
The conventional methods for combining polyaniline with resin mainly include: Dissolution method: use a special solvent to dissolve and add to the resin. This method will cause environmental pollution, poor construction conditions, and the expensive solvent will increase the cost sharply; Physical blending method: such as ball milling method, which consumes a lot of energy and time, and its dispersion and stability in the resin are poor, which ultimately affects the performance of polyaniline's anti-corrosion performance; (3) first dissolve polyaniline in the amine curing agent , and then compounded with epoxy resin, this method has insurmountable defects: the content of polyaniline is low, and the content with the best anti-corrosion effect cannot be achieved

Method used

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Embodiment 1: prepare a kind of anticorrosion coating, step is as follows:

[0028] (1) Preparation of component A: The number of raw materials used in the preparation of component A is as follows:

[0029] Liquid epoxy resin E42 96 grams;

[0030] 12 grams of dibutyl phthalate;

[0031] OP-10 4 grams;

[0032] 8 grams of isopropanol;

[0033] Ammonium persulfate 15 grams;

[0034] 3 grams of distilled water;

[0035] 2 grams of 0.6mol / L aqueous solution of camphorsulfonic acid;

[0036] 16 grams of aniline;

[0037] 1 gram of simethicone;

[0038] Propylene carbonate 5 g.

[0039] Under the protection of nitrogen, add liquid epoxy resin E42, plasticizer dibutyl phthalate, emulsifier OP-10, 1.5g isopropanol (as a co-emulsifier), distilled water, Ammonium sulfate was stirred rapidly for 2 hours to form a stable microemulsion system with epoxy resin and plasticizer as the oil phase and an aqueous solution of oxidant ammonium persulfate as the ...

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PUM

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Abstract

Disclosed environment-friendly type polyaniline shedding-preventing anticorrosion paint comprises a composition A and a composition B according to the A-to-B weight ratio of 10:1-20:1. The composition A is prepared from the following compositions: 96 g of liquid epoxy resin E42, 12 g of dibutyl phthalate, 4 g of OP-10, 8 g of isopropanol, 15 g of ammonium persulfate, 3 g of distilled water, 2 g of a camphorsulfonic acid aqueous solution with the concentration of 0.6 mol / L, 16 g of aniline, 1 g of simethicone and 5 g of propylene carbonate. The composition B is composed of the following compositions: 130 g of a liquid aliphatic polyamine, 40 g of polyaniline, 8 g of quartz sand, 8 g of 2-phenoxyethanol, 8 g of talcum powder, and 8 g of rosin glycerol ester. The paint has the advantages of high polyaniline content, good anticorrosion performance, no pollution, low cost and the like.

Description

technical field [0001] The invention relates to an environment-friendly polyaniline anti-shedding and anti-corrosion paint. Background technique [0002] The loss caused by metal corrosion to human beings is staggering. According to statistics, the global annual metal loss due to corrosion is as high as 20%-40% of global metal production, and the economic loss is about 1 trillion US dollars. Practice has proved that the use of coatings for corrosion protection of metals is the most economical, practical and effective method. However, the current commonly used anti-corrosion coatings contain a large amount of organic solvents, which cause great pollution to the environment during the construction process and pose a huge threat to the health of workers; at the same time, commonly used anti-corrosion coatings are also rich in zinc, which not only consumes a lot of zinc resources, but also affects the health of workers. The environment is seriously polluted by heavy metals....

Claims

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Application Information

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IPC IPC(8): C09D163/02C09D179/02C09D5/08C08G73/02
CPCC09D163/00C08G73/0266C08L2205/03C09D5/08C09D7/61C09D7/63C09D7/65
Inventor 董善刚刘永屏祝洒虎王伯凤张喆李春波殷晓燕潘金婷
Owner QINGDAO YIQUN PANT GRP
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