Hydrogel material for treating heavy metal containing sewage and preparation method of hydrogel material

A hydrogel and heavy metal technology, applied in water/sewage treatment, chemical instruments and methods, adsorption water/sewage treatment, etc., can solve the problem of poor structural stability of hydrogel materials, limited selection of sewage treatment materials, hydrogel materials Few types and other issues, to achieve the effect of high market application prospects, enhanced mechanical properties, and low cost

Inactive Publication Date: 2016-04-20
山东慈诚环境科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The hydrogel of this invention can efficiently adsorb heavy metal ions in water, and has the characteristics of high adsorption capacity, high selectivity, recyclable utilization, and biodegradability; however, the hydrogel material prepared by this invention has poor structural stability and long service life. short
[0006] With the rapid development of my country's economy and industrial technology, more and more attention has been paid to environmental issues. Sewage treatment materials have become an important part of sewage treatment technology and have attracted attention from various fields. However, the hydrogel materials currently used for sewage treatment There are fewer types, which greatly limits the selection of sewage treatment materials. Therefore, it is necessary to develop a hydrogel material suitable for sewage treatment that has good adsorption efficiency for heavy metal ions in sewage, large adsorption capacity, and excellent mechanical properties. materials, it is of great significance to promote the development of sewage treatment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A hydrogel material for treating sewage containing heavy metals:

[0032] (1) the sepiolite that is 10 parts by weight and the humic acid that is 3.0 parts by weight are placed in water, and carry out ultrasonic dispersion, form suspension;

[0033] (2) the methacrylic acid that the weight portion is 30, the polyethylene glycol that the weight portion is 20, the polyvinyl alcohol that the weight portion is 5.0, the ammonium persulfate that the weight portion is 0.4, the aluminum sulfate that the weight portion is 0.05 and the weight portion Add 0.05 part of N,N`-methylene acrylamide into the suspension in step (1), and carry out ultrasonic stirring and mixing at a heating temperature of 75°C, with a stirring speed of 400 rpm and a stirring time of 100 minutes, to obtain a homogeneous mixture containing primary products of phytic acid and sepiolite;

[0034] (3) Filter the primary product obtained in step (2) and uniformly mix humic acid and sepiolite, wash the filtered...

Embodiment 2

[0036] A hydrogel material for treating sewage containing heavy metals:

[0037] (1) the sepiolite that is 15 parts by weight and the humic acid that is 5.0 parts by weight are placed in water, and carry out ultrasonic dispersion, form suspension;

[0038] (2) the methacrylic acid that the weight part is 50, the polyethylene glycol that the weight part is 30, the polyvinyl alcohol that the weight part is 7.0, the ammonium persulfate that the weight part is 0.6, the aluminum sulfate that the weight part is 0.10 and weight part Add 0.10 parts of N,N`-methylene acrylamide to the suspension in step (1), and carry out ultrasonic stirring and mixing at a heating temperature of 75°C, with a stirring speed of 400-600rpm and a stirring time of 120 minutes, to obtain a uniform mixture Primary products containing humic acid and sepiolite;

[0039] (3) Filter the primary product obtained in step (2) and uniformly mix humic acid and sepiolite, wash the filtered product with ethanol, and p...

Embodiment 3

[0041] A hydrogel material for treating sewage containing heavy metals:

[0042] (1) the sepiolite that is 12 parts by weight and the humic acid that is 4.2 parts by weight are placed in water, and carry out ultrasonic dispersion, form suspension;

[0043] (2) the methacrylic acid that the weight part is 38, the polyethylene glycol that the weight part is 24, the polyvinyl alcohol that the weight part is 5.9, the ammonium persulfate that the weight part is 0.4, the aluminum sulfate that the weight part is 0.07 and weight part Add 0.08 part of N,N`-methylene acrylamide into the suspension in step (1), and carry out ultrasonic stirring and mixing at a heating temperature of 75°C, with a stirring speed of 480rpm and a stirring time of 100 minutes, to obtain a homogeneous mixture containing primary products of phytic acid and sepiolite;

[0044] (3) Filter the primary product obtained in step (2) and uniformly mix humic acid and sepiolite, wash the filtered product with ethanol, ...

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Abstract

The invention discloses a hydrogel material for treating heavy metal containing sewage. The hydrogel material is mainly prepared from, by weight, 30-50 parts of methacrylic acid, 20-30 parts of polyethylene glycol, 10-15 parts of sepiolite, 5.0-7.0 parts of polyvinyl alcohol, 3.0-5.0 parts of humic acid, 0.4-0.6 part of ammonium persulfate, 0.05-0.10 part of aluminum sulfate and 0.05-0.10 part of N,N'-methylene bisacrylamide. The reinforcing function of humic acid and sepiolite is utilized, humic acid and sepiolite are evenly inserted into a three-dimensional network hydrogel material formed by methacrylic acid, polyethylene glycol and polyvinyl alcohol, and the hydrogel material with good adsorption efficiency on heavy metal ions, the large adsorption amount, a stable structure and excellent mechanical performance is formed. Production cost is reduced, meanwhile, the thermal decomposition temperature of the material is raised, the service life of the material is prolonged, and the hydrogel material is suitable for the sewage treatment technology. The invention further discloses a preparation method of the hydrogel material for treating the heavy metal containing sewage. The production process is simple, cost is low, safety and environment friendliness are achieved, and market application prospects are achieved.

Description

technical field [0001] The invention belongs to the field of new materials, and in particular relates to a hydrogel material used for treating sewage containing heavy metals and a preparation method thereof. Background technique [0002] With the rapid development of modern industry and rapid economic growth, the traditional extensive and labor-intensive economic development model has brought a series of environmental problems. Among them, the problem of water pollution is particularly serious. At present, water pollution has become a major problem that restricts economic development, affects social stability, endangers human health and destroys ecological balance. At the same time, my country's natural water resources are extremely limited. Therefore, the development and innovation of sewage treatment and sewage resource technology should be further valued. [0003] Chinese Patent Publication No. CN103804828A discloses a composite hydrogel for absorbing heavy metal ions a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L71/02C08L29/04C08L99/00C08K3/34C08F283/06C08F220/06C02F1/28C02F1/62
CPCC02F1/281C02F1/285C02F1/62C08F283/06C08L71/02C08L2201/08C08L2205/03C08F220/06C08L29/04C08L99/00C08K3/34
Inventor 陈庆叶任海
Owner 山东慈诚环境科技有限公司
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