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Super capacitor electrode material

A technology for supercapacitors and electrode materials, which is applied in the direction of hybrid capacitor electrodes, etc., can solve the problems of easy agglomeration and the performance advantages of graphene cannot be fully utilized, and achieve effective utilization, easy preparation, and improved dispersion and adhesion. Effect

Inactive Publication Date: 2015-09-23
CHINA FIRST AUTOMOBILE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the two-dimensional nanosheet structure of graphene, it is easy to reunite together, and the performance advantages of graphene cannot be fully utilized.

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0019] Weigh 2 parts of polyacrylonitrile, 29 parts of porous graphene, and 69 parts of activated carbon, dissolve polyacrylonitrile in the solution formed by DMF, add porous graphene (specific surface area 2200 m 2 / g) Ultrasonic for 1h, then add activated carbon and stir for 3h; remove DMF, dry to constant weight at 100°C to obtain polyacrylonitrile-treated supercapacitor electrode materials, such as figure 1 , 2 shown.

[0020] Weigh 90 parts of electrode material, 5 parts of conductive agent and 5 parts of binder (graphene and activated carbon), acetylene black, CMC and SBR (CMC:SBR=2:3, SBR is 50% emulsion). After the CMC was dissolved in deionized water, the electrode material was added and stirred for 1 hour, then the SBR emulsion was added, and the stirring was continued for 2 hours, and the slurry was allowed to stand for defoaming. The uniformly mixed slurry was coated on aluminum foil, vacuum-dried, and cut to serve as a supercapacitor electrode. piece.

Embodiment 2

[0022] Weigh 2 parts of polytetrafluoroethylene, 30 parts of porous graphene, and 68 parts of activated carbon. 2 / g) Ultrasonic in deionized water for 1h to form a mixed solution, add activated carbon and ethanol of the same mass as activated carbon, stir for 2h, add polytetrafluoroethylene emulsion (60%), continue to stir for 2h, remove deionized water, and dry at 80°C to a constant weight to obtain a PTFE-treated supercapacitor electrode material, such as image 3 , 4 shown.

[0023] Weigh 90 parts of electrode material, 5 parts of conductive agent and 5 parts of binder (graphene and activated carbon), VGCF, CMC and SBR (CMC:SBR=2:3, SBR is 50% emulsion). After the CMC was dissolved in deionized water, the electrode material was added and stirred for 2 hours, then the SBR emulsion was added, and the stirring was continued for 3 hours. Let it stand for defoaming, and then coat the evenly mixed slurry on aluminum foil, vacuum dry, and cut it as a supercapacitor electrode. ...

Embodiment 3

[0025] Weigh 0.1 parts of polyethersulfone, 9.9 parts of porous graphene, and 90 parts of activated carbon, and weigh the porous graphite (specific surface area 1500 m 2 / g) alkene was added to the DMF solution and sonicated for 1 h to form a mixed solution, polyethersulfone was added to ultrasonic for 1 h, then activated carbon was added, and stirred for 2 h; DMF was removed, and dried at 100 °C to constant weight to obtain a polyethersulfone-treated supercapacitor electrode material, such as Figure 5 , 6 shown.

[0026] Weigh 90 parts of electrode material, 5 parts of conductive agent and 5 parts of binder (graphene and activated carbon), carbon nanotubes, CMC and SBR, (CMC:SBR=2:3, SBR is 50% emulsion). After the CMC was dissolved in deionized water, the electrode material was added and stirred for 1 hour, then the SBR emulsion was added, and the stirring was continued for 2 hours, and the slurry was allowed to stand for defoaming. The uniformly mixed slurry was coated on...

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Abstract

The invention relates to a super capacitor electrode material. The super capacitor electrode material comprises active carbon, graphene and a polymer, and is characterized in that the polymer treats the active carbon and the graphene. The super capacitor electrode material consists of the following components in parts by weight: 0.1-2 parts of the polymer, 30-90 parts of the active carbon and 8-70 parts of the graphene. The graphene is of a porous structure, and is 1,500-2,200m<2> / g in specific surface area. The polymer treats the active carbon and the graphene, so that the dispersion of the graphene and effective utilization of the specific surface area are improved, and the performance of the electrode material is enhanced.

Description

technical field [0001] The invention relates to a supercapacitor electrode material, in particular to an electrode material prepared by treating activated carbon and graphene with a polymer. Background technique [0002] Supercapacitors are a promising new energy vehicle power source with the advantages of high specific power, long cycle life, high current charge and discharge, environmental friendliness, safety and maintenance-free. The electrode is the core component of the supercapacitor, and the electrode material directly affects the performance of the supercapacitor. At present, the commonly used electrode material is activated carbon. [0003] With the development of nanomaterials, two-dimensional graphene materials with lamellar structures have attracted extensive attention. Combining it with electrode materials can improve the performance of supercapacitors. However, due to the two-dimensional nanosheet structure of graphene, which makes it easy to agglomerate tog...

Claims

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Application Information

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IPC IPC(8): H01G11/24H01G11/34H01G11/36
CPCY02E60/13H01G11/24H01G11/34H01G11/36H01G11/48
Inventor 荣常如陈书礼韩金磊张克金魏晓川
Owner CHINA FIRST AUTOMOBILE