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Preparation method of anode paste for lithium-ion power battery

A negative electrode slurry and power battery technology, applied in the direction of electrode manufacturing, battery electrodes, secondary batteries, etc., can solve the problems of easy aggregation of nano-sized particles into large particles, low equipment utilization rate, and influence on the coating process, so as to avoid Shear thickening effect, increase production capacity, and reduce machine loss

Inactive Publication Date: 2016-04-13
HEFEI GUOXUAN HIGH TECH POWER ENERGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method takes a long time to prepare the negative electrode slurry, the utilization rate of the equipment is low, the production capacity is relatively low, and the nano-sized particles are easy to aggregate into large particles, which will affect the subsequent coating process.
The dry mixing process that emerged in the later period uses two sets of equipment, one is used for glue making, the other is used for dry mixing of powder materials, and finally the glue liquid and powder materials are mixed. This method has short mixing time and high efficiency, but at the same time high equipment cost

Method used

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  • Preparation method of anode paste for lithium-ion power battery

Examples

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Embodiment 1

[0021] With 100 parts by weight of micron-sized negative electrode graphite (specific surface area 1.09m 2 / g) and 2 parts of conductive carbon black are added to the pulper ( figure 1 is the mixing effect diagram of the pulper), dry mixing and stirring for 10 minutes; continue to add 2 parts of dispersant CMC (carboxymethylated cellulose), and dry mixing for 10 minutes. Then, add 85 parts of deionized water, pass through the condensed water, stir at low speed for 10 minutes, and stir at high speed for 1 hour; scrape glue, vacuumize, and continue mixing at high speed for 3 hours. Finally, 3 parts of binder SBR (styrene-butadiene rubber emulsion) was added, stirred at a high speed, and dispersed at a low speed for 1 hour to obtain a negative electrode slurry for a lithium battery.

Embodiment 2

[0023] With 100 parts by weight of micron-sized negative electrode graphite (specific surface area 1.09m 2 / g) and 2 parts of conductive carbon black were added to the mixer, dry-mixed and stirred for 15 minutes; continue to add 2 parts of dispersant CMC, and dry-mixed for 15 minutes. Then, add 95 parts of deionized water, pass through the condensed water, stir at low speed for 15 minutes, and disperse at high speed for 1 hour; scrape the glue, vacuumize, and continue to mix at high speed for 3.5 hours. Finally, add 3 parts of binder SBR, stir at high speed and disperse at low speed for 1 hour to obtain negative electrode slurry for lithium battery.

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Abstract

The invention discloses a preparation method of an anode paste for a lithium-ion power battery. The anode paste is prepared from an active material, a conductive agent, a dispersing agent, a binder and a solvent; the preparation method comprises an order of mixing various components in the anode paste; and the method is characterized in that mixing is carried out by the following four steps: (1) carrying out high-speed stirring and dry mixing on the active material and the conductive agent; (2) adding the dispersing agent, and carrying out dry mixing on the dispersing agent and black powder obtained in the step (1); (3) adding the solvent, introducing condensate water, carrying out high-speed stirring and dispersing after low-speed stirring, carrying out fractioning and vacuum supply and further carrying out high-speed vacuum mixing; and (4) adding the binder, and dispersing and mixing the binder. A dry mixing technology is utilized; and the solvent is added once, so that the paste mixing time is shortened; the machine loss caused by a high solid content is reduced; the capacity is improved; and a relatively good mixing effect is obtained.

Description

technical field [0001] The invention relates to the field of lithium ion battery manufacturing, in particular to a preparation method of a lithium ion power battery negative electrode slurry. Background technique [0002] Lithium-ion power batteries have the advantages of high specific energy, light weight, good cycle performance, small self-discharge, no memory effect, wide working range and environmental protection, and their application range is becoming wider and wider. In general lithium-ion power batteries, the negative electrode is made of micron-sized traditional graphite materials such as artificial graphite, natural graphite, hard carbon or soft carbon. However, the conductivity of a single micron-scale graphite negative electrode is not very good, so adding nano-scale superconducting carbon black to the negative electrode material improves its conductivity. [0003] The traditional negative electrode slurry is prepared by wet mixing, that is, first glue (preparat...

Claims

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Application Information

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IPC IPC(8): H01M4/1393H01M4/04H01M10/0525
CPCH01M4/04H01M4/1393H01M10/0525Y02E60/10
Inventor 陶静宫璐陈炜侯守卫张俊张炎斌
Owner HEFEI GUOXUAN HIGH TECH POWER ENERGY
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