PIA (meta-phthalic acid)/nanometer titania modified alkyd resin and preparation method thereof

A nano-titanium dioxide, alkyd resin technology, applied in the direction of coating, can solve the problems of unsatisfactory coating hardness, poor weather resistance, corrosion resistance and water resistance, etc., to improve hardness, good compatibility, The effect of increasing the drying speed

Active Publication Date: 2015-09-23
ANHUI JINDUN PAINT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although water-based alkyd resin has many excellent properties, it also has disadvantages. Its molecular structure contains more ester groups, resulting in unsatisfactory hardness of the produced coating film, and poor weather resistance, corrosion resistance and water resistance. , in order to overcome the shortcomings of alkyd resin and expand its application range, it needs to be modified

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A kind of PIA / nanometer titanium dioxide modified alkyd resin proposed by the present invention, its raw material comprises the following components by weight: 10 parts of acrylic acid, 10 parts of methacrylic acid, 15 parts of methyl methacrylate, vinyl triethoxy 3 parts of silane, 25 parts of nano-titanium dioxide, 15 parts of epoxy resin, 35 parts of castor oil, 8 parts of trimethylolpropane, 8 parts of 2,2,4-trimethyl-1,3-pentanediol, tetrachloro 8 parts of phthalic anhydride, 8 parts of PIA waste, 6 parts of trimellitic anhydride, 10 parts of triethylamine, 5 parts of ethylene glycol monobutyl ether, 25 parts of propylene glycol monobutyl ether, 3 parts of lauric acid, 0.05 parts of catalytic promoter, 1 part of benzoyl peroxide, 50 parts of xylene, 20 parts of water.

[0026] The preparation method of PIA / nanometer titanium dioxide modified alkyd resin proposed in the present invention may further comprise the steps:

[0027] S1. Using vinyltriethoxysilane to mod...

Embodiment 2

[0032] A kind of PIA / nanometer titanium dioxide modified alkyd resin proposed by the present invention, its raw material comprises the following components by weight: 20 parts of acrylic acid, 8 parts of methacrylic acid, 30 parts of methyl methacrylate, vinyl triethoxy 8 parts of silane, 10 parts of nano-titanium dioxide, 20 parts of epoxy resin, 20 parts of castor oil, 15 parts of trimethylolpropane, 3 parts of 2,2,4-trimethyl-1,3-pentanediol, tetrachloro 15 parts of phthalic anhydride, 3 parts of PIA waste, 10 parts of trimellitic anhydride, 2 parts of triethylamine, 10 parts of ethylene glycol monobutyl ether, 8 parts of propylene glycol monobutyl ether, 10 parts of lauric acid, 0.01 parts of catalytic promoter, 2 parts of benzoyl peroxide, 35 parts of xylene, 50 parts of water.

[0033] The preparation method of PIA / nanometer titanium dioxide modified alkyd resin proposed in the present invention may further comprise the steps:

[0034] S1. Using vinyltriethoxysilane to ...

Embodiment 3

[0039] A kind of PIA / nanometer titanium dioxide modified alkyd resin proposed by the present invention, its raw material comprises the following components by weight: 16 parts of acrylic acid, 9.2 parts of methacrylic acid, 21 parts of methyl methacrylate, vinyl triethoxy 6 parts of silane, 20 parts of nano-titanium dioxide, 18 parts of epoxy resin, 28 parts of castor oil, 12 parts of trimethylolpropane, 6.6 parts of 2,2,4-trimethyl-1,3-pentanediol, tetrachloro 12 parts of phthalic anhydride, 6.6 parts of PIA waste, 8.3 parts of trimellitic anhydride, 7 parts of triethylamine, 8 parts of ethylene glycol monobutyl ether, 19 parts of propylene glycol monobutyl ether, 7 parts of lauric acid, dibutyltin dilaurate 0.01 part, 0.01 part of stannous octoate, 0.01 part of di(dodecylsulfide)-dibutyltin, 0.005 part of dibutyltin diacetate, 1.7 parts of benzoyl peroxide, 39 parts of xylene, and 40 parts of water.

[0040] The preparation method of PIA / nanometer titanium dioxide modified a...

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PUM

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Abstract

The invention discloses a PIA (meta-phthalic acid)/nanometer titania modified alkyd resin and a preparation method thereof. The PIA/nanometer titania modified alkyd resin comprises the following raw materials: acrylic acid, methylacrylic acid, methyl methacrylate, vinyltriethoxysilane, nanometer titania, epoxy resin, castor oil, trimethylolpropane, 2,2,4-trimethyl-1,3-pentanediol, tetrachlorophthalic anhydride, PIA waste, trimellitic anhydride, triethylamine, ethyl eneglycol monobutyl ether, propylene glycol mono-n-butyl ether, lauric acid, catalytic auxiliary, benzoyl peroxide, dimethylbenzene and water. The PIA/nanometer titania modified alkyd resin provided by the invention is good in water resistance, high in hardness and excellent in comprehensive performance; the PIA waste is used, so that the cost is saved.

Description

technical field [0001] The invention relates to the technical field of alkyd resins, in particular to a PIA / nano titanium dioxide modified alkyd resin and a preparation method thereof. Background technique [0002] Alkyd resin is the most widely used synthetic resin in the paint industry. It has the advantages of low price, simple construction, easy access to raw materials, low acid value, good solubility of various organic solvents, and good performance on pigments and fillers. Excellent wetting and dispersibility, and after curing, it is glossy and tough, has strong adhesion, and has good wear resistance, weather resistance and insulation, etc. It has been used in many fields. [0003] Isophthalic acid (1,3-phthalic acid, English abbreviation IPA, high-purity product called PIA) is a white crystalline solid with strong heat resistance, water resistance and chemical resistance, easy to deflagrate, It can be sublimated and is mainly used in the production of unsaturated pol...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/01C08F220/06C08F220/14C08F2/44C08K9/06C08K3/22C08G63/49C08G63/78C09D151/08
Inventor 朱恒衡张国胜梅长林
Owner ANHUI JINDUN PAINT
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