Crosslinked ultrahigh molecular weight polyethylene fiber and wet preparation method thereof

A technology of ultra-high molecular weight polyethylene fiber, applied in the direction of single-component polyolefin artificial filament, wet spinning method, fiber chemical characteristics, etc., can solve the problems of fracture, mechanical strength and elongation resistance of ultra-high molecular weight polyethylene fiber High temperature performance, reduced creep resistance, etc.

Pending Publication Date: 2015-08-05
JIANGSU SHENTAI SCI & TECH DEV
View PDF5 Cites 15 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, high-energy radiation irradiation will cause a large number of breakage, disproportionation and dehydrogenation of ultra-high molecular weight polyethylene macromolecular...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Crosslinked ultrahigh molecular weight polyethylene fiber and wet preparation method thereof
  • Crosslinked ultrahigh molecular weight polyethylene fiber and wet preparation method thereof
  • Crosslinked ultrahigh molecular weight polyethylene fiber and wet preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0071] Weigh 3 parts by weight of ultra-high molecular weight polyethylene powder (Gur 4022 of Ticona Company, the molecular weight range is 3 million), 0.003 parts by weight of antioxidant 2,6-di-tert-butylphenol, polar modifier 2-phenoxy 0.003 parts by weight of ethyl ethyl acrylate and 100 parts by weight of solvent white oil, the above raw materials were thoroughly mixed to prepare a spinning solution with a polyethylene concentration of 3 wt%. In spinning equipment (produced by Jiangsu Shentai Technology Development Co., Ltd., spinning temperature: screw preheating zone: 60~110°C, melting zone: 150°C, metering zone: 160°C, compression zone: 170°C, box temperature : 170 ℃), the spinning solution is extruded and spun by a screw to form jelly yarn. The jelly yarn is pre-stretched 1.2 times at room temperature, and is extracted with hydrocarbon cleaning agent 103 to form extraction yarn, and the extraction yarn is processed. Two-stage drying, respectively drying at 40°C for 1...

Embodiment 2

[0081] Take by weighing 3 parts by weight of ultra-high molecular weight polyethylene powder (the ultra-high molecular weight adopts Gur4022 of Ticona Company, the molecular weight range is 4 million), antioxidant 2,6-di-tert-butylphenol and 4,4'-thiobis( 0.003 parts by weight of 6-tert-butyl-3-methylphenol), 0.003 parts by weight of polar modifier lauric acid acrylate, and 100 parts by weight of solvent mineral oil. The above raw materials were thoroughly mixed to prepare a spinning solution with a polyethylene concentration of 4 wt%. In spinning equipment (produced by Jiangsu Shentai Technology Development Co., Ltd., spinning temperature: screw preheating zone: 60~110°C, melting zone: 150°C, metering zone: 160°C, compression zone: 170°C, box temperature: 170°C), the spinning solution was extruded through a screw to form jelly yarn, which was pre-stretched 1.2 times at room temperature, extracted with xylene to form extraction yarn, and the extraction yarn was dried in two st...

Embodiment 3

[0085] Take by weighing 3 parts by weight of ultra-high molecular weight polyethylene powder (the ultra-high molecular weight adopts Gur4022 of Ticona Company, the molecular weight range is 5 million), antioxidant 1010 is 0.01 parts by weight, antioxidant 4,4'-thiobis(6 - 0.006 parts by weight of tert-butyl-3-methylphenol), 0.003 parts by weight of cyclotrimethylolpropane acetal acrylate as a polar modifier, and 100 parts by weight of solvent mineral oil. The above raw materials were thoroughly mixed to prepare a spinning solution with a polyethylene concentration of 3 wt%. In spinning equipment (produced by Jiangsu Shentai Technology Development Co., Ltd., spinning temperature: screw preheating zone: 60~110°C, melting zone: 150°C, metering zone: 160°C, compression zone: 170°C, box temperature : 170°C), the above spinning solution is extruded through a screw to form jelly yarn, which is pre-stretched 1.2 times at room temperature, extracted with No. 120 gasoline to form extrac...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Average denieraaaaaaaaaa
Login to view more

Abstract

The invention relates to a crosslinked ultrahigh molecular weight polyethylene fiber and a wet preparation method thereof. The decreasing rate of the weight-average molecular weight of ultrahigh molecular weight polyethylene caused by radiation or irradiation splitting is less than 10%. The ultrahigh molecular weight polyethylene fiber disclosed by the invention has excellent heat resistance and creep resistance and high mechanical strength, and therefore, the ultrahigh molecular weight polyethylene fiber is especially suitable for preparing bulletproof vests, helmets, lightweight armors, sails, mooring ropes, fishing nets, optical cable reinforcement bodies, parachutes, filter materials, radomes, wind turbine blades and the like which are ultrahigh in mechanical strength and heat resistance.

Description

technical field [0001] The invention relates to polyethylene fiber and its preparation method, in particular to ultra-high molecular weight polyethylene fiber and its preparation method. Background technique [0002] UHMWPE fiber is the third-generation high-performance fiber after carbon fiber and aramid fiber. It has mechanical properties unmatched by other high-performance fibers. In addition, it also has excellent chemical resistance, weather resistance, and high energy. Absorption, impact resistance, low temperature resistance, wear resistance, bending resistance, cutting resistance, electrical insulation, electron beam or γ-ray penetration, water resistance and other excellent properties, are widely used in military bulletproof, safety protection, aerospace Nautical engineering and high-performance, lightweight composite materials and sports equipment, for example, for such as ropes, fishing nets, medical devices, fabrics, laminates, composite products and bulletproof ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): D01F6/46D01F1/10D01F13/04D01D5/06
CPCY02P70/62
Inventor 郭子贤王依民王新营倪建华王新鹏罗晓娟
Owner JIANGSU SHENTAI SCI & TECH DEV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap