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High-strength gel for snubbing operation and preparation method of high-strength gel

A high-strength, jelly-gel technology is used in the application field of chemical agents in petroleum drilling and completion engineering, which can solve the problem that the bridge plug rubber core cannot be well adapted to different pipe diameters, the operator has high technical requirements, and restricts the snubbing operation. Development and other issues, to achieve the effects of controllable glue forming time, broadening the scope of application, and controllable body strength

Inactive Publication Date: 2015-05-20
YANGTZE UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, compared with the well killing operation, the snubbing operation has problems such as high equipment investment, complicated operation, various operation techniques, and high technical requirements for operators; the shortage of equipment includes: the plugging process of the plugging device takes a long time and the performance Unstable, the bridge plug rubber core can not be well adapted to different pipe diameters, etc., all of which restrict the development of snubbing operation technology in China
Existing literature has reported a large number of polymer jelly systems formed with modified starch as the main agent or gel systems with a certain strength formed with starch as a filler, but most of these jelly systems are formula compound systems. So far, there is no single report on the use of modified starch as a new material for the jelly system.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A kind of high-strength jelly for snubbing operation provided by the present invention, wherein the weight percent of each component is: cornstarch 3%, oxidation-reduction initiator ammonium persulfate 0.03%, sodium bisulfite 0.01%, cross Linking agent A melamine 10%, crosslinking agent B formaldehyde aqueous solution 7.5%, initiator monomer acrylamide 10%, curing agent urotropine 0.02%, and the rest is water.

[0029] Under stirring conditions, gelatinize 2g of corn starch in water at 75°C for 1 hour in a container, adjust its pH value to 10 after starch gelatinization, adjust its temperature to 80°C, and keep it at a constant temperature for 60 minutes, then proceed according to the proportion Add ammonium persulfate, sodium bisulfite, melamine, formaldehyde solution, acrylamide and urotropine and stir evenly, then continue to stand at the above temperature for 60 minutes to form a gel.

[0030] The obtained colloid has a viscosity of 30000mPa.s and a maximum plugging...

Embodiment 2

[0032] A kind of high-strength jelly for snubbing operation provided by the present invention, wherein the weight percent of each component is: cornstarch 3%, water-soluble oxidation-reduction gel initiator potassium persulfate 0.3% and sodium bisulfite 0.2%, cross-linking agent A melamine 10%, cross-linking agent B formaldehyde solution 8%, initiating monomer acrylamide 8% and sodium acrylate 2%, acryloyloxyethyltrimethylammonium chloride 2% and N,N '-methylenebisacrylamide 0.5%, curing agent ammonium sulfamate 0.02%, and the rest is water.

[0033] Under stirring conditions, gelatinize 4g of corn starch in water at 80°C for 1.5 hours in a container, adjust its pH value to 8 after starch gelatinization, adjust its temperature to 80°C, and keep it at a constant temperature for 50 minutes, then proceed according to the proportion Add potassium persulfate, sodium bisulfite, melamine, aqueous formaldehyde, ammonium sulfamate, acryloyloxyethyltrimethylammonium chloride, N,N'-methy...

Embodiment 3

[0036] A kind of high-strength jelly for snubbing operation provided by the present invention, wherein the weight percent of each component is: potato starch 4%, oxidation-reduction initiator potassium persulfate 0.5% and sodium bisulfite 0.2%, alternating Linking agent A amino resin 10%, crosslinking agent B glutaraldehyde 8%, initiator monomer acrylamide 7% and sodium acrylate 5%, N-methylol acrylamide 2%, N,N'-methylenebis Acrylamide 0.5%, curing agent ammonium chloride, and the rest is water.

[0037] Under stirring conditions, gelatinize 2.2g of potato starch in water at 75°C for 2 hours in a container. Add potassium persulfate, sodium bisulfite, amino resin, glutaraldehyde, acrylamide, sodium acrylate, N-methylolacrylamide, N,N'-methylenebisacrylamide and ammonium chloride in sequence and stir well , continue to stand at the above temperature for 90 minutes to form a gel.

[0038] The obtained colloid has a viscosity of 29000mPa.s and a maximum plugging pressure of 13....

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Abstract

The invention relates to a high-strength gel for snubbing operation and a preparation method of the high-strength gel. The high-strength gel is characterized by being prepared from the following components in percentage by weight: 2%-5% of starch; 0.01%-0.1% of an oxidation-reduction initiator, 5%-13% of a cross-linking agent, 5%-20% of a cross-linking agent B, 10%-15% of an inimer, 0.015-0.1% of a curing agent and the balance of water. The preparation method comprises the steps; under the condition of stirring, dexitrinizing the starch in water in a proportion at a temperature ranging from 60 to 90 DEG C for 1-3 hours and then regulating the pH value of the solution to the range of 8-13 at the temperature of 30-150 DEG C; standing at constant temperature, sequentially adding the oxidation-reduction initiator, the inimer, the cross-linking agent A, the cross-linking agent B and the curing agent in a proportion, and uniformly stirring all the materials, and further standing, thereby obtaining the high-strength gel. The obtained high-strength gel has extremely high compressive strength and tube wall adhesion, is capable of meeting the basic property requirements of the snubbing operation on a gel system and controllable in gelation time, gel strength and viscosity, and has the characteristics of simple process, easily available raw materials and low cost.

Description

Technical field: [0001] The invention relates to a high-strength jelly for snubbing operation and a preparation method thereof, and belongs to the technical field of chemical agent application in petroleum drilling and completion engineering. Background technique: [0002] The snubbing operation is to complete operations such as tripping the drilling tool, coring under pressure, logging, running screens, running workover or completion strings under the condition of under-balanced pressure in the formation. This technology can further protect and maintain the integrity of the formation. In the original state, the purpose of preventing reservoir pollution and improving the development effect is achieved. At the same time, compared with the well killing operation, the snubbing operation has problems such as high equipment investment, complicated operation, various operation techniques, and high technical requirements for operators; the shortage of equipment includes: the pluggi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F251/00C08F220/06C08F220/56C08F220/58C08F222/38C08F220/34C08F228/02C08F236/02C08F4/40C08J3/24C08B30/12
Inventor 程立张慢来李振刘德基雷宇廖锐全孙景壮陈瞰瞰尹玉川陈超石锋陶媛王涛姚普勇唐小强
Owner YANGTZE UNIVERSITY
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