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Catalyst for injecting air into thick oil for oxidation and viscosity reduction

A technology of air injection and catalyst for heavy oil, applied in physical/chemical process catalyst, organic compound/hydride/coordination complex catalyst, refining with oxygenated compounds, etc. Viscosity increase, heavy oil viscosity increase, etc., to achieve the effect of reducing viscosity, good thermal stability, and good oil solubility

Inactive Publication Date: 2016-02-17
宋宏婷
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The problem is that if the oxidation rate of crude oil is slow, oxygen breakthrough is likely to occur, leading to high oxygen content, which will cause safety problems. In addition, the viscosity of heavy oil usually increases after oxidation. Therefore, how to increase the oxidation rate of heavy oil and It is of great significance to improve the properties of oxidized heavy oil
The catalyst is composed of iron, cobalt, nickel, copper, zinc, molybdenum, chromium sulfate and chloride; iron, manganese, copper, zinc, nitrate and carbonate; cobalt, copper, zinc oxalate With acetate; cobalt, copper, zinc, manganese, iron benzoate; iron, manganese, copper, zinc phthalate and other metal salt catalysts with urea, sodium carbonate, sodium bicarbonate, ammonium bicarbonate , Ammonium Bicarbonate, Sodium Hydroxide, Potassium Hydroxide and other additives, the composite catalyst was tested with heavy oil at 150°C-250°C by air injection catalytic oxidation, and it was found that this type of catalyst can accelerate the oxygen consumption of heavy oil Speed, but there are problems such as serious increase in the viscosity of oxidized heavy oil after the reaction

Method used

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  • Catalyst for injecting air into thick oil for oxidation and viscosity reduction

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Experimental program
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Effect test

Embodiment 1

[0038] Such as figure 1 As shown, a heavy oil injection air oxidation viscosity reduction catalyst is composed of 59.8% polymer carrier, 8.3% metal hydroxide, 12.3% metal linoleate, 5.3% benzoic acid and 14.3% petroleum sulfonate.

[0039] The polymer carrier consisted of 48% lauryl methacrylate, 23% cetyl methacrylate and 29% behenyl methacrylate.

[0040] The metal hydroxide consists of 25% iron hydroxide, 36% zinc hydroxide, 15% manganese hydroxide and 24% nickel hydroxide.

[0041] Metal linoleate consists of 46% molybdenum linoleate and 54% nickel linoleate.

Embodiment 2

[0043] Such as figure 1 As shown, a heavy oil injection air oxidation viscosity reduction catalyst is composed of 70.2% polymer carrier, 5.7% metal hydroxide, 9.7% metal linoleate, 2.7% benzoic acid and 11.7% petroleum sulfonate.

[0044]The polymer carrier consisted of 36% lauryl methacrylate, 29% cetyl methacrylate and 35% behenyl methacrylate.

[0045] The metal hydroxide consists of 43% iron hydroxide, 18% zinc hydroxide, 33% manganese hydroxide and 6% nickel hydroxide.

[0046] Metal linoleate is composed of 70% molybdenum linoleate and 30% nickel linoleate.

Embodiment 3

[0048] Such as figure 1 As shown, a heavy oil injection air oxidation viscosity reduction catalyst is composed of 65% polymer carrier, 7% metal hydroxide, 11% metal linoleate, 4% benzoic acid and 13% petroleum sulfonate.

[0049] The polymer carrier consisted of 42% lauryl methacrylate, 26% cetyl methacrylate and 32% behenyl methacrylate.

[0050] The metal hydroxide consists of 34% iron hydroxide, 27% zinc hydroxide, 24% manganese hydroxide and 15% nickel hydroxide.

[0051] Metal linoleate is composed of 58% molybdenum linoleate and 42% nickel linoleate.

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PUM

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Abstract

The invention discloses a catalyst for injecting air into thick oil for oxidation and viscosity reduction, and belongs to the field of catalysts. The catalyst for injecting air into the thick oil for oxidation and viscosity reduction is prepared from 59.8%-70.2% of polymer carriers, 5.7%-8.3% of metal hydroxide, 9.7%-12.3% of metal potassium linoleate, 2.7%-5.3% of benzoic acid and 11.7%-14.3% of petroleum sulfonate. The catalyst for injecting air into the thick oil for oxidation and viscosity reduction has the advantages that the structure of the thick oil is improved, the viscosity of the oxidized thick oil is reduced, and therefore the oil recovery rate is increased through injecting air into the thick oil for catalytic oxidation.

Description

technical field [0001] The invention relates to a catalyst, in particular to a heavy oil air injection oxidation viscosity reducing catalyst. Background technique [0002] The distribution of heavy oil resources in my country is very extensive. More than 70 heavy oil fields have been discovered in 12 basins, and the estimated resources can reach more than 300×108t. With the reduction of light oil production reserves and the continuous improvement of oil production technology, the proportion of heavy oil production in the 21st century will continue to increase. For example, the production of high pour point oil and super heavy oil in Liaohe Oilfield have always accounted for a large proportion; Since 2000, Shengli Oilfield has an annual production capacity of thermally recovered heavy oil exceeding 140×104t, and 70% of the oil reserves discovered offshore are also heavy oil. Since heavy oil was exploited in the 1960s, heavy oil thermal recovery technologies such as steam huf...

Claims

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Application Information

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IPC IPC(8): B01J31/34C10G27/04
Inventor 宋宏婷
Owner 宋宏婷
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