Single molecular magnet Dy2 (salen) 2 (tta) 4 (OAc) 2 and preparation method of single molecular magnet
A single-molecule magnet, c84h56dy2f12n4o16s4 technology, applied in chemical instruments and methods, inductance/transformer/magnet manufacturing, organic material/organic magnetic material magnetism, etc. It can solve the problems of complex synthesis method, etc., to achieve the effect of strong repeatability, high yield and simple synthesis method.
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specific Embodiment approach 1
[0024] Embodiment 1: This embodiment is a single-molecule magnet Dy 2 (sale) 2 (tta) 4 (OAc) 2 The molecular formula is C 84 h 56 Dy 2 f 12 N 4o 16 S 4 , the crystal system is triclinic, the space group is P-1, and the unit cell parameters are α=95.80(3)°, β=100.18(3)°, γ=90.38(3)°, V=1967.8(7), Z=1.
[0025] The advantage of this implementation mode:
[0026] 1. In this embodiment, rare earth ions and ligands are coordinated through solution diffusion, and rare earth complexes with excellent properties are obtained after crystallization;
[0027] Two, the Dy prepared in this embodiment 2 (sale) 2 (tta) 4 (OAc) 2 It is a single-molecule magnet with high energy barrier, and the production rate of the preparation method of the present invention is high, which can reach more than 57.26%. The synthesis method of the single-molecule magnet is simple and has strong repeatability.
[0028] This embodiment can obtain a single molecular magnet Dy 2 (sale) 2 (tta) ...
specific Embodiment approach 2
[0029] Specific embodiment two: this embodiment is a single molecule magnet Dy 2 (sale) 2 (tta) 4 (OAc) 2 The preparation method is prepared according to the following steps:
[0030] 1. Dissolving ethylenediamine salicylaldehyde in dichloromethane to obtain solution A; dissolving cadmium acetate in methanol to obtain solution B; then mixing solution A and solution B to obtain mixed solution C;
[0031] The volume ratio of the amount of substance of ethylenediamine salicylaldehyde described in step 1 to methylene chloride is (0.125mol~0.13mol): 1L;
[0032] The amount of substance of cadmium acetate described in step one and the volume ratio of methanol are (0.125mol~0.13mol): 1L;
[0033] The mol ratio of ethylenediamine salicylaldehyde and cadmium acetate in the mixed solution C described in step 1 is 1:1;
[0034] 2. Heat the mixed solution C obtained in step 1 to reflux at a temperature of 70°C to 80°C for 1h to 1.5h, then cool to room temperature, and then filter to ...
specific Embodiment approach 3
[0043] Embodiment 3: The difference between this embodiment and Embodiment 2 is that the volume ratio of the amount of ethylenediamine salicylaldehyde described in step 1 to methylene chloride is 0.125mol:1L. Others are the same as in the second embodiment.
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