Method for preparing synthesis gas from organic dissolvant and biomass residue

A biomass residue and organic solvent technology, applied in gasification process, manufacturing of combustible gas, petroleum industry, etc., can solve the problems of low-quality biomass energy waste, inability to remove harmful substances, low energy utilization rate, etc., to increase profits , Significant environmental protection benefits, the effect of reducing equipment investment costs and operating costs

Inactive Publication Date: 2016-03-02
陕西省煤化工工程技术研究中心
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] CN103319102A discloses a method of using furfural waste residue as fuel, but it directly burns it directly, and does not make full use of a large amount of organic matter in it, resulting in low energy utilization rate
Some are disposed of by stacking or digging pits and dumping, which not only wastes human and financial resources, pollutes the environment, but also takes up a lot of land, making these low-quality biomass energy go to waste
[0009] CN103316897A discloses a treatment method for solid waste through digestion, granulation, sintering, and blending. This method cannot remove harmful substances that cannot be decomposed in the process, but instead forms a cumulative
CN1454721A discloses a treatment method for oily waste residue, but it only separates the oil and does not substantially treat the residue
Solid waste can easily cause soil and air pollution, and even more seriously, it will cause harm to the human body

Method used

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  • Method for preparing synthesis gas from organic dissolvant and biomass residue

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0070] Example 1: Production of Syngas from Organic Solvents and Biomass Residues

[0071] The implementation steps of this embodiment are as follows:

[0072] A. Pretreatment

[0073] In this example, organic solvent waste butanol produced by a chemical company and oxytetracycline residue produced by a pharmaceutical company were used as raw materials for slurry preparation.

[0074] Use 1% hydrochloric acid solution by weight, sulfuric acid solution, phosphoric acid solution or 2% acetic acid solution pH value adjuster to adjust the pH value of organic solvent waste butanol to 7.0; obtaining a biomass residue powder whose particle size is 100% by weight less than 13 mm;

[0075] B. Slurry preparation

[0076] Add 60 parts by weight of waste butanol organic solvent obtained in step A, 40 parts by weight of biomass residue powder obtained in step A, and 0.4 parts by weight of auxiliary fatty alcohol polyoxyethylene ether dispersant into a mill and grind into a material pul...

Embodiment 2

[0083] Example 2: Preparation of Syngas from Organic Solvents and Biomass Residues

[0084] The implementation steps of this embodiment are as follows:

[0085] A. Pretreatment

[0086] In this example, organic solvent waste acetone produced by a pharmaceutical company and distiller's grains produced by a brewery company were used as raw materials for slurry preparation.

[0087] Use 1% aqueous sodium hydroxide solution, 2% aqueous ammonia solution or 5% aqueous sodium carbonate pH value regulator to adjust the pH value of the waste acetone organic solvent to 9.0; simultaneously use a crusher to crush the biomass residue distiller's grains to obtain a particle size by weight 100% biomass residue powder less than 13mm;

[0088] B. Slurry preparation

[0089] Add 50 parts by weight of the organic solvent obtained in step A, 50 parts by weight of the biomass residue powder obtained in step A and 0.05 parts by weight of auxiliary alkylphenol polyoxyethylene ether dispersant int...

Embodiment 3

[0095] Example 3: Preparation of Syngas from Organic Solvents and Biomass Residues

[0096] The implementation steps of this embodiment are as follows:

[0097] A. Pretreatment

[0098] In this example, organic solvent waste butanol produced by a pharmaceutical company and penicillin residue produced by a pharmaceutical company were used as raw materials for slurry preparation.

[0099] Use 1% aqueous sodium hydroxide solution, 2% aqueous ammonia solution or 5% aqueous sodium carbonate pH value regulator to adjust the pH value of the waste butanol organic solvent to 8.0; simultaneously use a crusher to crush the biomass residue penicillin scum to obtain a particle size of more than Biomass residue powder with 100% by weight less than 13mm;

[0100] B. Slurry preparation

[0101] Add 80 parts by weight of the organic solvent obtained in step A, 20 parts by weight of the biomass residue powder obtained in step A and 0.8 parts by weight of auxiliary fatty alcohol polyoxyethyle...

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Abstract

The invention discloses a method for preparing synthesis gas from an organic dissolvant and a biomass residue, wherein the method comprises the steps of pretreatment, slurry preparation, gasification and the like. The characteristics of high calorific value and organic matter cosolvency of the abandoned organic dissolvant and low mineral content, low ash fusion point and rich C and H elements of the biomass residue are fully used, and the waste harmless treatment and resource transfer application are realized. The calorific value of the prepared slurry is 10%-70% higher than that of 60% water coal slurry having the same mass as the slurry, and the method can be used in preparation of the synthesis gas with CO and H2 as main components through a wet entrained-flow bed gasification process.

Description

【Technical field】 [0001] The invention belongs to the technical field of coal gasification slurry preparation. More specifically, the present invention relates to a method for the production of synthesis gas from organic solvents and biomass residues. 【Background technique】 [0002] With the rapid development of my country's pharmaceutical industry, the pollutants produced in the production process have also caused great pressure on the environment. How to treat the waste generated in the pharmaceutical process in a harmless manner is an important problem to be solved urgently. The waste solvent produced in the pharmaceutical process is an organic substance rich in C and H, which has a high calorific value, and direct disposal is not conducive to resource recycling. Solvent recovery is an important link in the production of pharmaceutical companies, but its recovery rate needs to be improved, and its composition is complex. Waste organic solvents produced by chemical comp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10J3/00
CPCC10J3/00C10J2300/0906C10J2300/0946C10J2300/0959
Inventor 戴爱军贺根良张勇袁善录葛启明门长贵徐宏伟郑亚兰杜彦学谢欣馨韦孙昌党慧霞罗进成张瑜张晓慧
Owner 陕西省煤化工工程技术研究中心
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