PVC (polyvinyl chloride) foam material for sole and preparation method of PVC foam material

A technology for foaming materials and shoe soles, which is applied in the field of PVC foaming materials for shoe soles and its preparation, can solve the problems of poor foaming performance, poor thermal stability, poor fluidity, etc., and achieves improved heat resistance, excellent processing performance, good compatibility

Inactive Publication Date: 2016-03-30
广东祺龙科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general-purpose thermoplastics. It has light weight, high strength, insulation, flame retardancy, corrosion resistance, It has the advantages of excellent comprehensive performance, low price and wide source of raw materials; but it also has the following disadvantages: 1. Poor toughness, easy to be brittle when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. Large, the lower limit of general PVC products is -15°C, and the lower limit of soft PVC is -30°C; 2. Poor thermal stability, it begins to decompose HCl at 100°C, and decomposes more rapidly when it is higher than 150°C. The melting temperature of PVC is about 210°C; 3. The viscosity of PVC is extremely high and its fluidity is extremely poor, which limits its use to a certain extent.
[0005] Above-mentioned existing PVC material foaming performance is relatively poor, can't satisfy the demand of market, therefore, be necessary to develop a kind of performance excellent sole PVC foaming material

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0057] A PVC foam material for shoe soles, the PVC foam material for shoe soles includes the following parts by weight of raw materials:

[0058] 80 parts of PVC resin

[0059] Plasticizer 40 parts

[0060] 20 parts of filler

[0061] 6 parts of wear-resistant modifier

[0062] 4 parts of heat stabilizer

[0063] 2 parts of foaming agent

[0064] 0.8 parts of lubricant

[0065] 1 part of processing aid.

[0066] The PVC resin is an ethylene PVC resin with a degree of polymerization of 600.

[0067] The plasticizer is a mixture composed of cyclohexane 1,2-dicarboxylate diisononyl ester, triethyl citrate and epoxy soybean oil in a weight ratio of 1.5:0.8:1.

[0068] The filler is nano-active calcium carbonate with a particle size of 10 nm.

[0069] The wear-resistant modifier is a mixture composed of styrene-butadiene rubber and natural rubber in a weight ratio of 1.8:1.

[0070] The heat stabilizer is a mixture composed of a calcium-zinc composite heat stabilizer and a hydrotalcite heat stabiliz...

Embodiment 2

[0079] A PVC foam material for shoe soles, the PVC foam material for shoe soles includes the following parts by weight of raw materials:

[0080] 90 parts of PVC resin

[0081] Plasticizer 45 parts

[0082] 22 parts of filler

[0083] 7 parts of wear-resistant modifier

[0084] 5 parts of heat stabilizer

[0085] Blowing agent 2.5 parts

[0086] Lubricant 0.9 parts

[0087] 1.2 parts of processing aids.

[0088] The PVC resin is an ethylene PVC resin with a degree of polymerization of 700.

[0089] The plasticizer is a mixture composed of cyclohexane 1,2-dicarboxylate diisononyl ester, triethyl citrate and epoxy soybean oil in a weight ratio of 1.8:0.9:1.

[0090] The filler is nanometer active calcium carbonate with a particle size of 30 nm.

[0091] The wear-resistant modifier is a mixture composed of styrene-butadiene rubber and natural rubber in a weight ratio of 2.0:1.

[0092] The heat stabilizer is a mixture composed of a calcium-zinc composite heat stabilizer and a hydrotalcite heat sta...

Embodiment 3

[0101] A PVC foam material for shoe soles, the PVC foam material for shoe soles includes the following parts by weight of raw materials:

[0102] 100 parts of PVC resin

[0103] Plasticizer 50 parts

[0104] 25 parts of filler

[0105] 8 parts of wear-resistant modifier

[0106] 6 parts of heat stabilizer

[0107] 3 parts of foaming agent

[0108] 1 part lubricant

[0109] 1.5 parts of processing aid.

[0110] The PVC resin is an ethylene PVC resin with a degree of polymerization of 800.

[0111] The plasticizer is a mixture composed of cyclohexane 1,2-dicarboxylate diisononyl ester, triethyl citrate and epoxy soybean oil in a weight ratio of 2:1:1.

[0112] The filler is nano-active calcium carbonate with a particle size of 50 nm.

[0113] The wear resistance modifier is a mixture composed of styrene butadiene rubber and natural rubber in a weight ratio of 2.2:1.

[0114] The heat stabilizer is a mixture composed of a calcium-zinc composite heat stabilizer and a hydrotalcite heat stabilizer in...

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Abstract

The invention relates to the technical field of PVC materials, in particular to a PVC (polyvinyl chloride) foam material for a sole and a preparation method of the PVC foam material. The PVC foam material for the sole comprises raw materials in parts by weight as follows: 80-120 parts of PVC resin, 40-60 parts of a plasticizer, 20-30 parts of a filling agent, 6-10 parts of a wear-resistant modifier, 4-8 parts of a thermal stabilizer, 2-4 parts of a foaming agent, 0.8-1.2 parts of a lubricant and 1-2 parts of a processing aid. The raw materials are adopted for preparation of the PVC foam material for the sole, the weight proportion of the raw materials is controlled strictly, the performance of the prepared PVC foam material for the sole exceeds the national standards, and the PVC foam material is environment-friendly and has good temperature resistance and weather resistance, high strength, excellent anti-impact performance, good flame-retardant effect, good processing performance and excellent comprehensive performance.

Description

Technical field [0001] The invention relates to the technical field of PVC materials, in particular to a PVC foam material for shoe soles and a preparation method thereof. Background technique [0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general thermoplastics. It has the advantages of light weight, high strength, insulation, flame retardant, corrosion resistance, excellent comprehensive performance, low price and wide raw material sources; but also There are the following shortcomings: 1. Poor toughness, easily brittle and cracked when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. The lower limit of use for general PVC products is -15°C, soft The lower limit of the use of PVC is -30℃; 2. The thermal stability is poor. It starts to decompose HCl at 100℃, and decomposes more rapidly when it is higher than 150℃. The melting temperature of PVC ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L9/06C08L7/00C08L33/08C08L33/12C08L23/08C08K13/02C08K3/26C08K5/098C08K3/22C08K3/38C08J9/10B29C47/92A43B13/04B29C48/92
CPCC08L27/06A43B13/04B29C48/92C08J9/102C08J9/103C08J2203/04C08J2203/18C08J2327/06C08J2407/00C08J2409/06C08K2201/003C08K2201/011C08K2201/014C08L2201/02C08L2201/08C08L2203/14C08L2205/02C08L2205/025C08L2205/035C08L2205/06C08L9/06C08L7/00C08L33/08C08L23/0853C08K13/02C08K2003/265C08K5/098C08K3/2279C08K2003/387C08L33/12
Inventor 宁建华
Owner 广东祺龙科技有限公司
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