Sulfonated polyaryletherketone copolymer containing benzothiazole side group and preparation method thereof
A technology of sulfonated polyaryletherketone and copolymer, which is applied in the field of sulfonated polyaryletherketone copolymer and its preparation, and can solve the problems of reduced anti-oxidation stability, increased fuel transmission rate, and reduced life of membrane materials, etc. , to improve chemical stability and mechanical properties, hinder permeation, and inhibit excessive swelling
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0037] In a three-necked flask equipped with a mechanical stirrer, a water dispenser, a thermometer, a condenser tube, and nitrogen protection, add 0.04mol of tetramethylbiphenol, 0.06mol of diallyl bisphenol A, and 0.05mol of 4 , 4'-difluorobenzophenone, 0.05mol of 3,3'-sodium disulfonate-4,4'-difluorobenzophenone, 0.12mol of potassium carbonate as a salt-forming agent, and dimethylformaldehyde Amide is used as solvent, toluene is used as water carrier, and the solid content is 20%. Bring water at 120°C for 3 hours, then distill off the toluene, raise the temperature to 150°C and continue the reaction for 10 hours. After the reaction was complete, the reactant was poured into distilled water to form a light yellow strip solid, which was pulverized into a fine powder with a pulverizer, washed 5 times with acetone, and then washed 5 times with distilled water. Dry in an oven at 80°C to obtain sulfonated polyaryl ether ketone containing acryl group;
[0038] The polymer is the...
Embodiment 2
[0040] In a three-necked flask equipped with a mechanical stirrer, a water dispenser, a thermometer, a condenser tube, and nitrogen protection, add 0.08 mol of hexafluorobisphenol A, 0.02 mol of diallyl bisphenol A, and 0.05 mol of 4,4 '-Difluorobenzophenone, 0.05mol of 3,3'-sodium disulfonate-4,4'-difluorobenzophenone, 0.105mol of potassium carbonate as salt-forming agent, and dimethylacetamide as As a solvent, toluene is used as a water-carrying agent, and the solid content is 20%. Bring water at 130°C for 3 hours, then distill off the toluene, raise the temperature to 160°C and continue the reaction for 8 hours. After the reaction was complete, the reactant was poured into distilled water to form a light yellow strip solid, which was pulverized into a fine powder with a pulverizer, washed 5 times with acetone, and then washed 5 times with distilled water. Dry it in an oven at 80°C to obtain propylene-containing sulfonated polyaryletherketone.
[0041]Subsequently, the pol...
Embodiment 3
[0043] In a three-necked flask equipped with a mechanical stirrer, a water dispenser, a thermometer, a condenser tube, and nitrogen protection, add 0.02mol of bisphenol A, 0.08mol of diallyl bisphenol A, and 0.02mol of 4,4'- Difluorobenzophenone, 0.08mol of 3,3'-sodium disulfonate-4,4'-difluorobenzophenone, 0.11mol of potassium carbonate as a salt-forming agent, and N-methylpyrrolidone as a solvent, Toluene is used as the water-carrying agent, and the solid content is 20%. Bring water at 140°C for 3 hours, then distill off the toluene, raise the temperature to 170°C and continue the reaction for 6 hours. After the reaction was complete, the reactant was poured into distilled water to form a light yellow strip solid, which was pulverized into a fine powder with a pulverizer, washed 5 times with acetone, and then washed 5 times with distilled water. Dry it in an oven at 80°C to obtain propylene-containing sulfonated polyaryletherketone.
[0044] Subsequently, the polymer is ad...
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More