A method of recovering nickel, cobalt, iron, silicon and magnesium from lateritic nickel ore

A technology for laterite nickel ore and pulp, which is applied in the directions of silicon oxide, silicon dioxide, and process efficiency improvement, can solve the problems of high acid consumption, low nickel and cobalt leaching rates, and high sulfuric acid consumption, and achieves low operating costs and operation. and the effect of simple maintenance and low investment cost

Inactive Publication Date: 2015-07-22
JINCHUAN GROUP LIMITED
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Problems solved by technology

But this method has the following disadvantages and deficiencies: First, the time for leaching limonite under normal pressure is longer, usually more than 4 hours, so the required normal pressure leaching equipment is huge; the second is that the acid consumption is higher, and the total acid / ore=0.6 / 1. Although this acid consumption index is far lower than atmospheric acid leaching, it is much higher than high-pressure acid leaching; third, the amount of saprolite ore used is twice that of limonite, which also contradicts the ore belt composition of laterite ore , it is well known that in lateritic nickel deposits, the amount of limonite: the amount of saprolite ≥ 2:1
[0019] In short, in the above-mentioned invention patents of lateritic nickel ore wet smelting, the disadvantages of the high-pressure acid leaching (HPAL) process and the improved high-pressure acid leaching process are: complex high-temperature, high-pressure autoclaves and related equipment are required, and their installation and Both are expensive to maintain; the HPAL process consumes more sulfuric acid than is required to stoichiometrically dissolve the non-ferrous components of the ore; the HPAL process is limited to processing mainly limonite-type feedstock; the HPAL process operates at high pressure The kettle is prone to fouling, and needs to be shut down regularly for cleaning, and the operating rate is low
The disadvantages of the atmospheric pressure acid leaching process and the improved atmospheric pressure acid leaching process are: high sulfuric acid consumption; low nickel and cobalt leaching rates; long reaction time and huge equipment required
The common disadvantage of high-pressure acid leaching including improved high-pressure acid leaching process and atmospheric pressure acid leaching process including improved atmospheric pressure acid leaching process is that the amount of leaching slag is large, and it is a mixed slag of silicon and iron, so that the main component of laterite ore, iron, cannot Economical and effective development and utilization
Although the invention patent of CN102206749A mentions the recycling of leaching slag, since the silicon dioxide, iron oxide, goethite, etc. Simple magnetic separation and other methods separate them, so the economic benefits of the development and utilization of the above-mentioned leaching slag are very poor, and they can only be treated as waste solids, and even the leaching slag with a low nickel leaching rate must be treated as hazardous waste.

Method used

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  • A method of recovering nickel, cobalt, iron, silicon and magnesium from lateritic nickel ore
  • A method of recovering nickel, cobalt, iron, silicon and magnesium from lateritic nickel ore
  • A method of recovering nickel, cobalt, iron, silicon and magnesium from lateritic nickel ore

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Embodiment 1

[0033] The present invention will be further described below, as appended figure 1 Shown:

[0034] 1. Take and grind to -80 mesh 500Kg2 # Add 500Kg water to saprolite ore to make saprolite slurry, prepare 500Kg98% concentrated sulfuric acid for use;

[0035] 2. Strictly control the flow rate with a mortar pump and a concentrated sulfuric acid pump. After rapid mixing, the saprolite slurry and concentrated sulfuric acid are flowed into the double-screw pusher reactor. The entire reaction takes 12 minutes. After the reaction, the material is a loose honeycomb solid paste. ,stand-by;

[0036] 3. After cooling down, simply crush the reaction material of the crisp honeycomb solid paste and pour it into the water immersion tank, add 1500Kg of water, carry out the water dissolving step, and stir for about 30 minutes;

[0037] 4. Pump the water-soluble slurry into the plate and frame filter press for solid-liquid separation and filter residue washing, and the pH value ratio is cont...

Embodiment 2

[0056] 1. Take and grind to -80 mesh 500Kg5 # Add 500Kg water to saprolite ore to make saprolite slurry, prepare 450Kg98% concentrated sulfuric acid for use;

[0057] 2. Strictly control the flow rate with a mortar pump and a concentrated sulfuric acid pump. After rapid mixing, the saprolite slurry and concentrated sulfuric acid are flowed into the double-screw pusher reactor. The entire reaction takes 10 minutes, and the material after the reaction is a crisp honeycomb solid paste. ,stand-by;

[0058] 3. After cooling down, simply crush the reaction material of the crisp honeycomb solid paste and pour it into the water immersion tank, add 1500Kg of water, carry out the water dissolving step, and stir for about 30 minutes;

[0059] 4. Pump the water-soluble slurry into the plate and frame filter press for solid-liquid separation and filter residue washing, and the pH value ratio is controlled at 0.5; obtain 230Kg of normal pressure acid leaching filter residue (A2), 1500L of ...

Embodiment 3

[0076] The normal-pressure acid leaching stage of the present embodiment is the same as that of Example 1, and in the pressure leaching stage, 1 # Sinka Limonite changed to 4 # Indonesian limonite.

[0077] Take 3000g4 # For limonite, add washing solution (E1) 6000ml to be mixed with limonite slurry and then move it into the autoclave, then add 3000ml of normal pressure acid leaching filtrate (B1) into the autoclave. After sealing the autoclave, control the temperature and heat. When the temperature rises to 215° C., continue heating at a constant temperature for 50 minutes, then stop heating and cool down. After cooling down to 80°C, the reaction slurry was removed from the autoclave for solid-liquid separation and the filter residue was washed to obtain 2800g of pressurized leaching residue (C3), 7550ml of pressurized leaching solution (D3) and 4500ml of washing solution (F3). See Table 3-1, Table 3-2 and Table 3-3 for the components of pressure leaching residue (C3), pre...

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Abstract

The invention relates to the technical field of hydrometallurgical processes of lateritic nickel ore, and particularly relates to a method of recovering nickel, cobalt, iron, silicon and magnesium from lateritic nickel ore. The method includes following steps: adding sufficient concentrated sulfuric acid into saprolite pulp, and reacting at 95-120 DEG C to dissolve most of soluble non-iron metals and soluble iron; performing solid liquid separation to obtain atmospheric-pressure leaching slag and atmospheric-pressure leachate; adding the atmospheric-pressure leachate and limonite ore pulp into a pressurized reactor according to a ratio and performing pressure leaching at 195-240 DEG C; performing solid liquid separation to obtain pressure leaching slag and leachate of pressure leaching; purifying the leachate of pressure leaching to recover the nickel and the cobalt; washing pressure leaching slag and drying to obtain a fine iron powder product; and screening the atmospheric-pressure leaching slag to obtain a high-grade silicon dioxide product and building sand. The method can achieve treatment of the saprolite and the limonite at the same time, and is high in nickel and cobalt leaching rates, small in atmospheric-pressure devices, short in time and high in efficiency. Waste slag is low in amount and can be effectively utilized.

Description

technical field [0001] The present invention relates to the hydrometallurgical process of lateritic nickel ore, in particular, it relates to carrying out sulfuric acid atmospheric pressure leaching of saprolite components of this ore and pressure leaching of limonite components with normal pressure leachate in the same process, Cost-effective recovery of part of the ore's silicon while recovering nickel, cobalt, iron and magnesium. Background technique [0002] Laterite ore is a nickel oxide ore formed by nickel-bearing peridotite after large-scale long-term weathering and leaching metamorphism in tropical or subtropical regions. Due to differences in geographical location, climatic conditions and weathering degrees, the types of laterite ore around the world are not completely the same People subjectively divide the laterite deposit into three layers from top to bottom, namely limonite layer, transitional layer and saprolite layer, in which limonite has fine particles, low ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B3/08C22B23/00C22B26/22C21B15/00C01B33/12
CPCY02P10/20
Inventor 刘玉强王少华刘月悦陈学安吴川眉杜昊郝增选张飞朱慧姚菲
Owner JINCHUAN GROUP LIMITED
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