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Modified alkaline phenolic resin self-hardening sand of non-stick pump valve castings and preparation method of modified alkaline phenolic resin self-hardening sand

A technology of phenolic resin and phenolic resin bonding, which is applied in the field of modified alkaline phenolic resin self-setting sand and its preparation, can solve the problems of easy pinholes in castings, difficult recycling and high gas generation, and improve the reuse performance , Easier to release the mold and peel off, the effect of low viscosity

Inactive Publication Date: 2016-03-23
合肥李诺新材料贸易有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Although no-bake phenolic resin sand has its unique advantages, it also has some prominent shortcomings, mainly in high viscosity, high brittleness, high gas generation, easy pinholes in castings, high cost, and difficult recycling. etc., with the development of pump and valve castings in the direction of large-scale production and high precision, the development of high-efficiency, pollution-free, low-cost, and excellent comprehensive performance phenolic resin adhesives is an important prerequisite for casting high-quality castings

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0016] The resin sand in this example is prepared from the following raw materials in parts by weight: old sand 30, mullite sand 60, wollastonite powder 8, nano-graphite 1, nano-calcium fluoride 0.2, polypropylene chip 0.4, calcium carbonate 0.01, silane Joint agent 0.01, modified phenolic resin adhesive 1, curing agent 0.3.

[0017] Among them, the modified phenolic resin adhesive is made of the following raw materials in parts by weight: 0.2 octyl epoxy stearate, 0.1 silicone surfactant, 1 nano-alumina, 2 cellulose triacetate, 20 phenol, and the concentration is 35%. 20% formaldehyde solution, 30% potassium hydroxide solution 3, urea 1, silane coupling agent 0.1; the preparation method is: add phenol and formaldehyde into the reactor, heat to 60°C, stir and mix for 20min, then add hydrogen Potassium oxide solution, heated up to 80 °C for 4 hours, then added triacetate cellulose, urea, silicone surfactant, continued to stir and mix for 1.5 hours, cooled to room temperature af...

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PUM

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Abstract

The invention discloses modified alkaline phenolic resin self-hardening sand of non-stick pump valve castings. An adopted modified phenolic resin adhesive in the resin sand has the advantages that the viscosity is low, the bonding strength is high, the plasticity is good, the brittleness is low, the contents of free phenol and free formaldehyde are lower, the use amount is lower, the hardening speed is decreased, and the like, so that the use and reuse performance of the molding sand can be effectively improved; nano calcium fluoride porous polypropylene fiber blended in the sand adopts a uniform porous structure and is extremely good in toughness, so that the plasticity and stability of the molding sand can be effectively improved; complex and uniform meshy structures are formed in a sand mold, and nano calcium fluoride can form a non-stick layer on the surface of the sand mold, so that sand does not adhere to the surfaces of castings, the surface quality is improved, and the sand is more liable to collapse and peeling; and the added nano graphite can improve the self-lubricating performance of the surface of the molding sand and improve the non-stick capacity, so that the castings are more liable to demolding and peeling, and the working efficiency is improved while the quality of the castings is improved.

Description

technical field [0001] The invention relates to the technical field of resin sand, in particular to a modified alkaline phenolic resin self-setting sand that does not stick to pump valve castings and a preparation method thereof. Background technique [0002] Castings for pumps and valves have the characteristics of thin walls and complex shapes. In the casting process, the quality requirements for molding sand are particularly strict, and the quality of molding sand is also an important factor related to the quality of castings. Molding sand is mainly a kind of material used for molding in casting, which is made by mixing sand materials, adhesives and auxiliary substances according to different proportions. According to the different adhesives used, it can be divided into clay sand and water glass sand. , resin sand, etc. Among them, phenolic resin sand is widely used in the domestic foundry industry, and no-bake phenolic resin sand is widely used in the industry because of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22C1/00B22C1/22
Inventor 李诺
Owner 合肥李诺新材料贸易有限公司