Treating method for vanadium slag roasting tail gas

A treatment method and tail gas technology, applied in the direction of gas treatment, separation methods, chemical instruments and methods, etc., can solve the problems of unutilized waste heat of tail gas, difficulty in achieving standard discharge, and difficult treatment of sulfide, so as to save steam consumption and save Coal consumption of the boiler and the effect of reducing the amount of spraying of circulating water

Inactive Publication Date: 2016-07-06
PANZHIHUA UNIV
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  • Abstract
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  • Application Information

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Problems solved by technology

The problems with this traditional method are that firstly, the waste heat of the exhaust gas is not utilized, and secondly, that it is sometimes difficult to meet the emission standards. Even if the standards are met, the indicators are still close to the upper limit
[0008] To sum up, in the prior art, there are problems that the waste heat of the rotary kiln roasting tail gas is not utilized or the waste heat utilization efficiency is low, and the sulfides in the tail gas are difficult to control, and the tail gas often cannot meet the standard.

Method used

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  • Treating method for vanadium slag roasting tail gas
  • Treating method for vanadium slag roasting tail gas
  • Treating method for vanadium slag roasting tail gas

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Embodiment 1

[0149] From the tail of a vanadium pentoxide rotary kiln with an annual production capacity of 5,000 tons, the exhausted roasting tail gas at 350-450°C is connected to a multi-tube ceramic cyclone through the main flue of the rotary kiln. After cyclone dust removal, 90% The vanadate dust is collected in the collector at the lower part of the cyclone, and the exhaust gas is passed into the waste heat boiler.

[0150]Pass the desalted water to be heated into the deaerator, and exchange heat with the hot steam coming from the steam accumulator. After the temperature rises to 100-110°C, thermal deaeration is carried out. The desalinated water after oxygen removal is sent to the hot water heater of the waste heat boiler through the boiler feed water pump, and after heat exchange with the tail gas through the longitudinal fin heat pipe, the desalinated water becomes hot water at 150-160 °C. The tail gas then exchanges heat with the 150-160°C desalted water heated by the heater at th...

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Abstract

The invention belongs to the field of production of vanadium pentoxide, and particularly relates to a treating method for tail gas produced after vanadium slat is roasted through a rotary kiln. The method comprises the following steps that a, vanadium slag roasting tail gas enters a dust removal system and is separated to obtain vanadate and tail gas I, wherein the vanadate is transferred into a pulping groove; b, the tail gas I enters a waste heat boiler system and exchanges heat with process water supplied externally to be cooled, tail gas II is obtained, and the process water is changed into saturated vapor to be supplied externally; c, the tail gas II enters a Venturi system to be cooled further, and tail gas III is obtained; d, the tail gas III enters a desulfurizing tower from the bottom and makes countercurrent contact with alkali liquor sprayed on the top, defogging is carried out, up-to-standard emission is carried out, and the alkali liquor enters a sewage treating system. By means of the method, the vanadium pentoxide rotary kiln roasting tail gas waste heat utilization rate can be improved, sulfide in the roasting gas can be discharged on standard completely, and therefore a new technological process of clean production of a vanadium pentoxide roasting tail gas system is achieved.

Description

technical field [0001] The invention belongs to the field of vanadium pentoxide production, and in particular relates to a method for treating tail gas produced by vanadium slag roasting in a rotary kiln during the production process of vanadium pentoxide. Background technique [0002] Vanadium pentoxide is widely used in metallurgy, chemical industry and other industries, mainly for smelting ferrovanadium. It is used as an alloy additive, accounting for more than 80% of the total consumption of vanadium pentoxide, followed by a catalyst for organic chemical industry, that is, a catalyst, accounting for about 10% of the total. In addition, it is used as an inorganic chemical, chemical reagent, enamel and Magnetic materials, etc. account for about 10% of the total. A prominent problem in the current production process of vanadium pentoxide is environmental protection and energy saving. [0003] At present, the production of vanadium pentoxide generally uses vanadium slag as...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/80B01D53/48B01D45/12C01G31/02
CPCB01D45/12B01D53/48B01D53/80B01D2258/025C01G31/02Y02P20/129
Inventor 邹建新周洪伍斌谢四才徐国印刘延慧
Owner PANZHIHUA UNIV
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