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Resistance reduction agent for oil well fracturing and preparation method of resistance reduction agent

A drag-reducing agent and technology for oil wells, applied in the field of low-permeability fracturing chemicals and deep wells, can solve the problems of high interfacial tension, affecting construction, and high pressure, achieving broad application prospects, good resistance-reducing performance, and good solubility. Effect

Inactive Publication Date: 2016-01-13
西安长庆化工集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In stratum reconstruction, fracturing is generally adopted in order to increase the expansion of channels and seepage area. With the development of oilfields, more and more deep wells and low-permeability wells are reconstructed. Due to deep burial and compact formation, fracturing During the transformation, the flow resistance of the liquid in the pipeline is relatively high, resulting in excessive pressure, which reduces the construction efficiency and affects the normal construction. In order to reduce the friction of the fracturing fluid in the pipe string and achieve the purpose of effective fracturing, Add drag reducing agent in fracturing; the prior art generally utilizes the thickening effect of high molecular weight polymer to achieve drag reducing effect. In summary, the current drag reducing agents all have the following disadvantages: , the interfacial tension is high, which is not conducive to flowback. In order to improve the flowback efficiency of the gel breaking solution, it is often necessary to add a drainage aid

Method used

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  • Resistance reduction agent for oil well fracturing and preparation method of resistance reduction agent

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Effect test

Embodiment 1

[0037] In order to overcome the shortcomings of the prior art, provide a drag reducing agent for oil well fracturing with good water solubility, low frictional resistance, and low interfacial tension after gel breaking, and when the drag reducing agent is used, no need to add drainage aids, Fast flowback can be achieved. This embodiment provides a drag reducer for oil well fracturing and its preparation method, including component A and component B. In terms of mass ratio, component A:component B=20 : 80, the component A includes the following components: 25-37.5 parts of acrylamide, 5-50 parts of hydrophilic monomer, 2.5-10 parts of sodium hydroxide, 1.25 parts of persulfate, 1 part of sodium bisulfite , 150.25 to 215.25 parts of water, the component B includes the following components: 450 to 880 parts of hydrophobic monomer, 100 to 400 parts of span, 10 to 100 parts of alkylphenol polyoxyethylene ether, 10 to 50 parts of alcohol Amine salt type anionic fluorocarbon surfacta...

Embodiment 2

[0045] This embodiment provides a drag reducing agent for oil well fracturing, which is prepared according to the following raw material components:

[0046] Add 25g of acrylamide, 2.5g of 2-acrylamide-2-methylpropanesulfonic acid, and 2.5g of acrylic acid into a four-necked flask filled with 215.25g of water, and add 2.5g of sodium hydroxide under stirring conditions to dissolve completely;

[0047] ② Add 100g of Span 85, 10g of alkylphenol polyoxyethylene ether, and 10g of alcohol amine salt type anionic fluorocarbon surfactant into 880g of n-hexane and stir evenly;

[0048] ③The steps The temperature of the solution was controlled to 13~14°C; nitrogen gas was introduced for 20 minutes, and 1.25g ammonium persulfate and 1g sodium bisulfite were added in sequence;

[0049] ④Under the emulsification condition of the emulsifier, the step Solution slow addition step solution, and the temperature was raised to 60° C., and reacted for 1 hour to obtain the drag reducing age...

Embodiment 4

[0065] This embodiment provides a drag reducing agent for oil well fracturing, which is prepared according to the following raw material components:

[0066] Add 37.5g of acrylamide, 25g of 2-acrylamide-2-methylpropanesulfonic acid, and 25g of acrylic acid into a four-necked flask filled with 150.25 g of water, and add 10 g of sodium hydroxide under stirring conditions to dissolve completely;

[0067] 2. Add 400g Span 85, 100g alkylphenol polyoxyethylene ether, 50gI alcohol amine salt type anionic fluorocarbon surfactant into 450g n-hexane and stir;

[0068] ③The steps The temperature of the solution was controlled to 13~14°C; nitrogen gas was introduced for 20 minutes, and 1.25g ammonium persulfate and 1g sodium bisulfite were added in sequence;

[0069] ④Under the emulsification condition of the emulsifier, the step Solution slow addition step solution, and the temperature was raised to 60° C., and reacted for 1 hour to obtain the drag reducing agent.

[0070] Perfo...

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Abstract

The invention provides a resistance reduction agent for oil well fracturing. The resistance reduction agent for oil well fracturing comprises components A and components B., and the ratio of the components A to the components B is 20:80. The components A comprise 25-37.5 parts of acrylamide, 5-50 parts of hydrophilic monomers, 2.5-10 parts of sodium hydroxide, 1.25 parts of persulfate and 150.25-215.25 parts of water. The components B comprise 450-880 parts of hydrophobic monomers, 100-400 parts of spans, 10-100 parts of alkylphenol ethoxylates and 10-50 parts of alcohol amine salt type anionic fluorocarbon surfactants. Raw materials of the resistance reduction agent are easy to obtain, the preparation technology is simple, water solubility is good, friction resistance is reduced by more than 60%, the interface tension is below 10-2 mN / m after gel breaking, when the resistance reduction agent is used, fast flowback can be achieved while no discharge adding agent needs to be added, and wide application prospects are achieved.

Description

technical field [0001] The invention belongs to the research field of chemical agents for deep well and low permeability fracturing, and in particular relates to a drag reducing agent for oil well fracturing and a preparation method thereof. Background technique [0002] In stratum reconstruction, fracturing is generally adopted in order to increase the expansion of channels and seepage area. With the development of oilfields, more and more deep wells and low-permeability wells are reconstructed. Due to deep burial and compact formation, fracturing During the transformation, the flow resistance of the liquid in the pipeline is relatively high, resulting in excessive pressure, which reduces the construction efficiency and affects the normal construction. In order to reduce the friction of the fracturing fluid in the pipe string and achieve the purpose of effective fracturing, Add drag reducing agent in fracturing; the prior art generally utilizes the thickening effect of high...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/68C08F220/56C08F220/06C08F220/58
CPCC08F220/56C09K8/604C09K8/68C09K8/882C09K2208/28C08F220/06C08F220/585
Inventor 万华杜彪丁里叶智李晓玲周小玉程芳李强苗林潘谦宏
Owner 西安长庆化工集团有限公司
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