High-performance methanol gasoline catalyst

A methanol gasoline and catalyst technology, which is applied in the field of high-performance methanol gasoline catalysts, can solve the problems of metal corrosion and rubber swelling, restricting the development of methanol gasoline, and small replacement ratio, achieving low cost, inhibiting the formation of polar substances such as sludge, etc. The effect of reducing the saturated vapor pressure

Inactive Publication Date: 2015-11-11
CRPC INNOVATION ENERGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Methanol gasoline has a high octane number, is clean and environmentally friendly, and has good combustibility. It is the best alternative energy source for gasoline, but there are still technical problems such as small replacement ratio, poor stability, moisture stratification, metal corrosion and rubber swelling, which restrict the use of methanol gasoline. Development, in which the substitution ratio and stability are key issues, including the compatibility of methanol and gasoline, water resistance and low temperature stability, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A kind of high-performance methanol gasoline catalyst, the preparation method of described catalyst is as follows:

[0032] (1) Combustion catalyst prepared by mixing 4 parts of triethanolamine, 4 parts of propylene glycol, 2 parts of copper nitrate, 2 parts of ethyl acetate and 3 parts of sodium carbonate in parts by weight;

[0033] (2) The antioxidant is obtained by mixing 3 parts of 2,6-di-tert-butyl-p-cresol, 2 parts of primary-secondary zinc salt of phosphophosphine and 3 parts of glycerol triacetate in parts by weight;

[0034] (3) In parts by weight, 15 parts of isopentane, 22 parts of xylene, 10 parts of combustion catalyst, 5 parts of isopropanol, 2 parts of 3-nitrophenylhydrazine, 13 parts of diethyl ether, diethyl 15 parts of sodium dithiocarbamate were mixed uniformly at a temperature of 50° C. to obtain initial material A;

[0035] (4) In parts by weight, 18 parts of C12 and 12 parts of acetylacetone were uniformly mixed at a temperature of 55° C. to obta...

Embodiment 2

[0038] A kind of high-performance methanol gasoline catalyst, the preparation method of described catalyst is as follows:

[0039] (1) Combustion catalyst prepared by mixing 3 parts of triethanolamine, 2 parts of propylene glycol, 1 part of copper nitrate and 2 parts of sodium carbonate in parts by weight;

[0040] (2) The antioxidant is obtained by mixing 2 parts of 2,6-di-tert-butyl-p-cresol, 1 part of primary-secondary zinc salt of phosphophosphine and 1 part of glycerol triacetate in parts by weight;

[0041] (3) In parts by weight, 10 parts of isopentane, 18 parts of xylene, 5 parts of combustion catalyst, 1 part of isopropanol, 1 part of 3-nitrophenylhydrazine, 12 parts of diethyl ether, 9 parts of sodium dithiocarbamate were mixed uniformly at a temperature of 50° C. to obtain initial material A;

[0042] (4) In parts by weight, 15 parts of C12 and 8 parts of acetylacetone were uniformly mixed at a temperature of 50° C. to obtain raw material B;

[0043] (5) Mix prima...

Embodiment 3

[0045] A kind of high-performance methanol gasoline catalyst, the preparation method of described catalyst is as follows:

[0046] (1) Combustion catalyst prepared by mixing 5 parts of triethanolamine, 6 parts of propylene glycol, 4 parts of copper nitrate, 3 parts of ethyl acetate and 5 parts of sodium carbonate in parts by weight;

[0047] (2) In parts by weight, an antioxidant is prepared by mixing 6 parts of 2,6-di-tert-butyl-p-cresol, 3 parts of primary-secondary zinc salt of phosphophosphine and 5 parts of glycerol triacetate;

[0048] (3) In parts by weight, 20 parts of isopentane, 25 parts of xylene, 15 parts of combustion catalyst, 8 parts of isopropanol, 3 parts of 3-nitrophenylhydrazine, 16 parts of diethyl ether, diethyl 21 parts of sodium dithiocarbamate were mixed uniformly at a temperature of 50° C. to obtain initial material A;

[0049] (4) In parts by weight, 22 parts of C12 and 15 parts of acetylacetone were uniformly mixed at a temperature of 55° C. to obta...

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PUM

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Abstract

The invention relates to a high-performance methanol gasoline catalyst which consists of the following components in parts by weight: 10-20 parts of isopentane, 18-25 parts of dimethyl benzene, 5-15 parts of a combustion catalyst, 1-8 parts of isopropanol, 2-8 parts of an antioxidant, 1-3 parts of 3-nitrophenyl hydrazine, 3-6 parts of a T1201 metal passivating agent, 12-16 parts of diethyl ether, 15-22 parts of C-12, 8-15 parts of acetylacetone and 9-21 parts of sodium diethyldithiocarbamate. The high-performance methanol gasoline catalyst can be used for improving the compatibility and low-temperature stability of methanol gasoline and ensuring that the methanol gasoline has certain water resistance.

Description

technical field [0001] The invention relates to an alternative energy source for vehicles, more specifically, it belongs to a high-performance methanol gasoline catalyst. Background technique [0002] Since the emergence of the second oil crisis in the 1970s, many scholars and entrepreneurs around the world have conducted extensive trial research on methanol gasoline, an alternative fuel for vehicles. The United States, Germany, Japan, Sweden and other countries have developed methanol gasoline And applications have given a lot of financial support and policy preference. my country has actively developed methanol gasoline since the 1980s, and has entered the promotion and practical stage of M15-M30. The world is about to enter the post-oil era. According to the predictions of the U.S. Department of Energy and the World Energy Council, the global petroleum energy can be exploited for more than 30 years, and China's exploitable life is less than 20 years. China's national con...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L1/10C10L1/16C10L1/182C10L1/23C10L1/185C10L1/24C10L1/222C10L1/12C10L1/19C10L1/183C10L1/30
Inventor 王菊林
Owner CRPC INNOVATION ENERGY
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